• Journal of the Korean Magnetics Society
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• v.5 no.5
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• pp.556-560
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• 1995

The absorption properties of Cu-Zn ferrite/rubber composite microwave absorbers with PZT(Lead Zirconate Titanate) additive were evaluated. The composite specimens have prepared by molding and curing the mixture of matrix rubber and Cu-Zn ferrite powders which are synthesized by the coprecipitation method using Fe Cl/sub 3/ .center dot. 6H/sub 2/O, CuCl/sub 2/ .center dot. 2H/sub 2/O and Zn Cl/sub 2/ as a starting raw materials. PZT is used as another filler particles to adjust the material constants of Cu-Zn ferrite/rubber composite specimens. We have found that the material constants of specimens could be controlled by various PZT mixing ratio. On the Cu-Zn ferrite/rubber composite specimens with PZT 10[wt%] additive, the reflection losses were larger than 30[dB] in the frequency range from 2.72 to 4.4[GHz]' by adjusing the thickness.

• Proceedings of the Korean Ceranic Society Conference
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• 2003.10a
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• pp.188.1-188
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• 2003

• Proceedings of the Korea Association of Crystal Growth Conference
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• 2000.06a
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• pp.35-58
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• 2000

The demand for sub-micrometer or nanometer functional ceramic powders with a better suspension behavior in aqueous media in increasing. Redispersible barium titanate (BT) nanocrystals, green light emitting Mn2+ doped Zn$_2$SiO$_4$ and ZnS nanoparticle phosphors were synthesized by a hydrothermal method or chemical precipitation with surface modification. The nanoparticle redispersibility for BT was achieved by using a polymeric surfactant. X-ray diffraction(XRD) results indicated that the BT particles are of cubic phase with 80 nm in size. XRD results of zinc silicate phosphor indicate that seeds play an important role in enhancing the nucleation and crystallization of Zn$_2$SiO$_4$ crystals in a hydrothermal condition. This paper describes and discuss the methods of surface modification, and the resulting related properties for BT, zinc silicate and zinc sulfide.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1997.11a
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• pp.211-216
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• 1997

ZnO and A1$_2$O$_3$ powders were mixed in 1 : 1 mole ratio and ball-milled with ethanol for 3 h. After the pressing process, the mixtures were sintered at $700^{\circ}C$~130$0^{\circ}C$ for 5 h in air to form ZnA1$_2$O$_4$. Structural properties were analyzed by X-ray diffraction patterns ; optical properties by absorption spectra with UV-VIS-H[R Spectrophotometer ; microstructural properties by SEM ; photoluminescent properties by using PL Measuring System. In result, ZnAl$_2$O$_4$ phosphor is crystallized at 110$0^{\circ}C$ and optical bandgap is calculated at 4.65 eV. PL spectrums were shifted to longer wavelengths with increasing temperature and was appeared around 780nm at 130$0^{\circ}C$ . Additionally, the peak intensity was veil strong at 80$0^{\circ}C$ and was declined with increasing temperature.

• Journal of the Korean Ceramic Society
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• v.32 no.6
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• pp.719-725
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• 1995

ZST powders were synthesized by coprecipitation of (Zr4+, Ti4+)-hydroxide in the presence of SnO2 particles. Zn(NO3)2 was used as a sintering additive, and according to the adding sequence, sintering and dielectric properties were investigated. Sintered densities of ZST prepared by adding Zn(NO3)2 before calcination were a little higher than those added after calcination, and dielectric properties of the specimen added by Zn(NO3)2 after calcination were better (sintered at 125$0^{\circ}C$/2 h ; Q$\times$f(GHz)=49, 000, $\varepsilon$r=41) than before calcination (Q$\times$f(GHz)=42, 000, $\varepsilon$r=39.5). Through the observation of TEM, it was identified that the cause was due to the difference of the degree of Zn2+ diffusion into grains. With increasing sintering time from 2 to 8 hrs, grain size was doubled and dielectric properties were somewhat deteriorated.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.5 no.1
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• pp.60-66
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• 1995

Abstract The experimental results which is the aerosols behavior and distribution of atomized zinc nitrate ($Zn(NO_3)_2$) solution (0.5 M) by ultrasonic vibrator were in accord with the computer simulations. i.e., most aerosols passing through the reactor (hot zone) moved toward the center of reactor by thermophoresis as the axis of reactor increase. Also, the distribution of aerosols concentration was high at the center of reactor as the axis increase. Among the synthesized ZnO particles, shell-like aggregates of fracture type which could not see at the center of reactor were observed at near the wall of reactor, and the particle size ($ 1.2 {\mu\textrm{m}$) of near the wall was larger than that ($0.9 {\mu\textrm{m}$) of the center.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2000.11a
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• pp.11-12
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• 2000

Non-stoichiometric ceramics of $Ni_{x}ZnO_{1-x}Fe_{2}O_{4}$ were prepared by self-propagating high temperature synthesis reaction with various processing conditions and their stoichometric numbers were determined by neutron diffraction. The neutron diffraction patterns were measured at room temperature using monochromatic neutrons with a wave length of 0.18339 nm from a Ge(331) mocochromator at a 90 degree take off angle. The Rietveld refinement of each pattern converged to good agreement (x2=1.88-2.24). The neutron diffraction analysis revealed the final stoichiometries of the ferrites were $Ni_{0.38}Zn_{0.62}Fe_{2}O_{4}$ and $Ni_{0.33}Zn_{0.67}Fe_{2}O_{4]$, respectively. This supports that final stoichiometric number of the self-propagating high temperature synthesis product can be controlled by the processing parameters during the combustion reaction.

• Bulletin of the Korean Chemical Society
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• v.33 no.2
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• pp.398-402
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• 2012

ZnSe/$SiO_2$ coaxial nanowires were synthesized by a two-step process: thermal evaporation of ZnSe powders and sputter-deposition of $SiO_2$. Two different types of nanowires are observed: thin rod-like ones with a few to a few tens of nanometers in diameter and up to a few hundred of micrometers in length and wide belt-like ones with a few micrometers in width. Room-temperature photoluminescence (PL) measurement showed that ZnSe/$SiO_2$ coaxial nanowires had an orange emission band centered at approximately 610 nm. The intensity of the orange emission from the $SiO_2$-sheathed ZnSe nanowires was enhanced significantly by annealing in a reducing atmosphere whereas it was degraded by annealing in an oxidizing atmosphere. The origins of the PL changes by annealing are discussed based on the energy-dispersive X-ray spectroscopy analysis results.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2006.11a
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• pp.203-204
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• 2006

Nano-Varistors fabricated with ZnO 30nm and 80nm powders were studied about the electrical characteristics with AC accelerated degradation in this paper Especially, ZnO nano-powder varistors were sintered m air at $1050^{\circ}C$ and analyzed the phenomenons of before and after AC degradation test. The stress conditions of AC degradation test were $1.0V_{1mA}$ $115{\pm}2^{\circ}C$ for 24h. 80nm-varistor was exhibited better performance than 30nm-varistor m the electrical stabilities. And then 80nm-varistor resulted m the degradation characteristics that the variation rate of operating voltage, nonlinear coefficient and leakage current was -0 3%, -0 4% and -3 3%, respectively.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.06a
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• pp.383-384
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• 2007

The nano and micro-sized $ZnGa_2O_4$ phosphor were prepared by precipitation method and solid-state method. The luminescence, formation process and structure of phosphor powders were investigated by means of XRD, SEM and PL. The result of XRD analysis showed that $ZnGa_2O_4$ spinel structure was formed at as-prepared in the case of precipitation method. However, micro-sized phosphor was required high heating treatment to have a satisfactory spinel structure. The CL intensity of nano-sized phosphor was about 4-fold higher than that of micro-sized phosphor. The emission spectra of all $ZnGa_2O_4$ phosphor show a self activated blue emission band at around 420 nm in the wide range of 300~600 nm.