• Title/Summary/Keyword: ZnO-carbon nanotube composite

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Surface and small scale effects on the dynamic buckling of carbon nanotubes with smart layers assuming structural damping

  • Farokhian, Ahmad;Salmani-Tehrani, Mehdi
    • Steel and Composite Structures
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    • v.37 no.2
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    • pp.229-251
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    • 2020
  • In this paper, dynamic buckling of a smart sandwich nanotube is studied. The nanostructure is composed of a carbon-nanotube with inner and outer surfaces coated with ZnO piezoelectric layers, which play the role of sensor and actuator. Nanotube is under magnetic field and ZnO layers are under electric field. The nanostructure is located in a viscoelastic environment, which is assumed to obey Visco-Pasternak model. Non-local piezo-elasticity theory is used to consider the small-scale effect, and Kelvin model is used to describe the structural damping effects. Surface stresses are taken into account based on Gurtin-Murdoch theory. Hamilton principle in conjunction with zigzag shear-deformation theory is used to obtain the governing equations. The governing equations are then solved using the differential quadrature method, to determine dynamic stability region of the nanostructure. To validate the analysis, the results for simpler case studies are compared with others reported in the literature. Then, the effect of various parameters such as small-scale, surface stresses, Visco-Pasternak environment and electric and magnetic fields on the dynamic stability region is investigated. The results show that considering the surface stresses leads to an increase in the excitation frequency and the dynamic stability region happens at higher frequencies.

The Detection Characterization of NOX Gas Using the MWCNT/ZnO Composite Film Gas Sensors by Heat Treatment (열처리에 따른 MWCNT/ZnO 복합체 필름 가스센서의 NOX 가스 검출 특성)

  • Kim, Hyun-Soo;Jang, Kyung-Uk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.7
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    • pp.521-526
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    • 2018
  • In particular, gas sensors require characteristics such as high speed, sensitivity, and selectivity. In this study, we fabricated a $NO_X$ gas sensor by using a multi-walled carbon nanotube (MWCNT)/zinc oxide (ZnO) composite film. The fabricated MWCNT/ZnO gas sensor was then treated by a $450^{\circ}C$ temperature process to increase its detection sensitivity for NOx gas. We compared the detection characteristics of a ZnO film gas sensor, MWCNT film gas sensor, and the MWCNT/ZnO composited film gas sensor with and without the heat-treatment process. The fabricated gas sensors were used to detect $NO_X$ gas at different concentrations. The gas sensor absorbed $NO_X$ gas molecules, exhibiting increased sensitivity. The sensitivity of the gas sensor was increased by increasing the gas concentration. Additionally, while changing the temperature inside the chamber for the MWCNT/ZnO composite film gas sensor, we obtained its sensitivity for detecting $NO_X$ gas. Compared with ZnO, the MWCNT film gas sensor is excellent for detecting $NO_X$ gas. From the experimental results, we confirmed the enhanced gas sensor sensing mechanism. The increased effect by electronic interaction between the MWCNT and ZnO films contributes to the improved sensor performance.

Fabrication of Vertically Oriented ZnO Micro-crystals array embedded in Polymeric matrix for Flexible Device (수열합성을 이용한 ZnO 마이크로 구조의 성장 및 전사)

  • Yang, Dong Won;Lee, Won Woo;Park, Won IL
    • Journal of the Microelectronics and Packaging Society
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    • v.24 no.4
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    • pp.31-37
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    • 2017
  • Recently, there has been substantial interest in flexible and wearable devices whose properties and performances are close to conventional devices on hard substrates. Despite the advancement on flexible devices with organic semiconductors or carbon nanotube films, their performances are limited by the carrier scattering at the molecular to molecular or nanotube-to-nanotube junctions. Here in this study, we demonstrate on the vertical semiconductor crystal array embedded in flexible polymer matrix. Such structures can relieve the strain effectively, thereby accommodating large flexural deformation. To achieve such structure, we first established a low-temperature solution-phase synthesis of single crystalline 3D architectures consisting of epitaxially grown ZnO constituent crystals by position and growth direction controlled growth strategy. The ZnO vertical crystal array was integrated into a piece of polydimethylsiloxane (PDMS) substrate, which was then mechanically detached from the hard substrate to achieve the freestanding ZnO-polymer composite. In addition, the characteristics of transferred ZnO were confirmed by additional structural and photoluminescent measurements. The ZnO vertical crystal array embedded in PDMS was further employed as pressure sensor that exhibited an active response to the external pressure, by piezoelectric effect of ZnO crystal.

Temperature Calibration of a Specimen-heating Holder for Transmission Electron Microscopy

  • Kim, Tae-Hoon;Bae, Jee-Hwan;Lee, Jae-Wook;Shin, Keesam;Lee, Joon-Hwan;Kim, Mi-Yang;Yang, Cheol-Woong
    • Applied Microscopy
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    • v.45 no.2
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    • pp.95-100
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    • 2015
  • The in-situ heating transmission electron microscopy experiment allows us to observe the time- and temperature-dependent dynamic processes in nanoscale materials by examining the same specimen. The temperature, which is a major experimental parameter, must be measured accurately during in-situ heating experiments. Therefore, calibrating the thermocouple readout of the heating holder prior to the experiment is essential. The calibration can be performed using reference materials whose phase-transformation (melting, oxidation, reduction, etc.) temperatures are well-established. In this study, the calibration experiment was performed with four reference materials, i.e., pure Sn, Al-95 wt%Zn eutectic alloy, NiO/carbon nanotube composite, and pure Al, and the calibration curve and formula were obtained. The thermocouple readout of the holder used in this study provided a reliable temperature value with a relative error of <4%.