• Korean Journal of Optics and Photonics
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• v.4 no.3
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• pp.347-353
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• 1993

A picosecond transient absorption kinetic spectrometer using a pump-probe method is presented and compared with other methods of picosecond transient absorption measurements. This constructed kinetic spectrometer detects the transient transmittance of sample using a lock-in amplifier as a function of delay time between pump and probe pulses generated from a picosecond mode-locked cw dye laser. Typical transient absorption and ground state bleach recovery kinetic profiles measured with this spectrometer are shown. Excellent kinetic curves of transient absorption or ground state bleach recovery may be obtained at single wavelengths with this spectrometer.

• Journal of Plant Biology
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• v.21 no.1_4
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• pp.33-38
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• 1978

Phosphate absorption from a Na2H32PO4 solution by Oryza sativa L. was studied in order to elucidate kinetic mechanisms of ion transport. The rates of phosphate absorption from different concentraitons indicated the presence of dual mechanisms in root tips, one in the low (1$\times$10-6 to 8$\times$10-5M) and the other in the high (1$\times$10-4 to 8$\times$10-3M). A phosphate compensation point of phosphate transport was revealed with a 1$\times$10-6M solution of Na2H32PO4. The kinetic model that ion transport involves an exchange reaction of absorption and desorptin is prosposed as follows: where C represents an ionic-specific organic carrier in the membrane; M, Mo and Mi are the mineral ions, M-outside and M-inside; MC is a carrier-ion complex; and the K's represent rate constants. In this model, the Mi velocity, v, is given by: {{{{v= {dMi} over {dt}= {(K1K3Mo-K2K4Mi) Ct} over {(K2＋K3)＋K1Mo＋K4Mi} }} where Ct is equal to C＋MC, and t is time.

• Proceedings of the Optical Society of Korea Conference
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• 1990.02a
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• pp.172-176
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• 1990

A high resolution picosecond absorption kinetic spectrometer utilizing dye emission and a streak camera is presented and compared with other methods of picosecond transient absorption measurements. Typical transient absorption and bleach recovery kinetics measured with this spectrometer are shown. Single wavelength transient absorption or ground state bleach recovery kinetics are determined on the basis of a single laser shot, so that the samples are relatively free frm decomposition by irradiation. Excellent kinetics may be obtained from the near UV to the near IR and are not subject to interference from luminescence of samples. The sensitivity of this spectrometer is very high and it is reasonably easy and convenient to set up and use.

• The Journal of the Acoustical Society of Korea
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• v.31 no.2
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• pp.100-106
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• 2012

The aim of this work was to reveal the effect of butanoic acid in its dissociated form and undissociated form as a guest molecule on the kinetic parameters in an inclusion reaction with ${\beta}$-cyclodextrin (${\beta}$-CD). Ultrasonic absorption measurements in the frequency range from 0.2 to 45 MHz were carried out for ${\beta}$-CD solutions with butanoic acid at $25^{\circ}C$ by ultrasonic relaxation method. The rate and the equilibrium constants were obtained from the guest concentration dependence of the relaxation frequency, and the standard volume change of the complexation reaction were obtained from the maximum absorption per wavelength. A single relaxational absorption was observed, and the cause of the relaxation was attributed to a perturbation of the chemical equilibrium associated with a complexation reaction between ${\beta}$-CD and butanoic acid. These results were compared with those in solutions containing both ${\beta}$-CD and different guest molecules. It was found that the hydrophobicity of guest molecules played an important role in the formation of the inclusion complex and also that the charge on the carboxylic group had a considerable effect on the kinetic characteristics of the complexation reaction.

• Advances in environmental research
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• v.3 no.1
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• pp.29-43
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• 2014

Pharmaceutical wastewater effluents are well known for their difficult elimination by traditional biotreatment methods and their important contribution to environmental pollution due to its fluctuating and recalcitrant nature. OTC is one of the nonbiodegradable antibiotics that makes antibiotic-resistant, so it can make be high risk for environment. NZVI can be a good choice for removal of OTC in aqueous solution. Response surface methodology (RSM) was used to optimize the amounts of NZVI and OTC to be used at pH 3 and under 200 W, UV-A irradiation. The responses were removal percent of absorption at 290 and 348 nm, TOC and COD of OTC. In the optimum condition, Linear model was performed 155 ppm of OTC were removed by 1000 ppm NZVI after 6.5 hours and the removal efficiency of absorption at 290 and 348 nm, TOC and COD were 87, 95, 85 and 89 percent, respectively. In the similar process, there is no organic compound after 14 hours. The parameters ORP, DO and pH were investigated for 6:30 hours to study the type of NZVI reaction in process. In the beginning of reaction, oxidation was the dominant reaction after 3 hours, photocatalytic reaction was remarkable. The mechanism of OTC degradation is proposed by HPLC/ESI-MS and four by products were found. Also the rate constants (first order kinetic chain reaction model) were 0.0099, 0.0021, 0.0010, 0.0049 and $0.0074min^{-1}$, respectively.

• Journal of Photoscience
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• v.9 no.2
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• pp.296-298
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• 2002

Irreversible photobleaching of bacteriorhodopsin (bR), namely denaturation induced by illumination of visible light, was investigated by absorption kinetic measurements. The denaturation kinetics revealed that light illumination significantly enhanced the structural decay of bR. The kinetic analyses showed that the molecular structure of bR denatures according to a single-exponential decay, whereas irreversible photobleaching has two decay components. The decay constant of the slow component of photobleaching is almost same as that in the dark. An Arrhenius plot of the denaturation kinetic constants for the fast and slow components showed similar activation energies of approximately 19 kcal/mol.

• Journal of the Korean Wood Science and Technology
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• v.47 no.5
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• pp.557-566
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• 2019

Radial and tangential water diffusion in Eucalyptus globulus wood was investigated using three mature trees from a forest in Khemis Sahel (North Morocco). Absorption and desorption kinetics experiments were conducted at ambient temperature ($25^{\circ}C$) and $30^{\circ}C$, respectively, and a relative humidity of 60%. The diffusion coefficients in the two directions were determined under imposed hygrothermal conditions; they were greater in the radial direction for the absorption as well as desorption processes. Convective drying under load, preceded by reconditioning and followed up by balancing, revealed the drying conditions that corresponded to the appropriate drying schedules for E. globulus wood. This was verified by measuring the cracks and bowsbefore and after drying of boards.

• Bulletin of the Society of Naval Architects of Korea
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• v.19 no.1
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• pp.33-39
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• 1982

An experimental investigation on the ultimate load and energy absorption of thin plates is presented, which enables the damage to ship involved in a collision to be estimated in terms of the lost kinetic energy. The derived formulae are based upon experimental analysis and compared with theoretical presentations published by some authors. A relationship is found between the absorbed energy and the volume of damaged steel plates.

• Proceedings of the Korean Nutrition Society Conference
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• 1995.05c
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• pp.21-21
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• 1995

Absorption of fat-soluble vi tamin, retinol occurs mainly in the proximal part of small intestine. But its intestinal transport mechanism isn't yet clear. The aim of the present study was to investigate on the mechanism of absorption of retinol by determining a concentration-dependent kinetic of retinol absorption in rats. The study was carried out by applying in vivo technique in which vitamin solution was infused to intestinal lumen and at the same time thoracic duct and choledochus duct were canulated to collect samples. The investigations showed that retinol is absorbed in the small intestine by a saturable, carrier-mediated transport system, i.e. wi thout signi ficant differences between the proximal and distal halves of the small intestine. The transport of retinol taken up by the enterocytes occured via different mechanisms: while the main vitamin A transport via the thoracic duct was saturated by limiting transport factors such as retinol-CRBP-II-complex formation and retinol esterification with increasing substrate concentrations, the transport of retinol metabolite product via the portal vein was proportional to the substrate concentration.ration.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2000.11a
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• pp.84-87
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• 2000

Square tubes used for vehicle structure components have an important role on keeping its stiffness and preserving occupant safety in vehicle collision and rollover in which it experience axial collapse, bending collapse or both. Bending collapse, which absorbs kinetic energy of the impact and retains a survival space for the occupant, is a dominant failure mode in oblique collision and rollover. Thus, in this paper, the bending collapse characteristics such as the maximum bending moment and energy absorption capacity of the square tube replaced by light-weight material were evaluated and presented. The bending test of cantilever tubes which were fabricated with aluminum, GFRP and aluminum/ GFRP hybrid by co-curing process was performed. Then the maximum bending moment and the energy absorption capacity from the moment-angle curve were evaluated. Based on the test results, it was found that aluminum/ GFRP hybrid tube can show better specific energy absorption capacity compared to the pure aluminum or GFRP tube and can convert unstable collapse mode which may occur in pure GFRP tube to stable collapse mode like a aluminum tube in which plastic hinge is developed.