• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2004년도 춘계학술대회 논문집
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• pp.265-268
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• 2004

In this present study, mechanical properties of the Zr-Ti-Cu-Ni-Be bulk metallic glass are characterized by compression test over a wide range of temperatures and strain rates. Three different types of deformation behavior have been identified as a result, viz., Newtonian viscous flow, non-Newtonian flow and brittle fracture without plastic deformation. A transition state theory is applicable fur the flow stress - strain rate curve that contains the transition from Newtonian to non-Newtonian flow. Based on the relationship between viscosity and strain rate within undercooled liquid state, we can easily obtain the experimental deformation map and suggest the boundaries among different deformation behavior of this alloy.

• 한국재료학회지
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• 제19권9호
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• pp.504-509
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• 2009

The Zr-based bulk metallic glass matrix composites of a mixture of gas-atomized metallic glass powders and Fe-based nanostructured powders were fabricated by spark plasma sintering. The Fe-based nanostructured powders adopted for the enhancement of plasticity were well distributed in the matrix after consolidation, and the matrix remains as a fully amorphous phase. The successful consolidation of metallic glass matrix composite with high density was attributed to viscous flow in the supercooled liquid state during spark plasma sintering. Unlike other amorphous matrix composites, in which improved ductility could be obtained at the expense of their strength, the developed composite exhibited improvement both in strength and ductility. The ductility improvement in the composite was considered to be due to the formation of multiple shear bands under the presence of the Fe-based nanostructured particles.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2007년도 춘계학술대회 논문집
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• pp.123-126
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• 2007

Deformation behavior of $Zr_{55}Cu_{30}Al_{10}Ni_5$ (at. %) bulk metallic glass (BMG) fabricated by suction casting method has been investigated at elevated temperatures in this study. The BMG was first verified to have an amorphous structure thru X-ray diffraction (XRD) and differential scanning calorimetry (DSC). A series of compression tests has consequently been performed in supercooled liquid temperature region to investigate the high temperature deformation behavior. A transition from Newtonian to non-Newtonian flow appeared to take place depending upon both the strain rate and test temperature. A processing map based on a dynamic materials model has been constructed to estimate a feasible forming condition for this BMG alloy.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2004년도 추계학술대회논문집
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• pp.199-202
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• 2004

In this present study, an attempt was made to determine the deformation mode of the Zr-Ti-Cu-Ni-Be bulk metallic glass by compression test over a wide range of temperatures and strain rates. From the results, empirical deformation map could be constructed including the boundaries of different deformation modes. Considering power dissipation map and instability map developed on the basis of the Dynamic Materials Model (DMM), the processing map for extrusion could also be constructed. In addition, the macroscopic formability of this BMG alloy has also been examined through the extrusion in laboratory scale within undercooled liquid state. From the results of macroscopic extrusion formability, both deformation map and processing map present good criteria to determine optimal forming conditions.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2009년도 춘계학술대회 논문집
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• pp.353-354
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• 2009

Tensile deformation behavior with different strain rate was investigated. $Zr_{56.2}Ti_{13.8}Nb_{5.0}Cu_{6.9}Ni_{5.6}Be_{12.5}$ (bulk metallic glass alloy possessed crystal phase which was called $\beta$-phase of dendrite shape, mean size of $20{\sim}30{\mu}m$ and occupied 25% of the total volume) was used in this study. Maximum tensile strength was obtained as 1.74Gpa at strain rate of $10^2/s$ and minimum strength was found to be 1.6GPa at $10^{-1}/s$. And then, maximum plastic deformation occurred at the strain rate of $5{\times}10^{-2}/s$ and represented 1.75%, though minimum plastic deformation showed 0%. In the specific range of strain rate, relatively higher plastic deformation and lower ultimate tensile strength were found with lots of shear bands. The fractographical observation after tensile test indicated that vein like pattern on the fracture surface was well developed especially in the above range of strain rate.

• 한국주조공학회지
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• 제30권3호
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• pp.94-99
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• 2010

When the returned scrap of bulk amorphous alloy is remelted, impurities such as oxides and intermetallic compounds increase. Glass forming ability of its scrap is deteriorated remarkably. Melt fluxing technique is introduced to enhance the glass forming ability during melting and freezing of bulk amorphous alloys. Cu and Zr based alloys are chosen. Small pieces of these alloy scraps and $B_2O_3$ flux are put together in a quartz tube. Cyclic heating and cooling are done by induction heating and water quenching or air cooling. Melting fluxing was effective for both Cu-based and Zr-based alloy, and their glass forming abilities were improved with increasing the number of fluxing.

• 소성∙가공
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• 제16권4호
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• pp.309-312
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• 2007

Deformation behavior of $Zr_{55}Cu_{30}Al_{10}Ni_5$(at. %) bulk metallic glass(BMG) fabricated by suction casting method has been investigated at elevated temperatures in this study. The BMG was first verified to have an amorphous structure with the analysis of X-ray diffraction(XRD) and differential scanning calorimetry(DSC) data. A series of compression tests has consequently been performed in the region of supercooled liquid temperature to investigate the behavior of high temperature deformation. A transition from Newtonian to non-Newtonian flow appeared to take place depending upon both the strain rate and test temperature. A processing map based on a dynamic materials model has been constructed to estimate a feasible forming condition for this BMG alloy.

• 소성∙가공
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• 제18권6호
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• pp.500-507
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• 2009

Tensile deformation behavior with different strain rate was investigated. $Zr_{56.2}Ti_{13.8}Nb_{5.0}Cu_{6.9}Ni_{5.6}Be_{12.5}$(bulk metallic glass alloy possessed crystal phase which was called $\beta$-phase of dendrite shape, mean size of $20{\sim}30{\mu}m$ and occupied 25% of the total volume) was used in this study. Maximum tensile strength was obtained as 1.74GPa at strain rate $10^2s^{-1}$ and minimum strength was found to be 1.6GPa at $10^{-1}s^{-1}$. And then, maximum plastic deformation occurred at the strain rate of $5{\times}10^{-2}s^{-1}$ and represented 1.75%, though minimum plastic deformation showed 0%. In the specific range of strain rate, relatively higher plastic deformation and lower ultimate tensile strength were found with lots of shear bands. The fractographical observation after tensile test indicated that vein like pattern on the fracture surface was well developed especially in the above range of strain rate.

• 한국주조공학회지
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• 제32권4호
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• pp.177-180
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• 2012

Ti-based bulk metallic glasses with high glass forming ability were developed through a systematic alloy design technique. The main alloy design strategy was the selection of alloying elements that may not be toxic in the human body. The $Ti_{45.0}Cu_{40.1}Zr_{12.7}Si_{2.2}$ alloy could be cast into an amorphous rod with the diameter of 3 mm by a suction casting technique using Cu mold. The compressive strength of the amorphous rod was measured as 1826 MPa. Since the Ti-based amorphous alloys consist of non-toxic elements, they can be widely used as bio-materials and eco-materials with unique and beneficial properties.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2009년도 춘계학술대회 논문집
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• pp.64-67
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• 2009

Vibrational micro-forming of pyramidal shape patterns was conducted for an Al superplastic alloy, Al 5083 and a Zr-based bulk metallic glass, $Zr_{62}Cu_{17}Ni_{13}Al_8$. A vibrational micro-forming system was specially designed for generating vibrational load by combining a PZT actuator with a signal generator. Single crystal Si micro dies with wet-etched pyramidal patterns were used as master dies for vibrational micro-forming. The micro-formed pattern height was increasing with increasing the frequency of the vibrational load. In particular, the vibrationally-microformed pattern height was similar or even higher than the statically-microformed pattern height when the load frequency exceeded about 125 kHz. It was also observed that the crystal grains affect the surface quality of the microformed pattern and the distribution of the pattern height in the die cavity array.