• Title/Summary/Keyword: Zn-complex

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Modeling of RF Sputtering Process for ZnO Thin film Deposition using Neural Network (신경회로망을 이용한 RF 스퍼터링 ZnO 박막 증착 프로세스 모델링)

  • Lim, Keun-Young;Lee, Sang-Keuk;Park, Choon-Bae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.7
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    • pp.624-630
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    • 2006
  • ZnO deposition parameters are not independent and have a nonlinear and complex property. To propose a method that could verify and predict the relations of process variables, neural network was used. At first, ZnO thin films were deposited by using RF magnetron sputtering process with various conditions. Si, GaAs, and Glass were used as substrates. The temperature, work pressure, and RF power of the substrate were $50\sim500^{\circ}C$, 15 mTorr, and $180\sim210W$, respectively : the purity of the target was ZnO 4 N. Structural properties of ZnO thin films were estimated by using XRD (0002) peak intensity. The structure of neural network was a form of 4-7-1 that have one hidden layer. In training a network, learning rate and momentum were selected as 0.2, 0.6 respectively. A backpropagation neural network were performed with XRD (0002) peak data. After training a network, the temperature of substrate was evaluated as the most important parameter by sensitivity analysis and response surface. As a result, neural network could capture nonlinear and complex relationships between process parameters and predict structural properties of ZnO thin films with a limited set of experiments.

Optical properties of Zn-doped InGaN grown by MOCVD (MOCVD로 성장한 Zn-doped InGaN의 광특성 연구)

  • 이창명;이주인;임재영;신은주;김선운;서준호;박근섭;이동한
    • Journal of the Korean Vacuum Society
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    • v.10 no.1
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    • pp.67-71
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    • 2001
  • Optical investigation on Zn-doped InGaN grown by MOCVD was performed by using the photoluminescence. Two different spectra related to Zn-acceptor-like centers occurred at room temperature, with broad emissions peaking at 2.81, and 2.60 eV, Specially, emissions interacted with phonon were observed at 2.81 eV where phonon energy was 92.5 meV From temperature dependent blue-band emissions of InGaN, we observe that the intensity in high energy region was quickly decreased more than that in low energy region with increased temperature, and the peak position at 2.81 eV was blue shift of about 18 meV, The blue-band emmissions would be originated from the transition related to the localized Zn complex centers.

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Organic electroluminescent device using Zn(phen)q as emitting layer

  • Kim, Won-Sam;You, Jung-Min;Lee, Burm-Jong;Jang, Yoon-Ki;Kwon, Young-Soo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1280-1283
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    • 2005
  • A novel zinc complex, Zn(phen)q, was synthesized from 1,10-phenanthroline (phen) and 8-hydroxyquinoline (q) as organic ligands and its electroluminescent (EL) properties were characterized. The structure of Zn(phen)q was elucidated by FT-IR, UV-Vis and XPS. The complex Zn(phen)q showed thermal stability up to $300^{\circ}C$ under nitrogen flow, which was measured by TGA and DSC. The photoluminescence (PL) of the Zn(phen)q was measured from the THF solution and the solid film on quartz substrate. The PL emission of Zn(phen)q exhibited green light centered at about 505nm. The EL devices were fabricated by the vacuum deposition. The EL devices having the structure of ITO/a-NPD/Zn(phen)q/Li:Al were studied, where 4,4'-bis[N-(1-naphthyl)-N-phenylamino]biphenyl(a-NPD) used as a hole transport layer(HTL). a-NPD has high Tg of $96^{\circ}C$ and thus makes the device thermally stable. The EL emission of Zn(phen)q exhibited also green light centered at 532nm.

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Electrical characteristics of $Al_2O_3$ added ZnO ($Al_2O_3$가 첨가된 ZnO의 전기적 특성)

  • 최우성;소병문;홍진웅
    • Electrical & Electronic Materials
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    • v.9 no.6
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    • pp.572-577
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    • 1996
  • Alternating current and direct current of pure, ball milled, and $Al_{2}$O$_{3}$ added ZnO were investigated by means of complex impedance measurement and voltage-current source measurement unit. The electrical conductivity of A1$_{2}$O$_{3}$ added ZnO samples increases when the content of A1$_{2}$O$_{3}$ is used within 1 at% and decreases when it's used more than that. The increase and decrease of electrical conductivity seem to be the donor effect of $Al_{2}$O$_{3}$ and the increase of the number of ZnO grains, respectively. Impedance spectrum seems to be one semircicle. The size of semicircle increase with increasing the A1$_{2}$O$_{3}$ contents. The calculated dielectric constant(at 50.deg. C) were about 70-140 at the peak of the semicircle. The semicircles seem not to be the resistance of ZnO grain as compared to that of 10 for pure ZnO.

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Quality prediction method by using ZnO thin film deposition process modeling (ZnO 박막 증착 공정 모델링에 의한 품질 예측 기법)

  • Lim, Keun-Young;Chung, Doo-Yeon;Lee, Sang-Keuk;Park, Choon-Bae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.163-164
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    • 2006
  • ZnO deposition parameters are not independent and have a nonlinear and complex properties respectively. Therefore, finding optimal process conditions are very difficult and need to do many experiments. To predict ZnO deposition result, neural network was used. To gather training data, Si, GaAs, and Glass were used for substrates, and substrate temperature, work pressure, RF power were $50-500^{\circ}C$, 15 mTorr, and 180-210 W respectively, and the purity of target was ZnO 4N. For predicting the result of ZnO deposition process exactly, sensitivity analysis and drawing a response surface was added. The temperature of substrate was evaluated as a most important variable. As a result, neural network could verify the nonlinear and complex relations of variables and find the optimal process condition for good quality ZnO thin films.

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Effects of proteinate complex zinc on growth performance, hepatic and splenic trace elements concentrations, antioxidative function and immune functions in weaned piglets

  • She, Yue;Huang, Qiang;Li, Defa;Piao, Xiangshu
    • Asian-Australasian Journal of Animal Sciences
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    • v.30 no.8
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    • pp.1160-1167
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    • 2017
  • Objective: To assess the effects of proteinate complex zinc (PC-Zn) on growth performance, antioxidative function, trace element concentrations and immune function in weaned piglets. Methods: Three hundred newly weaned barrows ($Duroc{\times}Landrace{\times}Yorkshire$), 28 days of age, were randomly allotted to 3 dietary groups of 5 replicate pens per group for 4 weeks of feeding. Experimental diets were: i) zinc deficient diet (ZnD, 24 mg/kg Zn supplementation from $ZnSO_4$), ii) inorganic Zn diet supplemented with 120 mg/kg of Zn from Zn sulfate ($ZnSO_4$), and iii) organic Zn diet supplemented with 120 mg/kg of Zn from PC-Zn. The body weight of pigs were recorded at the beginning, at the middle and at the end of the experiment, and the amount of feed supplied each day was recorded. Five barrows from each dietary treatment group were selected to be anesthetized and euthanized at the end of the trial to determine the Zn, Cu, Fe, and Mn concentrations, the hepatic metallothionein content, the levels of methane dicarboxylic aldehyde (MDA), Mn, and Cu/Zn superoxide dismutase (SOD), and glutathione peroxidase (GSH-Px) in the spleen, the levels of interleukin (IL)-2, IL-4, IL-10, interferon $(IFN)-{\gamma}$, $CD3^+$, $CD4^+$, and $CD8^+$ T lymphocyte. Results: The accumulation of Zn in the spleen, levels of SOD, GSH-Px, IL-4, IL-10, the proportions of $CD3^+$ and $CD4^+$ T lymphocyte, and the ratio of $CD4^+/CD8^+$ T lymphocyte were increased by organic Zn supplementation compared to ZnD, while the levels of MDA, $IFN-{\gamma}$, and proportion of $CD8^+$ T lymphocyte were lowered. Conclusion: These findings indicate that Zn can improve the antioxidant potential and immune functions of weaned piglets.

Structural characterization and thermal behaviour of the bis(2-aminothiazole)bis(isothiocyanato)zinc(II) complex, Zn(NCS)2(C3H4N2S)2

  • Suh, Seung Wook;Kim, Inn Hoe;Kim, Chong-Hyeak
    • Analytical Science and Technology
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    • v.18 no.5
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    • pp.386-390
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    • 2005
  • The zinc(II) complex, $Zn(NCS)_2(C_3H_4N_2S)_2$, I, has been synthesized and characterized by single crystal X-ray diffraction, thermal analysis and infrared spectroscopy. The complex I crystallizes in the triclinic system, $P\bar{1}$ space group with a = 7.587(1), b = 8.815(1), $c=12.432(2){\AA}$, ${\alpha}=75.584(8)$, ${\beta}=83.533(9)$, ${\gamma}=68.686(8)^{\circ}$, $V=750.0(2){\AA}^3$, Z = 2, $R_1=0.036$ and ${\omega}R_2=0.101$. The central Zn(II) atom has a tetrahedral coordination geometry, with the heterocyclic nitrogen atoms of 2-aminothiazole ligands and the nitrogen atoms of isothiocyanate ligands. The crystal structure is stabilized by one-dimensional networks of the intermolecular $N-H{\cdots}S$ hydrogen bonds between the amino group of 2-aminothiazole ligands and the sulfur atom of isothiocyanate ligands. Based on the results of thermal analysis, the thermal decomposition reaction of complex I was analyzed to have three distinctive stages such as the loss of 2-aminothiazole, the decomposition of isothiocyanate and the formation of metal oxide.

Chemical Properties in the Soils of Reclaimed and Natural Tidelands of Southwest Coastal Area of Korea (I) - Distribution of Heavy Metal Fractions - (우리나라 서남해안 간척지 및 간석지 토양의 화학적 특성 (I) - 중금속 오염물질의 형태별 함량 분포 -)

  • Cho, Jae-Young;Koo, Ja-Woong;Son, Jae-Gwon
    • Journal of The Korean Society of Agricultural Engineers
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    • v.48 no.1
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    • pp.3-10
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    • 2006
  • The chemical fractions of heavy metals were investigated in the soils of reclaimed and natural tidelands of southwest coastal area of Korea. The distribution pattern of each heavy metal in different fractions was in the order: 1) Cu : organic bound > organic complex > residual > exchangeable = water soluble. 2) Cr : residual > organic bound > organic complex > water soluble > exchangeable. 3) Pb : organic bound > residual > organic complex > water soluble > exchangeable. 4) Cd residual > organic bound > organic complex > water soluble = exchangeable. 5) Zn : organic bound > residual > organic complex > water soluble > exchangeable. The content of residual Zn showed positive correlation with organic matter content but organic bound Zn showed negative correlation with CEC. The content of residual and exchangeable Cd showed highly positive correlation with organic matter content but residual, organic bound, and exchangeable Cd showed negative correlations with CEC. Water soluble Pb showed positive correlation with CEC but organic bound Pb showed negative correlation with CEC.

The Complex Permeability and Microwave Absorbing Characterisics of $Ni_{2-x}Zn_{x}Y$ - Rubber Composites ($Ni_{2-x}Zn_{x}Y$ - 고무 복합체의 복소투자율과 전파흡수특성)

  • 신재영;오재희;권형주
    • Journal of the Korean Magnetics Society
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    • v.5 no.1
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    • pp.27-33
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    • 1995
  • The microwave absorbing characteristics and complex permeability of $Ni_{2-x}Zn_{x}Y$ - rubber composites with variation of composition and particle size were investigated. With a ferrite particle with a diameter of about $1\mu\textrm{m}$, only spin rotational resonance was observed. This behavior probably due to the particle being sufficiently small to approach single domain characteristics so that only spin rotations can occur. The first matching frequency, found in $Ni_{2-x}Zn_{x}Y$ - rubber composites, which was higher than that of spin rotational resonance, increased with spin rotational resonance frequency. It is also found that the second matching frequency is independent of spin rotational resonance frequency. Based on these findings, it could be concluded that the microwave absorbing characteristics were caused by only one type of resonance, the spin rotational resonance.

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The Characteristics of Electromagnetic Wave Absorption in Sintered and Composite Ni-Zn Ferrites (니켈-아연 페라이트 소결체와 복합체의 전파흡수특성)

  • 조성백;오재희
    • Journal of the Korean Ceramic Society
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    • v.32 no.1
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    • pp.25-30
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    • 1995
  • The frequenc dependence of magnetic permeability($\mu$r) and dielectric constant($\varepsilon$r) in MHz-GHz frequency range and their relationships with microwave absorbing properties were investigated in sintered and composite Ni-Zn ferrites, respectively. It was confirmed that zero reflection condition was required the real parts of permeability and permittivity in sintered specimen, and the complex permeability, permittivity and dielectric loss tangent in composite specimen. The real part of permittivity varied with the replacement of nickel by manganese in sintered Ni-Zn ferrite. Therefore, we could control the matching frequency and matching thickness.

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