• Title/Summary/Keyword: absolute configuration

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Absolute Configuration of Di-(2-Picolyl) sulfur Dichloro Zinc(II) with an Enantiomorphic Space Group $P4_12_12$ (Enantiomorphic 공간군 $P4_12_12$을 갖는 Di-(2-Picolyl) sulfur Dichloro Zinc(II)의 Absolute Configuration)

  • Choi Ki-Young;Lee Han-Hyoung;Kim Min-Hee;Whang Min-Ah;Kang Sang Ook;Son Ho-Jin;Son Ki-Chul;Han Won-Sik;Suh Il-Hwan
    • Korean Journal of Crystallography
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    • v.16 no.1
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    • pp.21-29
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    • 2005
  • The crystal structure of an enantiomeric compound di-(2-picolyl)sulfur dichloro zinc(II), $C_{12}H_{12}N_2SCl_2Zn$, could be elucidated with two space groups $P4_12_12\;and\;P4_32_12$. However, its absolute configuration with the space group $P4_12_12$ was confirmed by means of the effect of anomalous dispersion.

Current-Controlled Wavelength-Tunable Fiber Comb Filter based on Polarization-Diversity Loop Configuration (전류 조절로 파장 튜닝 가능한 편광상이 배치구조 기반 광섬유 빗살 필터)

  • Choi, Dae-Ho;Lee, Yong-Wook
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.24 no.12
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    • pp.33-37
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    • 2010
  • In this paper, we have demonstrated absolute wavelength tuning in an optical fiber comb filter based on a polarization-diversity loop configuration by controlling the current injected into enameled wires wound on polarization-maintaining fibers (PMF's), that is, adjusting Joule heat generated from enameled wires. The proposed fiber comb filter consists of a polarization beam splitter, a half-wave plate, a quarter-wave plate, and PMF's. And we observed wavelength change of spectral dips in transmission spectra of the fabricated filter by varying an input current applied to enameled wires. The absolute wavelength of the filter could be controlled in proportional to the square of the input current with good linearity, and the rate of the wavelength shift with respect to the input current was measured as 36.79[nm/$A^2$].

Design and Implementation of an Absolute Position Sensor Based on Laser Speckle with Reduced Database

  • Tak, Yoon-Oh;Bandoy, Joseph Vermont B.;Eom, Joo Beom;Kwon, Hyuk-Sang
    • Current Optics and Photonics
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    • v.5 no.4
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    • pp.362-369
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    • 2021
  • Absolute position sensors are widely used in machine tools and precision measuring instruments because measurement errors are not accumulated, and position measurements can be performed without initialization. The laser speckle-based absolute position sensor, in particular, has advantages in terms of simple system configuration and high measurement accuracy. Unlike traditional absolute position sensors, it does not require an expensive physical length scale; instead, it uses a laser speckle image database to measure a moving surface position. However, there is a problem that a huge database is required to store information in all positions on the surface. Conversely, reducing the size of the database also decreases the accuracy of position measurements. Therefore, in this paper, we propose a new method to measure the surface position with high precision while reducing the size of the database. We use image stitching and approximation methods to reduce database size and speed up measurements. The absolute position error of the proposed method was about 0.27 ± 0.18 ㎛, and the average measurement time was 25 ms.

A Study on the Application of Spatial Configuration to Escher's Oppositive Tessellation (에셔의 대립적 테셀레이션 작품의 공간구성 적용에 관한 연구)

  • You, Jung-Hwan;Lee, Ho-Joung
    • Korean Institute of Interior Design Journal
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    • v.17 no.5
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    • pp.40-50
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    • 2008
  • This article examined the applicability of spatial configuration to Escher's works through configurative logics and rules and studied the contrasting relations among the unit elements in Escher's works and their characteristics and the creative process of the characteristics. As the results of the study on the bases to maintain and create the partial elements revealed as the characteristics, it was shown that Escher's sequential transformative works demonstrated diverse expressive characteristics as a creative process of Inter-complementary contrasting relations based on the independence of the unit elements. It was also shown that the creative process of the unit elements was actualized through the maintenance base of the fixed and absolute characteristic as the logic for the creation and the creation base of the dynamic and relative characteristic. Therefore, it was interpreted that by applying the logics for creation to Escher's unit elements through the spatial interpretation of the maintenance base and the creation base as well as by configuring the units created in such a way according to the characteristics of Escher's works, spatial possibility canbe derived out from Escher's contrasting tessellation works. The process of spatial configuration is the process to make a balance between various conditions, artists own understanding of the space and his/her intention of the space. From this viewpoint, the logics for maintenance base and for creation base seem to have the potentiality as a spatial configuration to consistently meet the given conditions as well as to derive out novelty through the transformation to maintain the fixed and absolute condition(base) and the characteristics of the independent(additional) transformation arising together with the implicit relations among the transformative units.

Synthesis and the Absolute Configurations of Isoflavanone Enantiomers

  • Won, Dong-Ho;Shin, Bok-Kyu;Han, Jae-Hong
    • Journal of Applied Biological Chemistry
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    • v.51 no.1
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    • pp.17-19
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    • 2008
  • Isoflavanone has been synthesized from the reduction of isoflavone in nearly quantitative yield. Isoflavone with seven equivalents of ammonium formate in the presence of Pd/C in ethanol under $N_2$ atmosphere exclusively produced the two-electron reduced product in two hours. It was characterized by various spectroscopic methods, including UV-VIS, EI-MS, $^1H$-NMR, $^{13}C$-NMR and $^1H$, $^1H$-COSY. The racemic mixture was separated by Sumi-Chiral column chromatography and the absolute configurations of the enantiomers were characterized by circular dichroism spectroscopy.