• Journal of the Korean Chemical Society
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• v.27 no.4
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• pp.273-278
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• 1983

With the synthetic standards, valuable metals $(Ta_2O_5, Nb_2O_5, TiO_2, SnO_2$, and $ZrO_2$) in the tin slags have been determined by the x-ray fluorescence spectrometry. The powder sample and the standards are homogeneously mixed with anhydrous $Li_2B_4O_7$ and La_2O_3$ in weight ratio of 15 : 42 : 3 respectively. The mixed material is fused at $1,150^{\circ}C$ for 30 minutes to be changed into the glass bead. The bead is ground to (-) 325 mesh size and pelletized. The analytical results obtained in this work are consistent with the data obtained by other common methods within allowable error range. The standard deviation for $Ta_2O_5$ in PTS-H sample is 0.12 % at level of 3.40 % content.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1994.11a
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• pp.13-16
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• 1994

In this paper, xPb(Zn$_{1/3}Nb_{2/3}$)$O_3$-yPbTiO$_3$-zPbZrO$_3$-(0.5wt%)MnO$_2$ ceramics were fabricated by the mixed oxide method sintered at $1250^{\circ}C$ for 2[hr] and then the deielectric, electromechanical coupling factor($K_{p}$ and mechanical coupling factor(Qm) properties were investigated. In 0.1PZN-0.45PT-0.45PZsample, dielectric properties and electromechanical coupling factor were 829 and 29%. In the case of 0.5PZN-0.45PT-0.50PZ sample, that was 101 according to mechanical quality facotr. molphotropic phase boundary(MPB) certained area which $PbTiO_3$addition quatity 40∼50[㏖%].

• Journal of the Korean Chemical Society
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• v.28 no.5
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• pp.293-301
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• 1984

-ray fluorescence analysis of $Ta_2O_5$, $Nb_2O_5$ and $ZrO_2$ in tin-slag samples using the simple dilution method was studied. The method is to correct mathematically the calibration curve to the linear line by the dilution. One synthesized standard having similar composition to the sample and tin slag samples were diluted with anhydrous $Li_2B_4O_7$ at the level of 1%, 2% and 3% of the sample content respectively. The diluted samples were fused at $1150^{\circ}C$ for 30 minutes and these glass beads were finely ground and pelletized. Measuring the X-ray intensities with these pellets, analytical results were calculated by the equation derived from J. Scherman's equation for the characteristic X-ray intensity of an element. Analytical results agreed with the reference values obtained by the standard calibration method within allowable error range and were reproducible.

• Journal of the Korean Chemical Society
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• v.29 no.3
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• pp.265-270
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• 1985

Ta$_2$O$_5$, Nb$_2$O$_5$, SnO$_2$ and ZrO$_2$ in tin-slag samples were determined by X-ray fluorescence spectrometry using the dilution parameter method and the analytical results were compared with the data obtained by standard calibration curve method. Tin-slag samples and one standard sample having very similar composition to the tin-slags were diluted with a proper diluent (La$_2$O$_3$) to the ratio of 1: 1, 1 : 2, 1 : 3 and 1 : 4. After measuring the X-ray intensities of original and diluted samples, the values of dilution parameters were calculated by using the dilution parameter equation. Without any calibration curve, the analytical results were calculated from the equation including the dilution parameter term. The results were in good agreement with the reference data by the standard calibration curve method.

• Journal of the Korean Chemical Society
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• v.28 no.5
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• pp.302-308
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• 1984

X-ray spectrometric determination of $Ta_2O_54, $Nb_2O_5$ and $ZrO_2$ in tin-slag samples using the double dilution technique was conducted. Tin-slag samples and one synthesized standard sample having similar composition to the samples were diluted with anhydrous $Li_2B_4O_7$ at the level of 1.00, 2.00 and 3.00% of the sample content, respectively. The diluted samples were fused at $1,150^{\circ}C$ for 30 minutes, and these glass beads were finely ground and pelletized. With the X-ray intensities measured, analytical results were calculated by the double dilution equation. The results agreed to the reference values obtained by the standard calibration method and the simple dilution technique within allowable error range and were reproducible.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.11a
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• pp.27-28
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• 2005

본 연구에서는$Cr_2O_3$ 와 $Nb_2O_5$ 를 첨가한 $Pb(Zr_{0.54}Ti_{0.48})O_3$ 세라믹스에서 $Nb_2O_5$ 첨가량에 따른 소결 및 압전, 유전특성을 조사하였다. $Pb(Zr_{0.54}Ti_{0.48})O_3$ + 0.2 wt% $Cr_2O_3$ + wt% $Nb_2O_5$ ($0.{\sim}2wt.%$)의 첨가량에 따른 압전, 유전특성 및 미세구조에 관해 연구하였다. 본조성에서 $Nb_2O_5$ 첨가량이 증가함에 따라 입경의 크기는 증가하였으며, 0.5 wt% $Nb_2O_5$ 첨가조성에서 $4\sim5\mu m$의 최대 평균입경을 보이다가 그 이상의 첨가 조성에서 급격히 감소하였다. 유전상수와 kp 는 $Nb_2O_5$ 첨가량이 1.0 wt% 조성까지 증가하였다가 그 이상 조성에서 감소하였다. $Nb_2O_5$ 첨가량이 증가함에 따라 삼방정(rhombohedral)구조에서 정방정(tetragonal)구조로 상전이 일어났으며, 본 조성의 상경계 영역인 0.5 wt% 조성에서 $\varepsilon_r$ = 730, $k_p$ = 0.72, $d_{33}$ = 450, $g_{33}$ = 70의 우수한 압전 특성을 나타내었다. 이러한 조성은 접촉센서용 복합압전소재의 실용가능성을 제시하였다.

• Korean Journal of Materials Research
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• v.14 no.10
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• pp.713-718
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• 2004

To study the dynamic strain aging behavior of Zr-0.4Sn-1.5Nb-0.2Fe sample tube for nuclear fuel cladding in the range of pressurized water reactor (PWR) operation temperature, the tensile tests of the tube specimens, which had been finally heat-treated at $470^{\circ}C\;and\;510^{\circ}C$, had been carried out with the strain rate $1.67{\times}10^{-2}/s\;and\;8.33{\times}10^{-5}/s$ at the various temperatures from room temperature to $500^{\circ}C$. It was observed that the elongation of the specimens got shortened as the temperature increased from $200^{\circ}C\;to\;340^{\circ}C$. The specimens that were finally heat-treated at $470^{\circ}C$ showed a plateau more remarkably on the plot of yield strength-temperature than those heat-treated at $510^{\circ}C$. In the range of $310\sim400^{\circ}C$, the strain rate sensitivity of the specimens finally heat-treated at $510^{\circ}C$ was $30.4\%\sim33.7\%$ lower but the work hardening exponent index of the specimens was a little higher than that without dynamic strain aging effect.

• Journal of the Korean Ceramic Society
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• v.25 no.5
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• pp.523-531
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• 1988

The dielectric and piezoelectric properties with compositions in Pb(Ni1/3Nb2/3)O3-PbTiO3-PbZrO3-(PNN-PT-PZ)solid solution ceramics were investigated. In this study, the compsition ranges were 30 PNN 45mole%, 20 PT 50mole% and 50 PZ5mole%. As PT fraction were increased the grain size was increased and the fired density was decreased, but the changes of PNN fraction had no effect on the grain size. The Curie temperature was increased when PT and PNN fraction were increased. The displacement was increased but had a great hysteresis loss when PT fraction was increased. In morphotropic phase boundary, the maximum piezoelectric and electromechanical coupling factor were indicated. Morphotropic phase boundary(MPB) was 34 PT 36mole% in chang of compositions.

• Proceedings of the Korean Nuclear Society Conference
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• 1995.05a
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• pp.759-764
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• 1995

여러 가지 Zr합금의 부식거동을 LiOH, NaOH, KOH, RbOH, CsOH 용액조건에서 autoclave를 이용하여 조사하였다. 용액내의 알칼리 농도는 0.3mmol 4.3mmol 31.5mmo1를 선택하였는데, 이는 Li의 경우에 2.2ppm 30ppm, 220ppm에 해당되는 농도이다. Zr합금은 ZrSn-TRM(천이원소)과 ZrSnNb-TRM(천이원소)의 두 종류의 합금을 사용하였다. 알칼리 분위기에서 Zr함금의 부식을 지배하는 이온은 양이 온인 것으로 밝혀졌으며, 양이온의 반경이 Zr합금의 천이전 영역에서의 부식을 지배하는 것으로 나타났다. Nb첨가 합금은 Zircaloy형 합금보다 내식성이 떨어진다. LiOH가 부식을 가장 가속시키는 알칼리로 밝혀졌으며 CsOH나 KOH는 거의 Zr합금의 부식을 가속시키지 않는다. 따라서 CsOH나 KOH는 PWR에 적응 가능한 대체 알칼리로서 가능성을 보였다.

• Proceedings of the Korean Nuclear Society Conference
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• 1998.05b
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• pp.231-236
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• 1998

원자력 발전소의 핵연료 피복관 재료로 사용되고 있는 Zr합금의 부식특성에 미치는 Sn의 영향을 조사하기 위해 Sn 함량을 0.5, 0.8, 1.5, 2.0wt.%로 조절한 Zr-xSn 2원계 합금과 Zr-0.4Nb-xSn 3원계 합금을 제조하여 36$0^{\circ}C$ 물 분위기의 mini-autoclave에서 부식실험을 수행하였다. 2원계 합금에서 Sn이 0.5, 0.8, 1.5wt.% 첨가된 합금에서는 15일에서 속도천이가 발생한 후 급격한 부식 가속 현상이 나타났으나, 2.0wt.%가 첨가된 합금에서는 100일까지 부식 실험에서도 천이 현상을 보이지 않는 매우 높은 부식 저항성을 보였다. 그러나 3원계 합금에서는 2원계 합금과는 달리 40일 시험에서도 모든 합금들이 속도 천이 현상을 보이지 않고 천이전 영역에서의 부식 거동을 보이며, Sn 함량 변화에 따른 부식 속도의 차이를 감지할 수 없었다. 이러한 경향은 2원계 합금과 3원계 합금에서 Sn의 고용도 차, 미량 첨가된 Nb의 영향 및 석출물의 특성과 관련이 있는 것으로 사료된다. 또한 수소 흡수율면에서도 Sn 함량 변화에 따라 부식 거동과 비슷한 경향을 보이면서 2.0wt.%에서 가장 낮은 수소흡수율을 보였다 천이전 영역에서 산화막 구조 관찰 결과 천이전 영역의 모든 산화막에서 보호적 성질을 나타내는 tetragonal-ZrO$_2$가 관찰되었는데, tetragonal-ZrO$_2$의 분율은 Sn 함량에 따라 거의 같게 나타났다.