• 제목/요약/키워드: Zircaloy cladding

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링 인장시험을 이용한 지르코늄 피복관의 반응도 사고(RIA) 시 연성 평가 (Evaluation of Ductility During Reactivity Initiated Accident for Zirconium Cladding using Ring Tension Test)

  • 김준환;이명호;최병권;방제건;정용환
    • 한국재료학회지
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    • 제15권2호
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    • pp.126-133
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    • 2005
  • Mechanical properties of zirconium cladding were evaluated by ring tension test to simulate Reactivity-Initiated Accident (RIA) at high burnup situation as an out-reactor test. Zircaloy-4 cladding was hydrided up to 1000 ppm as well as oxidized up to $100\;{\mu}m$ to simulate high-burnup situation. After simulated high-burnup treatment, ring tension test was carried out from 0.01 to 1/sec to correlate with actual RIA event. The results showed that ductility and circumferential toughness decreased with the hydrogen content and oxide thickness. Hydride generated inside cladding acted as brittle failure. Oxygen influenced cladding tube by the reduction of load bearing area, oxygen embrittlement, and thermal aging. Correlation between in-reactor RIA parameter like fuel enthalpy and out-reactor toughness was performed and showed a reasonable result.

중수로형 핵연료 피복관의 자동초음파탐상장치 개발 (Development of the Automated Ultrasonic Flaw Detection System for HWR Nuclear Fuel Cladding Tubes)

  • 최명선;양명승;서경수
    • Nuclear Engineering and Technology
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    • 제20권3호
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    • pp.170-178
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    • 1988
  • 중수로형 핵연료의 피복재로 사용되는 Zircaloy-4관의 결함검사를 위한 자동초음파 탐상 장치가 개발되었다. 이 장치에는 중심진동수가 14 MHz이고 대역폭이 11MHz인 집속 초음파 펄스를 사용한 수침 펄스-에코우 탐상기술과 특별히 고안된 시험수조 이송식 초음파주사 기술이 적용되었다 같은 크기와 방향을 갖는 관내외면 결함들을 같은 높이의 초음파 신호로 검출하기 위한 초음파 빔의 최적입사각은 26도이었다. Zircaloy-4피복관의 최대 허용 결함인, 깊이가 관두께의 10%인 0.04 mm이고, 길이가 0.76 mm인 축방향 및 길이가 0.38 mm인 원주방향 V형 인공결함들이 관내외면에 개재된 표준시험관을 사용하여 이 장치의 성능시험을 수행하였다. 그 결과 인공 표준시험관내의 모든 결함들을 매우 우수한 재현성을 갖고 분당 약 1m의 속도로 검출할 수 있었으며 이때의 신호 대 잡음 비는 축방향 결함에 대해서는 20 dB, 원주방향 결함에 대해서는 12 dB 이상이었다.

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Mechanism of Environmentally-Induced Stress Corrosion Cracking of Zr-Alloys

  • Park, Sang Yoon;Kim, Jun Hwan;Choi, Byung Kwon;Jeong, Yong Hwan
    • Corrosion Science and Technology
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    • 제6권4호
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    • pp.170-176
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    • 2007
  • Iodine-induced stress corrosion cracking (ISCC) properties and the associated ISCC process of Zircaloy-4 and an Nb-containing advanced nuclear fuel cladding were evaluated. An internal pressurization test with a pre-cracked specimen was performed with a stress-relieved (SR) or recrystallized (RX) microstructure at $350^{\circ}C$, in an iodine environment. The results showed that the $K_{ISCC}$ of the SR and RX Zircaloy-4 claddings were 3.3 and 4.8MPa\;m^{0.5}, respectively. And the crack propagation rate of the RX Zircaloy-4 was 10 times lower than that of the SR one. The chemical effect of iodine on the crack propagation rate was very high, which was increased $10^4$ times by iodine addition. Main factor affecting on the micro-crack nucleation was a pitting formation and its agglomeration along the grain boundary. However, this pitting formation on the grain-boundary was suppressed in the case of an Nb addition, which resulted in an increase of the ISCC resistance when compared to Zircaloy-4. Crack initiation and propagation mechanisms of fuel claddings were proposed by a grain boundary pitting model and a pitting assisted slip cleavage model and they showed reasonable results.

HIGH TEMPERATURE OXIDATION OF NB-CONTAINING ZR ALLOY CLADDING IN LOCA CONDITIONS

  • Chuto, Toshinori;Nagase, Fumihisa;Fuketa, Toyoshi
    • Nuclear Engineering and Technology
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    • 제41권2호
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    • pp.163-170
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    • 2009
  • In order to evaluate high-temperature oxidation behavior of the advanced alloy cladding under LOCA conditions, isothermal oxidation tests in steam were performed with cladding specimens prepared from high burnup PWR fuel rods that were irradiated up to 79 MWd/kg. Cladding materials were $M5^{(R)}$ and $ZIRLO^{TM}$, which are Nb-containing alloys. Ring-shaped specimens were isothermally oxidized in flowing steam at temperatures from 1173 to 1473 K for the duration between 120 and 4000s. Oxidation rates were evaluated from measured oxide layer thickness and weight gain. A protective effect of the preformed corrosion layer is seen for the shorter time range at the lower temperatures. The influence of pre-hydriding is not significant for the examined range. Alloy composition change generally has small influence on oxidation in the examined temperature range, though $M5^{(R)}$ shows an obviously smaller oxidation constant at 1273 K. Consequently, the oxidation rates of the high burnup $M5^{(R)}$ and $ZIRLO^{TM}$ cladding are comparable or lower than that of unirradiated Zircaloy-4 cladding.

Development of Cr cold spray-coated fuel cladding with enhanced accident tolerance

  • Sevecek, Martin;Gurgen, Anil;Seshadri, Arunkumar;Che, Yifeng;Wagih, Malik;Phillips, Bren;Champagne, Victor;Shirvan, Koroush
    • Nuclear Engineering and Technology
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    • 제50권2호
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    • pp.229-236
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    • 2018
  • Accident-tolerant fuels (ATFs) are currently of high interest to researchers in the nuclear industry and in governmental and international organizations. One widely studied accident-tolerant fuel concept is multilayer cladding (also known as coated cladding). This concept is based on a traditional Zr-based alloy (Zircaloy-4, M5, E110, ZIRLO etc.) serving as a substrate. Different protective materials are applied to the substrate surface by various techniques, thus enhancing the accident tolerance of the fuel. This study focuses on the results of testing of Zircaloy-4 coated with pure chromium metal using the cold spray (CS) technique. In comparison with other deposition methods, e.g., Physical vapor deposition (PVD), laser coating, or Chemical vapor deposition techniques (CVD), the CS technique is more cost efficient due to lower energy consumption and high deposition rates, making it more suitable for industry-scale production. The Cr-coated samples were tested at different conditions ($500^{\circ}C$ steam, $1200^{\circ}C$ steam, and Pressurized water reactor (PWR) pressurization test) and were precharacterized and postcharacterized by various techniques, such as scanning electron microscopy, Energy-dispersive X-ray spectroscopy (EDX), or nanoindentation; results are discussed. Results of the steady-state fuel performance simulations using the Bison code predicted the concept's feasibility. It is concluded that CS Cr coating has high potential benefits but requires further optimization and out-of-pile and in-pile testing.