• Title/Summary/Keyword: ZnS: Cu

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Approach to the Extraction Method on Minerals of Ginseng Extract (추출조건(抽出條件)에 따른 인삼(人蔘)엑기스의 무기성분정량(無機成分定量)에 관(關)한 연구(硏究))

  • Cho, Han-Ok;Lee, Joong-Hwa;Cho, Sung-Hwan;Choi, Young-Hee
    • Korean Journal of Food Science and Technology
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    • v.8 no.2
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    • pp.95-106
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    • 1976
  • In order to investigate chemical components and mineral of ginseng cultivated in Korea and to establish an appropriate extraction method, the present work was carried out with Raw ginseng(SC), White ginseng(SB) and Ginseng tail(SA). The results determined could be summarized as follows : 1. Among the proximate components, moisture content of SC, SB and SA were 66.37%, 12.61% and 12.20% respectively. The content of crude ash in SA was the highest value of three kinds of ginseng root: SA 6.04%, SB 3.52% and SC 1.56%. The crude protein of Dried ginseng root(SA and SB) was about 12-14%, which was more than two times compared with that of SC(6.30%) The content of pure protein seemed to be in similar tendency with that of crude protein in three kinds of ginseng root: 2.26% in SC, 5.94% in SB and 5.76% in SA. There was no significant difference in the content of fat among the kinds of ginseng root. $(1.1{\sim}2.5%)$ 2. The highest Ginseng extract was obtained by use of Continuous extractor which is a modified Soxhlet apparatus for 60 hours extraction with 60-80% ethanol. 3. Ginseng and the above-mentioned ginseng extract (Ginseng tail extract: SAE, White Ginseng extract : SBE, Raw Ginseng extract: SCE) were analyzed by volumetric method for the determination of Chlorine and Calcium, by colorimetric method for that of Iron and Phosphorus, by Atomic Absorption Spectrophotometer for that of Zinc, Copper and Manganese. The results were as follows : 1. The content of phosphorus in SA, SB and SC were 1.818%, 1.362%, 0.713% respectively and phosphorus content in three kinds of extract were in low level (SAE: 0.03%, SBE: 0.063%, SCE: 0.036%) 2. In the Calcium content, SA, SB and SC were 0.147%, 0.238%, 0.126% and the Calcium contents of Ginseng extracts were 0.023%, 0.011% and 0.016%. The extraction ratio of Calcium from SA was the highest value (15.6%), while that in the case of SB was 4.6%. 3. The Chlorine content of SA was 0.11%, this was slightly higher than others(SB: 0.07%, SC: 0.09%) and extraction ratio of SA and SB were 36.4%, 67.1% while that of SC was 84.4%. 4. The Iron content of SA, SB and SC were 125ppm, 32.5ppm and 20ppm but extraction ratio was extremely low (SAE: 1.33%, SBE: 0.83%, SCE: 1.08%), 5. The Manganese content of SA, SB and SC were 62.5ppm, 25.0ppm and 5.0ppm respectively but the Manganese content of extract could not determined, Copper content of SA, SB and SC were 15.0ppm, 20.0ppm and those of extract were 7.5ppm, 6.5ppm, 4.5ppm while those of extraction ratio were 50%, 32.5% and 90% respectively, Zinc was abundant in Ginseng compared with other herbs, (SA: 45.5ppm, SB: 27.5ppm and SC: 5.5ppm) and the extracted amount were 4.5ppm, 1.25ppm 1.50ppm respectively.

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Concentration of metallic elements in surface sediments at a waste disposal site in the Yellow Sea (황해 폐기물 투기해역(서해병) 표층 퇴적물의 금속원소 분포)

  • Koh, Hyuk-Joon;Choi, Young-Chan;Park, Sung-Eun;Cha, Hyung-Kee;Chang, Dae-Soo;Lee, Chung-Il;Yoon, Han-Sam
    • Journal of Environmental Science International
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    • v.22 no.7
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    • pp.787-799
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    • 2013
  • The aim of this study was to investigate the accumulation of metallic elements and the control effect of marine pollution caused by ocean dumping in the sediments at a waste disposal area in the Yellow Sea. In July 2009, concentrations of organic matter and metallic elements (Al, Fe, As, Cd, Cr, Co, Hg, Ni, Mn, Pb, and Zn) were measured in surface sediments at the site. The ignition loss (IL) in the surface sediments showed a mean value of 15.4%, about 1.5 times higher than the mean value of the sediments in the coastal areas of Korea. The chemical oxygen demand (COD) at some disposal sites exceeded 20 mg $O_2/g{\cdot}dry$, which signifies the initial concentration of marine sediment pollutants in Japan. The disposal sites contain higher concentrations of Cr, Cu and Zn than the sediments of bays and estuaries that might be contaminated. The magnitude of both metal enrichment factors (EF) and adverse biological effects suggest that pollution with Cr and Ni occurred due to the dumping of waste in the study area. In addition, the geoaccumulation index (Igeo) showed that the surface sediments were moderately contaminated. By the mid-2000s, when the amount of waste dumped at this site was the highest, the concentration of metallic elements was higher than ever recorded. On the other hand, in 2008-09, the need for environmental management was relatively low compare with the peak. As a result, the quality of marine sediment has been enhanced, considering the effect of waste reduction and natural dilution in the disposal area.

감마선 조사전 홍삼 추출물의 투여가 생쥐 간에서의 Superoxide dismutase의 활성과 지질 과산화에 미치는 영향

  • Park, Yeong-Sun;Kim, Dong-Yun;Jang, Jae-Cheol;Kim, Dong-Jo;Jeon, Cheol
    • The Journal of Korean Society for Radiation Therapy
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    • v.5 no.1
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    • pp.142-151
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    • 1992
  • Radioprotective effects of a red ginseng extracts on antioxidant enzymes(Superoxide dismutase, catalase and peroxidase) activities relationship to lipid peroxidation were studied in the cytosol fraction of mice liver. The experiments were carried out on Irradiated (5.5 Gy, $^{\60}Co$) and non-irradiated ICR mice after treatment of red ginseng extracts (5.5mg/mouse ; ip), In wholebody irradiated mice, irradiation caused a decrease in the activity of all these enzymes(on Day 21) The activities of SOD, Catalase and Peroxidase of red ginseng extracts treated mice were enhanced by $35.4\%,\;20.2\%$ and $20.1\%$, compared with non-treated mice. The red ginseng extracts led to inhibited increase of malondialdehyde product by ionizing radiation. The enhanced activity of enzymes that removed free radicals generated by radiation and thereby indicate that ginseng probably plays on important role in radioprotective effect.

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Effect of pre-planting liming fertilization in peatmoss based substrates on plug seeding growth of 'Red Madness' petunia and changes in soil chemical properties (피트모스 혼합상토에 기비로 혼합된 석회질 비료가 'Red Madness' 페튜니아 플러그 묘 생장과 상토화학성에 미치는 영향)

  • Lee, Poong-Ok;Lee, Jong-Suk;Choi, Jong-Myung
    • Korean Journal of Agricultural Science
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    • v.38 no.1
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    • pp.17-23
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    • 2011
  • This research was conducted to investigate the influence of application rate of liming fertilizers on changes in soil chemical properties and growth of 'Red Madness' petunia in plug production. To achieve this, dolomite (DO) with 0, 1.0, 3.5, 8.0 or 13.0 $g{\cdot}L^{-1}$ and calcium carbonate (CC) with 0, 2.0, 2.5, 3.0, 3.5, or 4.0 $g{\cdot}L^{-1}$ were incorporated into peatmoss + vermiculite (1:1, v/v) during the root substrates formulation. The treatments of 3.5 $g{\cdot}L^{-1}$ of DO and 2.5 or 3.0 $gL^{-1}$ of CC had acceptable ranges of pH and EC in soil solution such as 5.6~6.2 and 0.7~1.0 $dS{\cdot}m^{-1}$, respectively. The faster rising of pH was observed in root media containing CC rather than those of DO. This indicates that the solubility of CC is higher than DO. The soil Ca concentrations in all treatments of CC were 1.8 times as high as those of DO. The treatments of 3.5 or 8.0 $g{\cdot}L^{-1}$ of DO had the highest soil Mg concentrations, but all treatments of CC had lower soil Mg concentrations than control treatment indicating that additional application of Mg fertilizers are required. The elevated application rate of DO or CC resulted in the increase of fresh and dry weight. But plant heights were not influenced by application of liming fertilizers. The results of tissue analysis showed that application of DO or CC influenced the $PO_4{^-}P$, Ca and Mg contents, but not influenced the contents of other nutrients such as N, P, Fe, Mn, Zn and Cu.

Geology and Polymetallic Mineralization in the Cusco Area, Peru (페루 꾸스코 지역 지질특성과 다금속 광화작용)

  • Ryoo, Chung-Ryul;Heo, Chul-Ho;Munoz, Michael Valencia;Cornejo, Raymond Rivera;Angeldonis, Alexander Santisteban
    • Journal of the Mineralogical Society of Korea
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    • v.25 no.1
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    • pp.41-50
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    • 2012
  • 페루 남동부 지역에 위치한 꾸스코 동-금을 포함한 다중금속 광상 지역의 지질은 고생대 페름기-중생대 삼첩기 변성퇴적암인 미투(Mitu)층군과 이를 관입한 동시기 관입암으로 구성되어 있다. 조사지역은 페름기-삼첩기 관입암과 관련된 U-W-Sn-Mo, Au-Cu-Pb-Zn, REE 광화작용과 관련된 금속광화 대로 알려져 있다. 특히 해당 관입암은 대자율 측정 결과 S-type, 티탄철석계열과 관련이 있는 것으로 보인다. 꾸스코 지역은 깔까 북쪽과 시꾸아니 부근에 주요 광화대가 발달하고 있다. 조사대상 광상은 아줄 동, 올미오 동, 빅토리아 금, 빠딴자 동, 나우챠피-초차까나 동, 체카 금광상이다. 아줄 광상의 모암은 안산암질암이며 광석광물로는 반동석 및 황동석이 산출하며, 동은 7.81~15.3%의 범위를 가지고 평균 10.7%이다. 올미오 광상의 모암은 흑색편암이며 엽리를 따라 산화동이 충진되어 있고, 동은 0.61~2.60%의 범위를 가지고 평균 1.74%이다. 빅토리아 광상의 모암은 변성퇴적암이며, 석영맥 충진형 광상으로 금함량은 < 0.1 g/t, 은함량은 < 0.1~< 0.3 g/t이다. 빠딴자 광상에서는 이암 또는 실트암의 층리를 따라 충진하고 있는 산화동이 산출하며, 동은 3.74~9.21%의 범위를 보이며 평균 6.21%이다. 나우챠피-초차까나 광상은 적색사암의 층리를 교대충진하고 있는 산화동 광체이며, 동은 1.62~10.5%의 범위를 가지며 평균 6.39%이다. 체카 광상은 모암인 규암이 각력화작용을 받은 부분에서 금이 산출되고 있는 것으로 보고되어있으나 분석결과 금이 탐지되지는 않았다.

Analysis of Mineral Contents in Tissues and Bone Mineral Density of Rats (흰쥐의 조직 중 무기질 함량과 골밀도 분석)

  • Kim, Myung-Hee;Kim, Moo-Kyung;Lee, Jong-Wan;Kim, Mi-Hyun;Kang, Myung-Hwa;Choi, Mi-Kyeong
    • Reproductive and Developmental Biology
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    • v.34 no.3
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    • pp.123-126
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    • 2010
  • The purpose of present study was to analyze mineral contents in various tissues and investigate theirs relation with bone mineral density (BMD) in rats. Fifteen Sprague-Dawley rats were fed standard diet for 4 weeks. Body weight gain, feed intake, and feed efficiency ratio were 41.00 g/week, 171.15 g/week, and 0.24 respectively. Among 12 minerals in serum, Ca is the highest with 6.86 mg/dl. Serum Mg, Se, and Cu were 2.52 mg/dl, 0.23 mg/dl and 0.22 mg/dl respectively. Mg contents in liver, spleen, and kidney were $246.36\;{\mu}/g$, $105.01\;{\mu}/g$, and $273.38\;{\mu}/g$ respectively. Tibia contents of Ca, Mg, Zn, Fe and V were 194.91 mg/g, 23.10 mg/g, 0.60 mg/g, 0.35 mg/g and 0.14 mg/g respectively. BMDs of right tibia and spine were 122.04 mg/cm and $153.61\;mg/cm^2$. There were significantly positive correlations between tibia BMD and Se (p<0.05), tibia BMD and V (p<0.01), spinal BMD and V(p<0.05), respectively. It's expected that these results are used as a reference data in following study to elucidate physiological function of minerals.

Source Identification of Ambient PM-10 Using the PMF Model (PMF 모델을 이용한 대기 중 PM-10 오염원의 확인)

  • 황인조;김동술
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.6
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    • pp.701-717
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    • 2003
  • The objective of this study was to extensively estimate the air quality trends of the study area by surveying con-centration trends in months or seasons, after analyzing the mass concentration of PM-10 samples and the inorganic lements, ion, and total carbon in PM-10. Also, the study introduced to apply the PMF (Positive Matrix Factoriza-tion) model that is useful when absence of the source profile. Thus the model was thought to be suitable in Korea that often has few information about pollution sources. After obtaining results from the PMF modeling, the existing sources at the study area were qualitatively identified The PM-10 particles collected on quartz fiber filters by a PM-10 high-vol air sampler for 3 years (Mar. 1999∼Dec.2001) in Kyung Hee University. The 25 chemical species (Al, Mn, Ti, V, Cr, Fe, Ni, Cu, Zn, As, Se, Cd, Ba, Ce, Pb, Si, N $a^{#}$, N $H_4$$^{+}$, $K^{+}$, $Mg^{2+}$, $Ca^{2+}$, C $l^{[-10]}$ , N $O_3$$^{[-10]}$ , S $O_4$$^{2-}$, TC) were analyzed by ICP-AES, IC, and EA after executing proper pre - treatments of each sample filter. The PMF model was intensively applied to estimate the quantitative contribution of air pollution sources based on the chemical information (128 samples and 25 chemical species). Through a case study of the PMF modeling for the PM-10 aerosols. the total of 11 factors were determined. The multiple linear regression analysis between the observed PM-10 mass concentration and the estimated G matrix had been performed following the FPEAK test. Finally the regression analysis provided source profiles (scaled F matrix). So, 11 sources were qualitatively identified, such as secondary aerosol related source, soil related source, waste incineration source, field burning source, fossil fuel combustion source, industry related source, motor vehicle source, oil/coal combustion source, non-ferrous metal source, and aged sea- salt source, respectively.ively.y.

Synthesis and properties of indole based chemosensor

  • Lee, Jun-Hee;Wang, Sheng;Yu, Hyung-Wook;Kim, Hyung-Joo;Son, Young-A
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.03a
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    • pp.36-36
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    • 2011
  • We synthesized new dye sensor based on indole compound. Through the UV-vis absorptions, we analyzed chemosensing properties to explain metal binding properties. The peak absorptions increased at 472 nm when added metal cations($Cd^{2+}$, $Cu^{2+}$, $Hg^{2+}$, $Fe^{2+}$, $Zn^{2+}$, $Ni^{2+}$ and $Cr^{3+}$) and gradually decreased the peak at 516 nm. Thus, this UV-Vis absorption behavior clearly showed the metal binding reaction. To measure energy level of used dye sensor, HOMO/LUMO energy value was calculated with cyclovaltagramm(CV) and using computational calculation method, in which we estimated the optimum structure of dye sensor. CV and computational calculation method, both compared to find suitable geometric structure. (with almost same energy values.) From the computational calculation, dye sensor has plane structure. So, Amine and ketone in the dye sensor faced each other and makes position to bind metal cations. In addition, these positions was supported pull-push electron system and generated MLCT process, when the dye sensor was bonded with the metal cations and resulted chemosensing properties. Through the electrochemical and computational calculation method analyze, we proposed the chemosensing principles that the dye sensor bind the metal cation between ketone and amine. Finally, the formation type of metal ion bindings was determined by Job's plot measurements.

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Relationship between Soil Management Methods and Soil Chemical Properties in Protected Cultivation

  • Kang, Yun-Im;Lee, In-Bog;Par), Jin-Myeon;Kang, Yong-Gu;Kim, Seung-Heui;Ko, Hyeon-Seok;Kwon, Joon-Kook
    • Korean Journal of Environmental Agriculture
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    • v.28 no.4
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    • pp.333-339
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    • 2009
  • Various cultural practices have been promoted as management options for enhancing soil quality and health. The use of soil management methods can cause changes in fertility by affecting soil chemical properties. This study aimed to evaluate interactions between soil chemical properties and soil management methods in protected cultivation, and to classify soil management methods that similarly affect soil chemical properties. Water-logging and irrigation reduced soil pH and available $P_2O_5$ content. Application of animal manures has a positive effect on levels of organic matter, Av.$P_2O_5$, K, Zn, and Cu. The electrical conductivites tened to be low in the application of organic amendments, including rice and wood residues. Deeper plowing caused a reduction in Ca content. Practicing soil nutrient-considering fertilization and fertigation did not exert an influence on nutrient element contents. In a cluster analysis of the soil management methods according to major nutrients, low similarities were found with deeper plowing and crop rotation with rice in comparison with other practices. In a cluster analysis by minor nutrient characteristics, crop rotation and application of animal manures and rice residues were linked at a high Ward's distance, while other practices were found to be relatively low distinct. Each soil management method has a similar or different effect on soil chemical properties. These results suggest the necessity of establishing limits and standards according to the effects of soil management methods on soil chemical properties for economic soil practices.

Expression of Cu/Zn SOD Protein Is Suppressed in hsp 70.1 Knockout Mice

  • Choi, S-Mi;Park, Kyung-Ae;Lee, Hee-Joo;Park, Myoung-Sook;Lee, Joung-Hee;Park, Kyoung-Chan;Kim, Man-Ho;Lee, Seung-Hoon;Seo, Jeong-Sun;Yoon, Byung-Woo
    • BMB Reports
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    • v.38 no.1
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    • pp.111-114
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    • 2005
  • Heat shock proteins (HSPs) are known to protect cells from oxidative stress and other types of injuries. We previously reported the neuroprotective effect of HSP70 following cerebral ischemia and reperfusion using hsp 70.1 knockout (KO) mice. However, the precise role of HSP70 in neuroprotection has not been established yet. The purpose of this study was to investigate the relationship between HSP70 and antioxidant enzymes using hsp 70.1 KO mice. The activities of both SOD-1 and SOD-2 were significantly decreased in hsp 70.1 KO mice than in the wild type (WT) littermates. SOD-1 protein level in the hsp 70.1 KO mice was lower than that of WT. We speculate that HSP70 might be involved in regulation of expression of SOD-1 at the level of transcription or by post-transcriptional modification.