• 한국세라믹학회지
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• 제32권12호
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• pp.1401-1407
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• 1995

Zirconia powder coated with alumina was prepared by hydrolysis of alumina butoxide. The coated powder was obtained by a hydrolysis reaction between the adsorbed water on the surface of zirconia particles and aluminum sec-butoxide. Amorphous aluminum hydroxide was uniformly coated on the surface of zirconia particles with the thickness of about 30 nm. The shape and distribution of aluminum hydroxide was varied with an existence of surfactant. The coated layer of aluminum hydroxide consists of the fine particle size, and the zirconia powder coated by alumina hydroxide have the large specific surface area of 120 $m^2$/g, compared with that of starting zirconia powder.

• 한국진공학회지
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• 제6권S1호
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• pp.160-165
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• 1997

Yttria stabilized zirconia coating is an attractive material for several engineering applications. In order to produce coatings with consistent and reliable performance it is important to understand the influence of spraying parameters on the coating properties and optimize the spraying parameters. In this paper the low pressure plasma spray(LPPS) deposition of as-received zirconia powder has been investigated using simple one-factor-at-a-time approach. The deposition efficiency was chosen to evaluate the melting characteristics of the as-received zirconia powder. The results obtained indicated that the deposition efficiency of zirconia powder is very sensitive to the spraying parameters such as plasma gas flow rate and ranges from 24% to 57% The microstructure and the phase composition of zirconia coating deposited with the different plasma spraying parameters were also examined by SEM and XRD respectively. The relationship between deposition efficiency and the microstructure of zirconia coating was discussed.

• 한국신뢰성학회지:신뢰성응용연구
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• 제15권3호
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• pp.216-221
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• 2015

Sintering behavior of 3%yttria-stabilized zirconia was comparatively studied using a spray-dried powder produced by a domestic and global company. Quality of the sintered block was analysed in terms of relative density, shrinkage rate, grain growth, hardness, and fracture toughness. Relative density, shrinkage rate, and hardness value of the finally sintered block was similar between domestic and global zirconia powder, respectively. But, flexural strength of the domestic powder specimen was about 70% of the sintered block produced by using a global powder. The poor sintering quality of the domestic powder was discussed in relation with compressibility of the spray-dried granule-type powder and the amount of monoclinic phase in the as-received powder.

• 한국세라믹학회지
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• 제24권4호
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• pp.357-363
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• 1987

This study consists of two powder preparation process. One is that the synthesized Forsterite at 1400$^{\circ}C$ mixed with Zirconia powder. Another, theoretical Forsterite composition mixed with Zirconia. These two Forsterite bodies were heat-treated at 1400$^{\circ}C$, 1450$^{\circ}C$. Synthesized Foresterite composition showed higher density, strength than Forsterite composite which was directly mixed with Zirconia KIC value was measured by Microhardness Indentation method. It shows the highest value when 15 weight percent Zirconia dispersed.

• 한국분말재료학회지
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• 제14권5호
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• pp.309-314
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• 2007

Zirconia powders with nano size pores and high specific surface areas were synthesized via aqueous precipitation and hydrothermal synthetic method using $ZrOCl_28H_2O$ and $NH_4OH$ under pH=11 and ambient condition. By this reaction. zirconia hydrate $(ZrO_x(OH)_{4-2x})$ was primarily synthesized and the obtained zirconia hydrate was heat treated hydrothermally using an autoclave at various temperatures under pH=11. X-ray diffraction, Scanning electron microscopy, Energy dispersive X-ray spectroscopy, FT-IR, Raman, Particle size analysis, DTA-TG, and BET techniques were used for the characterization of the powder. The synthesized zirconia showed an amorphous phase, however, the phase was transformed to the crystalline state during the hydrothermal process. The observed crystalline phase above $160^{\circ}C$ was a mixed phase of monoclinic and tetragonal zirconia. By the BET analysis, it was found that the specific surface area was ranged in $126{\sim}276m^2/g$ and the zirconia had the cylindrical shaped pores with average diameter of $2{\sim}7nm$.

• 한국세라믹학회지
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• 제49권6호
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• pp.566-574
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• 2012

Porous zirconia ceramics are widely considered to be important due to their unique properties and potential applications. In this paper, we propose a novel approach to produce porous zirconia ceramics. The linear shrinkage of the prepared porous zirconia ceramics could be controlled to 4% by incorporating pre-sintered zirconia granules and hollow polymeric spheres. We also investigated the effect of pre-sintered zirconia granules on the microstructure and the properties, such as the porosity, pore distribution, and bending strength of the porous zirconia ceramics.

• 한국재료학회지
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• 제23권8호
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• pp.441-446
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• 2013

There is increasing interest in zirconia as a dental material due to its aesthetics, as well as the exceptionally high fracture toughness and high strength that are on offer when it is alloyed with certain oxides like yttria. In recent years, many solution based chemical synthesis methods have been reported for synthesis of zirconia, of which the sol-gel method is considered to be best. Here, we synthesize zirconia by a sol gel assisted precipitation method using either PEG or PVA as a stabilizing agent. Zirconia sol is first synthesized using the hydrothermal method. We used NaOH as the precipitating agent in this method because it is easy to remove from the final solution. Zirconium and yttrium salts are used as precursors and PEG or PVA are used as stabilizers to separate the metal ions. The resulting amorphous zirconia powder is calcined at $900^{\circ}C$ for 2 h to get crystallized zirconia. XRD analysis confirmed the partially stabilized zirconia synthesis in all the synthesized powders. SEM was taken to check the morphology of the powder synthesized using either PEG or PVA as a stabilizing agent and finally the transparency was calculated. The results confirmed that the powder synthesized with 10 % PVA as the stabilizing agent had highest percentage of transparency among all the synthesized powder.

• 한국분말재료학회지
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• 제18권6호
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• pp.502-509
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• 2011

In this study, a novel-processing route for fabricating microcellular zirconia ceramics has been developed. The proposed strategy for making the microcellula zirconia ceramics involved hollow microspheres as pore former. Compared to conventional dense microspheres pore former, well-defined pore structured zirconia ceramics were successfully fabricated. Effects of hollow microsphere content and sintering temperature on microstructure, porosity, pore distribution, and strength were investigated in the processing of microcellular zirconia ceramics.

• 대한기계학회논문집A
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• 제21권8호
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• pp.1175-1187
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• 1997

Densification behavior and grain growth of zirconia powder compacts are investigated under high temperature. Experimental data are obtained for zirconia powder under pressureless sintering, sinter forging and hot isostatic pressing. The constitutive equations by Kwon et al. are used for diffusional creep and grain growth. The constitutive equations by McMeeking and co-workers are also included to study the effect of power-law creep. These constitutive equations are implemented into a finite element program (ABAQUS) to investigate the friction effect during sinter forging and the canning effect during hot isostatic pressing. The agreements between experimental data and finite element results are very good in pressureless sintering and hot isostatic pressing, but not as good in sinter forging.

• 한국정밀공학회지
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• 제28권7호
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• pp.783-788
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• 2011

The recent development of bio-ceramic material is being studied in various bio-material engineering field. There are lots of technical difficulties because manufacturing or bonding technique are required bio-friendliness, cleanliness and persistence. Zirconia ceramic powder is cladded on Ti-6AI-4V metallurgically by laser cladding processing. Laser cladding system with powder feeding delivery is designed and manufactured for optimum processing condition. Increasing of manufacturing speed and good quality of clad layer are achieved by application of preheating of substrate before laser cladding. The thin dilution and good clad layer on the substrate are obtained for applications of bio-materials such as the dental materials and the articulated joints of human body.