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Damping Ratios for Seismic Design of SC Structures (SC구조의 내진설계를 위한 감쇠비)

  • Lee, Seung-Joon;Kim, Won-Ki
    • Journal of Korean Society of Steel Construction
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    • v.22 no.5
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    • pp.487-496
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    • 2010
  • The structural damping ratios for seismic design of nuclear power plant structures are specified in Regulatory guide 1.61 of the United States NRC for RC structures of 4%(OBE) and 7%(SSE), and for steel structures of 3%(OBE) and 4%(SSE), but not for steel-plate concrete (SC) structures that have been developed recently. The objective of this study is to investigate the damping ratios of SC structures by identifying the relative differences in the damping ratios between RC and SC structures. An experimental study was performed on four specimens, RC-S, RC-M, SC-S and SC-M, where S stands for shear-governed and M for moment-governed. The conducted method was free vibration testing by rupturing a brittle steel plate that linked the actuator and the mass center. The test results were analyzed to determine fundamental frequencies and damping ratios at various load levels. By examining the relative differences in damping ratios of four specimens, it is proposed for SC structures to use the same damping ratio of 4% as RC one at OBE, but 1% less damping ratio than RC one resulting in 6% at SSE.

CO2 PSA Process using Double-Layered Adsorption Column (이단 적층 흡착탑을 이용한 CO2 PSA 공정)

  • Lee, Hwaung;Choi, Jae-Wook;Song, Hyung Keun;Na, Byung-Ki
    • Clean Technology
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    • v.7 no.1
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    • pp.51-63
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    • 2001
  • In this study, PSA, known as the most economic process, was used to recover $CO_2$ from the power-plant flue gas. Activated carbon and zeolite molecular sieve 13X were used as adsorbent. Activated carbon has been deemed inadequated adsorbent for separating $CO_2$ from the flue gas. However, highly concentrated $CO_2$ could be obtained as a product on the activated carbon adsorbent using the new operating cycle modifying the rinse step. Also, the recovery of $CO_2$ was improved using double-layered adsorption column packed with the activated carbon and the zeolite 13X simultaneously. Adsorption column was filled with the activated carbon in the feed-end side, and the zeolite 13X in the product-end side. The recovery of $CO_2$ increased about 40% with only 25% zeolite, and increased 67% with 50% zeolite at the experimental conditions of 13% $CO_2$ concentration, 10 SLPM flow rate and 2.2 atm adsorption pressure.

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Properties of non-cement mortars with small addition of alkali activator using fly ash and fused waste slag (석탄회 및 용융폐기물 슬래그에 소량의 알칼리 활성화제를 첨가한 무시멘트 모르타르의 특성)

  • Kim, Yootaek;Lee, Kyongwoo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.6
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    • pp.257-262
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    • 2015
  • Recently the world wide efforts reduce occurrence of $CO_2$; global warming main reason. The aim of this study is to improve recycling rate of the fly ash (FA) and fused waste slag (FWS) from the power plant and to carbonate under supercritical condition ($40^{\circ}C$, $80kgf/cm^2$ pressure, 60 min) for $CO_2$ fixation. Specimens of mortar with various mixing ratios of FA, FWS (from 100:0 to 20:80 in 5 steps of 20 % reduction each time), distilled water and 3 M NaOH alkali activators were prepared. As a result, the proportion of weight change ratio increases with CaO content, to 12 % after carbonation under the supercritical condition. There is difference of compressive strength between the carbonated and the alkali activator mortar specimens. The stabilization of $CO_2$ fixation through carbonation which could confirm the applicability of the eco-friendly materials without loss of compressive strength.

Use of Flue Gas Desulfurization Gypsum as an Activator for a Ground Granulated Blast Furnace Slag (고로슬래그 자극재로써 건식 및 습식 배연탈황석고의 활용가능성 평가)

  • Lee, Hyun-Suk;Kim, Ji-Hyun;Lee, Jae-Yong;Chung, Chul-Woo
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.4
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    • pp.313-320
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    • 2017
  • Flue gas desulfurization gypsum(FDG) is produced when removing sulfur oxides from combustion gas generated by coal power plant. However, the recycling of FDG is still limited to the certain purposes. In order to expand the possible application of FDG, this study aims to utilize FDG as an activator for ground granulated blast furnace slag. FDG produced by dry- and wet-process were used for the experiments. Slag paste specimens were produced by mixing with deionized water and simulated pore solution, and the role of FDG as an activator for blast furnace slag was evaluated using hydration study by XRD analysis and compressive strength development. According to the results, dry-type FDG was found to work as an activator for blast furnace slag without the presence of soluble alkalis. However, wet-type FDG needs assistance by soluble alkalis in order to work as an activator for blast furnace slag. It was also found that the substitution of dry- and wet-type FDG into blast furnace slag can increase the 28 day compressive strength of slag paste. It is expected that efficient and economical recycling of FDG will be possible if quantitative analysis of strength enhancement according to substitution rate of both dry- and wet-type FDG.

Experimental study on the characteristics of Vacuum residue gasification in an entrained-flow gasifier (습식 분류상 가스화장치를 이용한 중질잔사유(Vacuum residue)의 가스화 특성연구)

  • ;;;;;;;A. Renevier
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2002.11a
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    • pp.171-184
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    • 2002
  • Approx. 200,000 bpd vacuum residue oil is produced from oil refineries in Korea. These are supplying to use asphalt, high sulfur fuel oil, and upgrading at the residue hydro-desulfurization unit. Vacuum residue oil has high energy content, however high sulfur content and high concentration of heavy metals represent improper low grade fuel. To meet growing demand for effective utilization of vacuum residue oil from refineries, recently some of the oil refinery industries in Korea, such as SK oil refinery and LG Caltex refinery, have already proceeded feasibility study to construct 435-500 MWe IGCC power plant and hydrogen production facilities. Recently, KIER(Korea Institute of Energy Research) are studing on the Vacuum Residue gasification process using an oxygen-blown entrained-flow gasifier. The experiment runs were evaluated under the reaction temperature : 1,100~1,25$0^{\circ}C$, reaction pressure : 1~6kg/$\textrm{cm}^2$G, oxygen/V.R ratio : 0.8~0.9 and steam/V.R ratio : 0.4-0.5. Experimental results show the syngas composition(CO+H$_2$) : 85~93%, syngas flow rate : 50~110Mm$^3$/hr, heating value : 2,300~3,000 ㎉/Nm$^3$, carbon conversion : 65~92, cold gas efficiency : 60~70%. Also equilibrium modeling was used to predict the vacuum residue gasification process and the predicted values were compared reasonably well with experimental data.

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Experimental Study on the Characteristics of Vacuum Residue Gasification in an Entrained-flow Gasifier (습식 분류상 가스화장치를 이용한 중질잔사유(Vacuum Residue)의 가스화 특성연구)

  • ;;;;;;;A. Renevier
    • Journal of Energy Engineering
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    • v.12 no.1
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    • pp.49-57
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    • 2003
  • Approx. 200.000 bpd vacuum residue oil is produced from oil refineries in Korea, and is supplied to use asphalt, high sulfur fuel oil and for upgrading at the residue hydro-desulfurization unit. Vacuum residue oil has high energy content, however its high sulfur content and high concentration of heavy metals represent improper low grade fuel. To meet growing demand for effective utilization of vacuum residue oil from refineries, recently some of the oil refinery industries in Korea, such as SK oil refinery and LG Caltex refinery, have already proceeded feasibility study to construct 435~500 MWe IGCC power plant and hydrogen production facilities. Recently, KIER (Korea Institute of Energy Research) are studying on the Vacuum Residue gasification process using an oxygen-blown entrained-flow gasifier. The experiment runs were evaluated under the reaction temperature: 1.100~l,25$0^{\circ}C$, reaction pressure: 1~6 kg/$\textrm{cm}^2$G, oxygen/V.R ratio: 0.8~0.9 and steam/V.R ratio: 0.4~0.5. Experimental results show the syngas composition (CO+H$_2$): 85~93%, syngas flow rate: 50~l10 Nm$^3$/hr, heating value: 2,300~3,000 k㎈/Nm$^3$, carbon conversion: 65~92, cold gas efficiency: 60~70%. Also equilibrium modeling was used to predict the vacuum residue gasification process and the predicted values were compared reasonably well with experimental data.

Probe Study on the Failure Factors of Venture Companies (벤처기업의 부실요인에 대한 탐색적 연구)

  • Lee, Hoon;Hong, Jae-Bum
    • Asia-Pacific Journal of Business Venturing and Entrepreneurship
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    • v.12 no.1
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    • pp.25-31
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    • 2017
  • The objective of this study is to find the failure factors of venture companies. We analyze 210 troubled venture companies, all of which have been under guarantee from the Korea Technology Finance Corporation over the last three years. Methods of analysis for failure factors are as follows. First, we categorize the failure factors into the four different types based on growth and profitability indicators in the financial statements of targeted venture companies. Then we analyzed the failure factors of the subject companies based on the troubled guarantee reports made by the Korea Technology Finance Corporation. If a venture company under its guarantee program falls into insolvency, the Korea Technology Finance Corporation make the troubled guarantee report to find out the failure factors and evaluate the recovery potentials. We identify 374 failure factors of venture companies through the analysis. The most prominent among them are deteriorating of business environments (79 factors) and decreasing or withdrawing orders from major suppliers (54 factors) due to bankruptcies or change in business plans. They are followed by slowing collection of accounts receivable (31 factors), dropping or frozen product price (24 factors) due to intensifying competition and escalating pressures from major suppliers, rising raw material costs both at home and abroad (21 factors). In addition, the nuclear power plant disaster in Japan, shut-down of the Kaesong Industrial Complex and subsequent lawsuits, delay in technology development projects, high cost-low efficiency management structure, etc., are also revealed as new factors causing trouble for venture companies.

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Studies on the Production of Artificial Zeolite from Coal Fly Ash and Its Utilization in Agro-Environment

  • Lee, Deog-Bae;Henmi, Teruo;Lee, Kyung-Bo;Kim, Jae-Duk
    • Korean Journal of Environmental Agriculture
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    • v.19 no.5
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    • pp.401-418
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    • 2000
  • 1. Production of the artificial zeolite from coal ash Coal fly ash is mainly composed of several oxides including $SiO_2$ and $Al_2O_3$ derived from inorganic compounds remained after burning. As minor components, $Fe_2O_3$ and oxides of Mg, Ca, P, Ti (trace) are also contained in the ash. These components are presented as glass form resulting from fusion in the process of the combustion of coal. In other word, coal ash may refer to a kind of aluminosilicate glass that is known to easily change to zeolite-like materials by hydrothermal reaction. Lots of hot seawater is disposing near thermal power plants after cooling turbine generator periodically. Using seawater in the hydrothermal reaction caused to produce low price artificial zeolite by reduction of sodium hydroxide consumption, heating energy and water cost. As coal ash were reacted hydrothermally, peaks of quartz and mullite in the ash were weakened and disappeared, and new Na-Pl peaks were appeared strengthily. Si-O-Si bonding of the bituminous coal ash was changed to Si-O-Al (and $Fe^{3+}$) bonding by the reaction. Therefore the produced Na-Pl type zeolite had high CEC of 276.7 $cmol^+{\cdot}kg^{-1}$ and well developed molecular sieve structure with low concentration of heavy metals. 2. Utilization of the artificial zeolite in agro-environment The artificial zeolite(1g) could remove 123.5 mg of zinc, 164.7 mg copper, 184.4 mg cadmium and 350.6 mg lead in the synthetic wastewater. The removability is higher 2.8 times in zinc, 3.3 times in copper, 4.7 times in cadmium and 4.8 times in lead than natural zeolite and charcoal powder. When the heavy metals were treated at the ratio of 150 $kg{\cdot}ha^{-1}$ to the rice plant, various growth inhibition were observed; brownish discoloration and death of leaf sheath, growth inhibition in culm length, number of panicles and grains, grain ripening and rice yield. But these growth inhibition was greatly alleviated by the application of artificial zeolite, therefore, rice yield increased $1.1{\sim}3.2$ times according to the metal kind. In addition, the concentration of heavy metals in the brown rice also lowered by $27{\sim}75%$. Artificial Granular Zeolites (AGZ) was developed for the purification of wastewater. Canon exchange capacity was 126.8 $cmol^+{\cdot}kg^{-1}$. AGZ had Na-Pl peaks mainly with some minor $C_3S$ peaks in X-ray diffractogram. In addition, AGZs had various pore structure that may be adhere the suspended solid and offer microbiological niche to decompose organic pollutants. AGZ could remove ammonium, orthophosphate and heavy metals simultaneously. Mixing ratio of artificial zeolite in AGZs was related positively with removal efficiency of $NH_4\;^+$ and negatively with that of $PO_4\;^{3-}$. Root growth of rice seedling was inhibited severely in the mine wastewater because of strong acidity and high concentration of heavy metals. As AGZ(1 kg) stayed in the wastewater(100L) for 4days, water quality turned into safely for agricultural usage and rice seedlings grew normally.

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Numerical Analysis of CO2 Behavior in the Subsea Pipeline, Topside and Wellbore With Reservoir Pressure Increase over the Injection Period (시간 경과에 따른 저류층 압력 상승이 파이프라인, 탑사이드 및 주입정 내 CO2 거동에 미치는 영향에 대한 수치해석적 연구)

  • Min, Il Hong;Huh, Cheol;Choe, Yun Seon;Kim, Hyeon Uk;Cho, Meang Ik;Kang, Seong Gil
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.19 no.4
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    • pp.286-296
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    • 2016
  • Offshore CCS technology is to transport and inject $CO_2$ which is captured from the power plant into the saline aquifer or depleted oil-gas fields. The more accumulated injected $CO_2$, the higher reservoir pressure increases. The increment of reservoir pressure make a dramatic change of the operating conditions of transport and injection systems. Therefore, it is necessary to carefully analyze the effect of operating condition variations over the injection period in early design phase. The objective of this study is to simulate and analyze the $CO_2$ behavior in the transport and injection systems over the injection period. The storage reservoir is assumed to be gas field in the East Sea continental shelf. The whole systems were consisted of subsea pipeline, riser, topside and wellbore. Modeling and numerical analysis were carried out using OLGA 2014.1. During the 10 years injection period, the change of temperature, pressure and phase of $CO_2$ in subsea pipelines, riser, topside and wellbore were carefully analyzed. Finally, some design guidelines about compressor at inlet of subsea pipeline, heat exchanger on topside and wellhead control were proposed.

Verification of MCNP/ORIGEN-2 Model and Preliminary Radiation Source Term Evaluation of Wolsung Unit 1 (월성 1호기 MCNP/ORIGEN-2 모델 검증 및 예비 선원항 계산)

  • Noh, Kyoungho;Hah, Chang Joo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.13 no.1
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    • pp.21-34
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    • 2015
  • Source term analysis should be carried out to prepare the decommissioning of the nuclear power plant. In the planning phase of decommissioning, the classification of decommissioning wastes and the cost evaluation are performed based on the results of source term analysis. In this study, the verification of MCNP/ORIGEN-2 model is carried out for preliminary source term calculation for Wolsung Unit 1. The inventories of actinide nuclides and fission products in fuel bundles with different burn-up were obtained by the depletion calculation of MCNPX code modelling the single channel. Two factors affecting the accuracy of source terms were investigated. First, the neutron spectrum effect on neutron induced activation calculation was reflected in one-group microscopic cross-sections of relevant radio-isotopes using the results of MCNP simulation, and the activation source terms calculated by ORIGEN-2 using the neutron spectrum corrected library were compared with the results of the original ORIGEN-2 library (CANDUNAU.LIB) in ORIGEN-2 code package. Second, operation history effect on activation calculation was also investigated. The source terms on both pressure tubes and calandria tubes replaced in 2010 and calandria tank were evaluated using MCNP/ORIGEN-2 with the neutron spectrum corrected library if the decommissioning wastes can be classified as a low level waste.