• Title/Summary/Keyword: ZnS: Cu

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Spectroscopic characterization of electroluminescent ZnS:Cu,Cl phosphor coated by sol-gel process

  • Lee, You-Hui;Han, Chi-Hwan;Han, Sang-Do;Chang, Mi-Youn;Sharma, Gaytri.;Park, Youn-Bong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1323-1326
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    • 2005
  • The photoluminescence, electroluminescence and surface properties of ZnS:Cu,Cl phosphor coated by sol-gel process were studies. Na-silicate was used as precursor coating material. pH of solution and the concentration of Na-silicate are the important conditions to obtain the uniform coating on the phosphors. Also, the electroluminescent devices were made with Na-silicate coated phosphor. The spectroscopic characterization is performed by photospectrometer.

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Heavy metals and VOCs contamination of urban Broundwaters in Seoul, Korea

  • Park, Seong-Sook;Yun, Seong-Taek;Park, Byoung-Young;Yu, Soon-Young
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.09a
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    • pp.291-295
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    • 2002
  • We measured the concentrations of heavy metals and VOCs in groundwaters (N=38) in Seoul. The comparison of our data with U.S. Environmental Protection Agency's Maximum Contaminant Levels for Drinking Water and with the Korean Drinking Water Standards shows that most of the metals except for Fe and Mn do not exceed the levels. However, the concentrations of most heavy metals (esp., Zn, Cu, Cr, Ni) tend to increase in residential and industrialized areas. The examination of the metal speciation using Anodic Stripping Voltammetry (ASV) and TOC analyzer Indicates that large amounts of Zn occur as labile metal fraction, whereas Cu occurs as non- labile forms at many sites, possibly due to its tendency to be adsorbed onto inorganic colloidal particles to form electroinactive species in groundwater. The most frequently existed VOCs in Seoul groundwaters are trichloroethylene and tetrachloroethylene, especially in agricultural, industrial, and high traffic areas.

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Finite Element Analysis of Combustion Reaction on Iron and Metal Oxides Interface (Fe-금속 산화물 계면에서 연소반응의 유한 요소해석)

  • Gu, Mun-Seon;Choe, Yong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.118.2-118.2
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    • 2017
  • Combustion behavior of Fe, CuO, NiO, ZnO and $Fe_2O_3$ powder mixture was carried out by finite element method (FEM) to understand a reaction at iron and metal oxide interface. The FEM was done by using ANSYS Fluent 17.0. Initial and boundary conditions are 1 atmosphere, room temperature, 0.1MPa of oxygen partial pressure, $T_{S1}=1127^{\circ}C$, $T_{S2}=327^{\circ}C$ for a cylindrical shape specimen with dia. $35{\times}80$ [mm]. The maximum combustion temperature is $1537^{\circ}C$ for the condition of conduction, convection and radiation. The combustion temperature and rate are about $847^{\circ}C$ and 3.9mm/sec, respectively. The combustion wave is enough to make ternary ferrite phase like $CuNiZnFe_2O_3$.

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The Flexible Information Display Using Powder Electroluminescent Device (후막 EL소자를 이용한 정보 표시형 Flexible 디스플레이)

  • Lee, Jong-Chan;Kim, Hyun-Hoo;Park, Dae-Hee
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.50 no.5
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    • pp.207-210
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    • 2001
  • In this paper, the Flexible information display was implemented uing AC powder electroluminescent device. ZnS:Cu and $BaTiO_3$ were used as a phosphor and dielectric respectively. The growth of phosphor and dielectric layer was performed with screen printing. The flexible information display in this paper was categorized as following; EL display, driving circuit, software for driving. EL spectrum and brightness was measured as the device properties.

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Fabrication of Bulk Metallic Glass Alloys by Warm Processing of Amorphous Powders (비정질 분말의 열간 성형법에 의한 벌크 비정질합금의 제조)

  • 이민하;김도향
    • Journal of Powder Materials
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    • v.11 no.3
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    • pp.193-201
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    • 2004
  • 1960년 Au-Si계 합금에서 처음으로 비정질상이 급속 응고법에 의해 보고된 이래/sup 1)/ 지난 40년 간 많은 합금계에서 비정질상이 보고되어졌다. 대표적으로 Fe-, Ni-, Co기 합금 등 많은 합금계에서 비정질상이 보고되었으나, 비정질상의 형성을 위해서는 약 105 K/s이상의 높은 냉각속도를 필요로 하였다. 1980년대 수백 K/s의 낮은 냉각속도 하에서도 비정질상이 형성될 수 있는 다원계 합금(multi-component alloy)이 Mg-Ln-(Ni, Cu, Zn), Ln-Al-TM 합금에서 보고되어 졌으나 많은 관심을 받지 못하다가 1993년 Zr-Ti-Ni-Cu-Be 합금에서 수 ㎝ 크기의 비정질합금 제조가 보고되면서 전 세계적으로 많은 관심을 받게 되었다. Zr-Ti-Ni-Cu-Be계 벌크 비정질 합금이 보고된 후 Zr-(Nb,Pd)-Al-TM, Pd-Cu-Ni-P, Fe-Co-Zr-Mo-W-B, Ti-Zr-Ni-Cu-Sn등 여러 합금계에서 벌크 비정질 합금이 보고되었다. (중략)

Spectrophotometric Determination of Copper After Selective Extraction with $\alpha$-(2-Benzimidazolyl)-$\alpha ^{\prime}, \alpha ^{\prime} ^{\prime}$-(N-5-nitro-2-pyridyl hydrazone)-toluene in the Presence of Brij 58

  • 박찬일;김현수;차기원
    • Bulletin of the Korean Chemical Society
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    • v.20 no.3
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    • pp.352-354
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    • 1999
  • The spectrophotometric determination of Cu(Ⅱ) with α-(2-benzimidazolyl)-α',α"-(N-5-nitro-2-pyridylhydrazone)-toluene has been investigated. The optimum conditions of pH, stability, concentration of ligand and surfactant were evaluated. This method is a simple and sensitive method for determination of Cu(Ⅱ) and offers a selective separation of Cu(Ⅱ) from sample solution containin- I ppm below amount of Ni(Ⅱ), Co(Ⅱ), Zn(Ⅱ) and Sn(Ⅱ). Copper was determined by measuring the absorbance of Cu(Ⅱ)-BINPHT complex extracted with benzene in Brij 58 surfactant at 410 nm. Beer's law is obeyed over the concentration range 0∼2.5 μgmL-1 and the detection limit (S/N=2) is 0.06 μgmL-1. The relative standard deviation at the 0.3 μgmL-1 is 2.4% (N=7). The method was applied for the determination of Cu(Ⅱ) in various milks.

Selective Removal of Toxic Heavy Metals in Fe-Coagulants (철염 응집제 중 유독성 중금속의 선택적 제거)

  • 박상원
    • Journal of Environmental Science International
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    • v.8 no.3
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    • pp.393-397
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    • 1999
  • Among various reactions which metal sulfides can undergo in the reducing environment, the lattice exchange reaction was examined in a attempt to selectively remove heavy metal ions contained in the Fe-Coagulants acid solution. We have examined Zeta potential along with pHs to investigate surface characteristics of ${FeS}_{(s)}$. As a result of this experiment, zero point charge(ZPC) of FeS is pH 7 and zeta potential which resulted from solid solution reaction between Pb(II) and ${FeS}_{(s)}$ is similar to that of ${PbS}_{(s)}$. Solubility characteristics of ${FeS}_{(s)}$ is appeared to that dissolved Fe(II) concentration increased in less than pH 4, and also increased with increasing heavy metal concentration. Various heavy metal ions(Pb(II), Cu(II), Zn(II)) contained in Fe-coagulants acid solution were removed selectively more than ninety-five percent in the rang of pH 2.5~10 by ${FeS}_{(s)}$. From the above experiments, therefore, We could know that the products of reaction between heavy metal ions and $FeS_{(S)}$ are mental sulfide such as $PbS_{(S)}$, $CuS_{(S)}$ and $ZnS_{(S)}$.

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A Survey on the Heavy Metal Concentration of Soil Samples around Onsan Industrial Complex (온산공단(溫山工團)주변토양의 중금속(重金屬) 농도조사)

  • Lee, Su-Rae;Song, Ki-Joon
    • Korean Journal of Environmental Agriculture
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    • v.4 no.2
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    • pp.88-94
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    • 1985
  • In order to investigate the pollution potential of soils after the construction of Onsan Industrial Complex(non-ferrous metal refineries), concentrations of hazardous heavy metals were analyzed for soil samples collected from paddy, upland, orchard and forest soils around the Complex during the period of March 1978 to May 1979. The results are summarized as follows. 1) The concentrations of heavy metals (air-dry basis) for cultivated soil samples from 46 sites were obtained in the range of trace-9.3 ppm As, trace-0.6 ppm Cd, 4${\sim}$22 ppm Cu, trace-0.37 ppm Hg, 6${\sim}$43 ppm Pb and 27${\sim}$93 ppm Zn, which were regarded as non-polluted when compared with the whole Korea data for non-polluted paddy soils. 2) When the heavy metal concentrations were compared with respect to paddy, upland and orchard soils, no significant difference was observed in As, Cd, Cu and Zn whereas significant difference was observed in Hg and Pb. When they were compared with respect to region surrounding the Complex, no significant difference was observed in As, Cd, Hg whereas significant difference was observed in Cu and Pb. 3) Soil samples from several sites near Korea Zinc Refinery were contaminated with Cd, Pb and Zn, due to the accidental emission during its testing operation. Any further contamination was not observed after regular operation of the Refinery.

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Trace element levels and selenium uptake in cereals grown in lower Austria

  • Sager M.;Hoesch J.
    • 한국지구물리탐사학회:학술대회논문집
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    • 2003.11a
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    • pp.479-492
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    • 2003
  • Wheat, barley, rye, and maize were grown in field and pot experiments at various non-contaminated soils in order to establish uptake rates for added selenate, and to find baseline concentrations for various soil types. Edible parts (grains) and stalks of the crops were analyzed separately for Se, as well as for Ca, Cu, Fe, Mn, P, S, and Zn. The addition of Na-selenate in admixture with the NPK 20:8:8 fertilizer had no influence on the composition of the other elements investigated. The proportions of added nitrate: selenate, and sulfate:selenate were kept constant. The Se- uptake rate differed among the cereals tested, it was highest for winter wheat. Utilization of added Se in the field ranged from $0,4-4,7\%$, and and in the pots from $3,3-5,4\%$, it was markedly lower in clay soil. Whereas P and Zn were preferably found in the grains, Ca-Fe-Mn-S got enriched in the stalks. For the fields, the location had some influence upon Fe, Mn, and Zn, whereas it was not important for P, S, Cu, and strikingly, Ca. Pot and field experiments on similar soils led to different results, except for P and S. Maize (whole grains) was significantly lower in Ca, Cu, and Mn, and might even cause trace element deficiencies, if exclusively fed. Few correlations between the trace elements investigated led to the conclusion that most element contents were governed by plant metabolism. Variations of mobile Fe in the soils were balanced by uptake into the stalks. The data are compared with data from other presumably non-contaminated sites.

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A Geochemical Study on Jindong Granites in Relation to Copper Ore Deposits in Gyeongsang Basin (경상분지내 동광상 관련 진동화강암류에 대한 지화학적 연구)

  • Lee, Jae Yeong;Lee, Jin Kook;Park, Beob Jeong;Lee, In Ho;Kim, Sang Wook
    • Economic and Environmental Geology
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    • v.27 no.2
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    • pp.161-170
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    • 1994
  • Jindong Granites are plotted mainly in the region of granodiorite~diorite of the Streckeisen's diagram, while Yucheon-Eonyang Granites and Onjonri Granites in the region of monzo-granite and monzo-granite~granodiorite, respectively. Jindong Granites show a differenciation trend of calc-alkaline magma, and its magmatic evolution from intermediate to acidic rocks, which might form mineralizing solution, is consistant with the general path of the Cretaceous granitic rocks including Yucheon-Eonyang Granites and Onjongri Granites. The differenciation index (D.I.) is 35~80 for Jindong Granites, which is lower than 85~95 of Yucheon-Eonyang Granites and is partly overlapped by 67~84 of Onjongri Granites. There is clear difference in content of some major and trace elements between Jindong Granites of Cu province and the other granitic rocks of Pb-Zn and Mo provinces. Between these metallogenic provicnes, Cu content is high in Jindong Granites near Haman-Gunbuk mineralized zone, while Pb and Zn are relatively abundant in Yucheon-Eonyang Granites and Mo in Onjongri Granites. Therefore, Jindong Granites of the Cu province are distinguishable by chemical compositions and their related geochemical characteristics from the other Cretaceous granitic rocks of Pb-Zn and Mo provinces. However, the content of Cu and Cl in biotite is applicable to distinguish a productive phase from a barren phase of Jindong Granites, because Cu and Cl show a trend to be concentrated in biotite of Jindong Gratites in the Haman-Gunbuk mineralized zone.

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