• 한국건설순환자원학회논문집
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• 제3권3호
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• pp.220-227
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• 2015

초고성능 콘크리트(UHPC)는 낮은 물-결합재비를 바탕으로 다량의 강섬유, 실리카퓸, 충전재 및 고성능 감수제를 사용한다. UHPC는 높은 역학적 성능을 가지는 대신 실리카퓸을 사용함에 따라 점성이 증가되며 고가의 재료를 다량으로 사용하기 때문에 제조비용이 일반 콘크리트에 비하여 고가이다. 따라서 본 연구에서는 180MPa급 UHPC의 점성 저하를 위하여 실리카퓸 대신 지르코늄 실리카퓸(Zr)을 사용한 UHPC의 고성능 감수제(SP)의 사용량 및 종류, 충전재 크기에 따른 공학적 특성을 분석하였다. 그 결과 W/B 20%, Zr 100% 사용, SP-L 사용량 2~3%, 강섬유 혼입율 1.5 vol.%이고 $4{\mu}m$의 충전재를 사용하는 Zr-UHPC의 경우 기존의 실리카퓸을 사용한 배합에 비하여 우수한 유동성을 발현하고 압축강도 180MPa이상 확보 하였다. 또한 기존 UHPC 대비 33%의 제조비용 절감이 가능한 것으로 분석되었다.

• 한국산업보건학회지
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• 제16권3호
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• pp.254-263
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• 2006

Manganese has a role as both toxic and essential in humans. Manganese is also an essential component in the welding because it increases the hardness and strength, prevents steel from cracking of welding part and acts as a deoxidizing agent to form a stable weld. In this study, manganese generation rate and its content was determined in flux cored arc welding on stainless steel. Domestic two products and foreign four products of flux cored wires were tested in the well designed fume generation chamber as a function of input power. Welding fume was measured by gravimetric method and metal manganese was determined by inductively coupled plasma-atomic emission spectrophotometer. The outer shell of the flux cored wire tube and inner flux were analyzed by scanning electron microscopy to determine their metal compositions. Manganese generation rate($FGR_{mn}$) was increased as the input power increased. It was 16.3 mg/min at the low input power, 38.1 mg/min at the optimal input power, and up to 55.4 mg/min at the high input power. This means that $FGR_{mn}$ is increased at the work place if welder raise the current and/or voltage for the high productivity. The slope coefficient of $FGR_{mn}$ was smaller than that of the generation rate of total fume(FGR). Also, the correlation coefficient of $FGR_{mn}$ was 0.65 whereas that of FGR is 0.91. $FGR_{mn}$ was equal or higher in the domestic products than that of the foreign products although FGR was similar. From the electron microscopic analytical data, we concluded that outer shell of the wire was composed mainly of iron, chromium, nickel and less than 1.2 % of manganese. There are many metal ingredients such as iron, silica, manganese, zirconium, titanium, nickel, potassium, and aluminum in the inner flux but they were not homogeneous. It was found that both $FGR_{mn}$ and content of manganese was higher and more varied in domestic flux cored wires than those of foreign products. To reduce worker exposure to fumes and hazardous component at the source, further research is needed to develop new welding filler materials that improve the quality of flux cored wire in respect to these points. Welder should keep in mind that the FGR, $FGR_{mn}$ and probably the generation rate of other hazardous metals were increased as the input power increase for the high productivity.