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Effect of KOH Concentrations and Pyrolysis Temperatures for Enhancing NH4-N Adsorption Capacity of Rice Hull Activated Biochar (KOH 농도 및 탄화온도가 왕겨 활성 바이오차의 NH4-N 흡착능 향상에 미치는 영향)

  • Kim, HuiSeon;Yun, Seok-In;An, NanHee;Shin, JoungDu
    • Korean Journal of Environmental Agriculture
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    • v.39 no.3
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    • pp.171-177
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    • 2020
  • BACKGROUND: Recently, biomass conversion from agricultural wastes to carbon-rich materials such as biochar has been recognized as a promising option to maintain or increase soil productivity, reduce nutrient losses, and mitigate greenhouse gas emissions from the agro-ecosystem. This experiment was conducted to select an optimum conditions for enhancing the NH4-N adsorption capacity of rice hull activated biochar. METHODS AND RESULTS: For deciding the proper molarity of KOH for enhancing its porosity, biochars treated with different molarity of KOH (0, 1, 2, 4, 6, 8) were carbonized at 600℃ in the reactor. The maximum adsorption capacity was 1.464 mg g-1, and an optimum molarity was selected to be 6 M KOH. For the effect of adsorption capacity to different carbonized temperatures, 6 M KOH-treated biochar was carbonized at 600℃ and 800℃ under the pyrolysis system. The result has shown that the maximum adsorption capacity was 1.76 mg g-1 in the rice hull activated biochar treated with 6 M KOH at 600℃ of pyrolysis temperature, while its non-treated biochar was 1.17 mg g-1. The adsorption rate in the rice hull activated biochar treated with 6 M KOH at 600℃ was increased at 62.18% compared to that of the control. Adsorption of NH4-N in the rice hull activated biochar was well suited for the Langmuir model because it was observed that dimensionless constant (RL) was 0.97 and 0.66 at 600℃ and 800℃ of pyrolysis temperatures, respectively. The maximum adsorption amount (qm) and the bond strength constants (b) were 0.092 mg g-1 and 0.001 mg L-1, respectively, for the rice hull activated biochar treated with 6 M KOH at 600℃ of pyrolysis. CONCLUSION: Optimum condition of rice hull activated biochar was 6M KOH at 600℃ of pyrolysis temperature.

Growth Characteristics of Ginseng Seedlings as Affected by Mixed Nursery Soil under Polyethylene Film Covered Greenhouse (비닐하우스에서 상토의 조성에 따른 묘삼의 생장특성)

  • Park, Hong Woo;Jang, In Bae;Kim, Young Chang;Mo, Hwang Sung;Park, Kee Choon;Yu, Jin;Kim, Jang Uk;Lee, Eung Ho;Kim, Ki Hong;Hyun, Dong Yun
    • Korean Journal of Medicinal Crop Science
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    • v.22 no.5
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    • pp.363-368
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    • 2014
  • This study was conducted to find out the optimum composition of nursery soil for raising seedling of ginseng (Panax ginseng C. A. Meyer). Total 9 kinds of raw materials were used such as peat-moss, perlite, leaf mould, rice bran, gull's guano, castor-oil plant bark, palm bark, cow manure and chicken manure for optimum composition of nursery soil in ginseng. Occurrence of damping-off in ginseng was lowered about 50% in nursery soil type 1, 2 and 4 than in other types nursery soil in June, and occurrence rate of rusty root also lowest in nursery soil type 1. As the salinity of nursery soil increased, so did the occurrence of physiological disorder in ginseng seedling. The cause of salinity increasing in nursery soil has closely relation to $NO_3-N$, $P_2O_5$ and $Na^+$ content. Plant height, root length, diameter and weight were longer and heavier in nursery soil type 1 (mixing ratio of peat-moss, perlite and leaf mould was 50 : 20 : 30 based in volume) than in other types of nursery soil. So nursery soil type 1 was selected for raising seedling of ginseng. pH and electric conductivity (EC) of selected nursery soil type 1 was 5.55 and 0.13 dS/m. Contents of $NO_3-N$ and $P_2O_5$ were 21.0 and 40.0 mg/L, and $K^+$ 0.36, $Ca^{2+}$ 3.38, $Mg^{2+}$ 2.01 and $Na^+$ $0.09cmol^+/L$, respectively.

Effect of Bordeaux Mixture on Control of Rice Leaf Blast (벼 유기재배에서 석회보르도액을 이용한 벼 잎도열병 방제 효과)

  • Kang, Beom-Ryong;Kim, Seon-Gon;Kim, Do-Ik;Lee, Yong-Hwan;Choi, Kyong-Ju;Choi, Yong-Soo
    • Research in Plant Disease
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    • v.14 no.3
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    • pp.182-186
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    • 2008
  • Recently organic farming practice of rice has been emerged in Korea, but one of the major limiting factor is the no effective environmental-friendly agro-materials to control major plant diseases. Bordeaux mixture has been used effectively as a preventive agro-chemical. The aim of this study was to investigate efficacy of Bordeanux mixture on control of rice blast caused by Magnaporthe grisea which is one of the disruptive rice diseases in world-wide. In greenhouse experiment, pre-treatment of 6-6 type of Bordeaux mixture before inoculation of spore suspension of M. grasea showed 71 % of control value. In field experiment, preventive applications of 4-8 and 6-6 types of Bordeaux mixture showed over 71 % of the control value. Chemical injury on rice leaves were not found in the application concentrations of all types of Bordeaux mixture, but observed in applications of Bordeaux mixtures between 30 and 100 diluted concentrations. This results indicate Bordeaux mixture can be used as an effective environmental-friendly agro-chemical to control rice blast disease in the field.

Characteristics of Stormwater Runoff discharged from vinyl greenhouse growing area in farming area (농촌의 비닐하우스 재배지역에서 배출되는 강우유출수의 특성)

  • Jeon, Je Chan;Lee, Sang Hyeub;Kwon, Koo Ho;Lee, Jea Woon;Kwon, Heun Gag;Min, Kyung Sok
    • Journal of Wetlands Research
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    • v.16 no.4
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    • pp.413-422
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    • 2014
  • In national water quality policy, it changed previous regulation method that focuses on concentration of pollutants in effluent water to the way that regulates total amount of pollutants. The target of water quality in watershed of each river was set up, as the government instituted Total Maximum Daily Loads(TMDL). In order to accomplish successfully TMDL, it requires that the amount of pollutant loads discharged from point and nonpoint pollutant source should be investigated. This study, therefore, conducted the monitoring of the stormwater runoff at field region in farming area. And pollutants loads and unit loads discharged from field region results is calculated. As a result, the concentration of pollutants were calculated as follows: 10.5 BOD mg/L, 19.6 $COD_{Mn}$ mg/L, 4.5 TN mg/L and 2.4 TP mg/L. The unit load of BOD, $COD_{Mn}$, TOC, TSS, TN and TP discharged from field region, also, were determined to $31.8kg/km^2/yr$, $56.7kg/km^2/yr$, $8.5kg/km^2/yr$, $560.9kg/km^2/yr$, $8.3kg/km^2/yr$ and $5.1kg/km^2/yr$, respectively. It was identified that there were some differences of unit loads between the results obtained from this study and previous one. To calculate exact unit loads, therefore, long term monitoring should be conducted.

Analysis of the Impact of Initial Carbon Emission Permits Allocation on Economic Growth (초기 탄소배출권 배분이 경제성장에 미치는 영향 분석)

  • Park, Sunyoung;Kim, Dong Koo
    • Environmental and Resource Economics Review
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    • v.20 no.2
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    • pp.167-198
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    • 2011
  • The Korean government recently announced greenhouse gases (GHG) emissions reduction target as 30% of 2020 business as usual (BAU) emission projection. As carbon emissions trading is widely used to achieve reductions in the emissions of pollutants, this study deals with the sectoral allocation of initial carbon emission permits in Korea. This research tests the effectiveness of a variety of allocation rules based on the bankruptcy problem in cooperative game theory and hybrid input-output tables which combines environmental statistics with input-output tables. The impact of initial emission permits allocation on economic growth is also analyzed through green growth accounting. According to the analysis result, annual GDP growth rate of Korea is expected to be 4.03%, 4.23%, and 3.67% under Proportional, Constrained Equal Awards, and Constrained Equal Losses rules, respectively. These rates are approximately from 0.69% points to 0.13% points lower than the growth rate of 4.36% without compulsory $CO_2$ reduction. Thus, CEA rule is the most favorable in terms of GDP growth. This study confirms the importance of industry level study on the carbon reduction plan and initial carbon emission permits should reflect the characteristic of each industry.

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A Study on the impact of the changes in international emissions trade market on non-CO2 CDM projects (국제 배출권 거래 시장의 제도변화가 국내 비(非)CO2 CDM 사업에 미치는 영향 분석)

  • Lee, Eungkyoon;Hwang, Minsup;Lee, Myung-Kyoon
    • Environmental and Resource Economics Review
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    • v.23 no.2
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    • pp.157-185
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    • 2014
  • The Kyoto Protocol has extended its life until 2020 by the decision at COP18 in Doha, Qatar in 2012. So has the Kyoto Mechanism of CDM, JI, and ETS. Nonetheless, the sustainability of CDM projects is jeopardized by the recent rule changes in the international emissions trade market such as EU ETS and the price decrease in emission credits. In particular, the domestic CDM projects reducing non-$CO_2$ GHG emissions are being directly affected. This study examines the trend of carbon credit price change in the international market. It also examines how the rule changes in the international emissions trade market have affected domestic non-$CO_2$ CDM projects through which mechanisms. The policy implications drawn from this study is two-fold: it suggests how the government can assist the project developers in utilizing GHG emission reduction technologies and the market in promoting investment environment before the domestic ETS enters into effect in 2015; apart from possible measures within ETS, an additional measures such as bilateral carbon offset system is suggested to help the private sector reduce uncertainty in investment and increase options to choose.

An Empirical Analysis of the Effect of Energy Saving Investment on the Improvement of Energy Intensity in Korean Manufacturing (한국 제조업에 대한 에너지절약 투자의 에너지 원단위 개선효과 분석)

  • Park, Changsuh;Yoo, Dongheon
    • Environmental and Resource Economics Review
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    • v.16 no.3
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    • pp.485-510
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    • 2007
  • The purpose of this paper is to empirically analyze the economic effect of energy saving investment on the improvement of energy intensity. The data used in this paper are panel data, both time-series and cross-section data. In addition, eight manufacturing sectors has been divided into two groups: massive energy consuming (four industries) and non-massive energy consuming (four industries) ones and the time period of analysis is from 1982 to 2004. According to the empirical results, firstly, energy saving investment has a negative relationship with energy intensity, however, its effect is not high in terms of absolute volume of energy consuming. Secondly, in improving energy intensity of energy saving investment, its elasticity IS higher in non-massive energy consuming sector compared it with massive energy consuming sector. Thirdly, automation investment is also playing an important role in energy conservation. The elasticities of automation investment to energy intensity are larger than those of energy saving investment. In terms of the reduction of greenhouse gas per investment unit cost, however, energy saving investment has larger effect than automation investment.

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Estimation of the Shadow Price of Carbon Dioxide Emissions, the Potential Reduction, and Substitution Possibility for fuels in the Chinese Fossil-fueled Power Generation Sector (중국 화력발전산업의 CO2 암묵가격 및 잠재감축량, 연료에 대한 대체가능성 분석)

  • Jin, Yingmei;Lee, Myunghun
    • Environmental and Resource Economics Review
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    • v.22 no.1
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    • pp.77-98
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    • 2013
  • China, the world's largest $CO_2$ producer, is likely to be obligated to reduce greenhouse gas emissions under the post-Kyoto protocol. This paper estimates a Shephard input distance function for the Chinese fossil-fueled power generation sector to measure the shadow price of $CO_2$ emissions, technical efficiency, and indirect Morishima elasticities of substitution between inputs. Empirical results show that, on average, it costs approximately 3.2 US dollars per year to reduce $CO_2$ emissions by one ton over the period 1981-2009. This finding indicates that Chinese power sector is expected to benefit from selling emission permits to other countries such as Korea and Japan, given that our estimate for China is lower than the ones previous literatures estimated for the power sector in these countries. The maximum attainable average $CO_2$ reduction potential amounts to approximately 25 million tons per year by improving technical efficiency. Capital is substitutable with both coal and oil and capital is relatively more readily substituted for these fuels.

Impact Assessment of Forest Development on Net Primary Production using Satellite Image Spatial-temporal Fusion and CASA-Model (위성영상 시공간 융합과 CASA 모형을 활용한 산지 개발사업의 식생 순일차생산량에 대한 영향 평가)

  • Jin, Yi-Hua;Zhu, Jing-Rong;Sung, Sun-Yong;Lee, Dong-Ku
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.20 no.4
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    • pp.29-42
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    • 2017
  • As the "Guidelines for GHG Environmental Assessment" was revised, it pointed out that the developers should evaluate GHG sequestration and storage of the developing site. However, the current guidelines only taking into account the quantitative reduction lost within the development site, and did not consider the qualitative decrease in the carbon sequestration capacity of forest edge produced by developments. In order to assess the quantitative and qualitative effects of vegetation carbon uptake, the CASA-NPP model and satellite image spatial-temporal fusion were used to estimate the annual net primary production in 2005 and 2015. The development projects between 2006 and 2014 were examined for evaluate quantitative changes in development site and qualitative changes in surroundings by development types. The RMSE value of the satellite image fusion results is less than 0.1 and approaches 0, and the correlation coefficient is more than 0.6, which shows relatively high prediction accuracy. The NPP estimation results range from 0 to $1335.53g\;C/m^2$ year before development and from 0 to $1333.77g\;C/m^2$ year after development. As a result of analyzing NPP reduction amount within the development area by type of forest development, the difference is not significant by type of development but it shows the lowest change in the sports facilities development. It was also found that the vegetation was most affected by the edge vegetation of industrial development. This suggests that the industrial development causes additional development in the surrounding area and indirectly influences the carbon sequestration function of edge vegetaion due to the increase of the edge and influx of disturbed species. The NPP calculation method and results presented in this study can be applied to quantitative and qualitative impact assessment of before and after development, and it can be applied to policies related to greenhouse gas in environmental impact assessment.

Growth and Development of 'Gutbier V-10 Amy' Poinsettia (Euphorbia pulcherrima Willd.) as Affected by Application of Waste Nutrient Solution (폐양액 시비에 따른 포인세티아 생육)

  • Kim, Ju-Hyoung;Kim, Tae-Joung;Kim, Hag-Hyun;Lee, Hee-Doo;Lee, Jong-Won;Lee, Cheol-Hee;Paek, Kee-Yoeup
    • Horticultural Science & Technology
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    • v.18 no.4
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    • pp.518-522
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    • 2000
  • The objective of this research was to determine the effect of waste nutrient solution (WNS) on growth and development of poinsettia 'Gutbier V-10 Amy'. To achieve this, WNS collected from rose grown in greenhouse was diluted with various times and 500 mL of each solution was applied every week. Then growth characteristics and nutrient uptake were determined at 180 days after transplanting. The treatment of undiluted WNS had highest plant height and length of branch among treatments tested, but there were no statistical differences in the number of bract and branches. Undiluted WNS had higher leaf number, leaf length, leaf width, fresh weight, and dry weight than any other treatments tested. There was also a trend that increased dilution times of WNS resulted in decreased plant growth. Undiluted WNS had higher chlorophyll content than Hyponex treatment, but diameter of crown did not show significant differences among treatments. In the analysis of root media collected at 6 months after fertilization, the treatment of undiluted WNS had higher electrical conductivity and organic matter content than other treatments, but the Hyponex treatment had higher phosphorus concentration than other treatments tested.

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