• Title/Summary/Keyword: Zircaloy

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원자로 조사 Zircaloy-4의 $500^{\circ}C$ 공기중 산화거동 연구

  • 유길성;김건식;민덕기;노성기;김은가
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05c
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    • pp.341-346
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    • 1996
  • 사용후핵연료에 대한 장기건식저장과 관련하여 원자로에서 조사된 사용후 핵연료피복관에 대한 산화시험을 공기분위기에서 수행하였다. 피복관 시료의 50$0^{\circ}C$ 공기중 산화시험 결과 산화 초기에 급격한 산화율을 보였으며, 이 후 천이점까지 느리게 산화가 진행되다가 천이 후에는 선형적으로 급격히 무게가 증가하는 지르코늄 합금의 수증기 및 공기중에서의 전형적인 산화양상을 나타내었다. 시편별로는 가장 두꺼운 노내 산화막을 가진 시편이 가장 높은 산화율을 나타내었으며, 노내 산화시 천이점에 근접한 시편들이 가장 낮은 산화율을 보였다. 산화율이 가장 높은 시편의 천이후 영역에서의 산화율은 $\Delta$W = 0.74 t + 38.61과 같은 관계식으로 표현될 수 있었다. 이 때 $\Delta$W는 무게이득(mg/dm$^2$)이고 t는 산화시간(h)을 나타낸다. 시험에 사용된 피복관의 단위 산화막두께(l$\mu$m)에 대한 산화무게증가량은 약 13.4mg/dm$^2$으로 나타났다. 이러한 결과들은 사용후핵연료 중간저장 시설 및 저장캐스크의 설계 전산코드 작성 및 저장시설의 운영에 관련되어 기반자료로 활용될 수 있을 것이다.

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경수로용 핵연료 피복관의 부식특성

  • 김성호;백종혁;유호식;정진곤;이종철;김양은;배성만
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05c
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    • pp.238-243
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    • 1996
  • 현재 상용 공급되고 있는 4종의 경수로 핵연료 피복관에 대해 노외 부식특성 시험을 수행하여 그 특성을 비교하였다. 이중 3종의 피복관은 제조공정을 달리하여 제조된 low tin Zircaloy-4 (피복관 A, B, C)이며, 1종은 Nb이 첨가된 Zr 합금 (피복관 D)이었다. 증류수내 Li 함량을 2.2 ppm, 30 ppm, 220 ppm으로 변화시키며 부식시험을 수행한 결과 최종 pilgering시 낮은 Q 인자와 높은 열처리 온도로 제조된 피복관 A의 내부식성이 대체로 우수하였으며, 220 ppm Li 수용액에서는 Nb이 첨가된 피복관의 내부식성이 매우 우수한 것으로 나타났다. Li 첨가의 영향을 보면 2.2 ppm Li 첨가시에는 증류수와 거의 동일한 부식거동을 나타내고 있으나 30 ppm Li 첨가시에는 부식이 가속되고 있었으며, 220 ppm Li으로 Li 함량이 크게 증가하였을 때 부식속도도 크게 증가하였다. 수소흡수율은 피복관 A에서 가장 높았으며, 피복관 D가 가장 낮은 값을 나타내었다.

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고연소도 핵연료 피복관 개발 연구

  • 정용환;김창호;김경호;김성호;백종혁;김영석;국일현
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05c
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    • pp.259-264
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    • 1996
  • 상용 Zircaloy-4보다 성능이 우수한 고연소도용 Zr 신합금을 개발하는 것을 목표로 외국에서 개발중인 12종의 신합금 피복관에 대한 특성평가, 부식기구 규명 연구, 국내에서 제조된 Zr 신합금의 특성평가를 실시하였다. 외국 피복관의 부식특성 평가로 부터 Sn을 0.6-1.0 wt.% 첨가하고 Nb을 0.4 wt.% 첨가하는 것이 내식성 관점에서 바람직함을 알 수 있었다. 여러 가지 LiOH용액에서의 부식기구 연구를 통해 수소화물이 부식가속의 원인임을 알 수 있었으며 수소화물 형성을 억제하는데는 Nb첨가가 효과적인 것으로 나타났다. 이와 같은 연구결과를 토대로 신합금의 개발방안을 수립하였으며 예비적으로 합금을 설계. 제조하여 특성시험을 실시한 결과, Zr-Sn-Nb-FeCr 합금이 우수한 내식성을 보이며 Fe, Mo는 강도 증가 효과가 큰 것으로 나타났다. 이러한 연구결과를 종합적으로 평가하여 신합금을 설계하고 노외성능 평가를 통해서 신합금을 선정한후, 단계적으로 하나로를 이용한 노내성능 평가를 실시할 예정이다.

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A Study on the Characteristics of Zr-4 End Cap Welded Joints Using Resistance Upset Welding (저항업셋 용접법을 이용한 Zr-4 End Cap용접부의 특성에 관한 연구)

  • 박철주;김형수;이영호;강원석
    • Journal of Welding and Joining
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    • v.10 no.4
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    • pp.240-249
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    • 1992
  • The objective of this study is to investigate the characteristics of welded joints on the Zircaloy-4 resistance upset welding for HWR(Heavy Water reactor)fuel rods. To estimate the characteristics of welded joints, the various tests were performed on the test coupons systematically with a wide range of each welding parameters in terms of a tensile test, burst test, knoop hardness test and metallography. Major results obtained in this study are as follows: 1. The tube and machined with 120.deg. projection was the reliable weld joint design for the nuclear fuel rod end cap welding. 2. As the weld current and the amount of upset increased linearly with increasing welding main heat input, it could make an estimate of their variation in accordance with the phase shift control. 3. It was found that an increase in squeeze force has an effect on the upset contour of welded joint because the amount of upset were increased by the change of squeeze force.

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Welding Quality Analysis on the Welding Parts of the Zircaloy Spacer Grid Assembly for PWR Fuel Assembly (경수로 원전연료용 지르칼로이 지지격자체의 용접품질 분석)

  • Song, Gi-Nam;Kim, Su-Seong;Han, Hyeong-Jun
    • Proceedings of the KWS Conference
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    • 2006.10a
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    • pp.125-127
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    • 2006
  • A spacer grid assembly, which is an interconnected array of slotted grid straps and is welded at the intersections to form an egg crate structure, is one of the main structural components of the nuclear fuel assembly for pressurized water reactors(PWRs). The spacer grid assembly is structurally required to have enough buckling strength under various kinds of lateral loads acting on the nuclear fuel assembly so as to keep the nuclear fuel assembly straight. To meet this requirement, it is necessary to weld the welding parts carefully and precisely. In this study, weld qualities such as, weld bead size, penetration, spatter, etc. manufactured by various welders were compared and analyzed. Comparison results show that the weld qualities could be improved by selecting the optimal welding condition and also improving the welding technique.

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The Development of Evaluating Tensile Property Method used the Single Notched Ring Test (단일노치 링시험편을 이용한 인장 특성 평가방법 개발)

  • Bae, Bong-Kook;Koo, Jae-Mean;Seok, Chang-Sung
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.322-327
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    • 2003
  • In this study, the single notched specimen which was proposed the previous study was used to evaluate of the transverse tensile property of zircaloy cladding. The single notched specimen has notches which give stress intensity effect, so both FEM and experiment are needed for the same time. Take a coincidence of tensile behavior about both FEM and experiment, then obtain stress and strain from FEM only. The influence of notch was estimated by comparing the result of experimental, FEM. Then the relationship between stress-strain and displacement was evaluated.

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Technology of the End Cap Laser Welding for Irradiation Fuel Rods (조사연료봉 봉단마개의 레이저용접기술)

  • 김수성;이정원;고진현;이영호
    • Journal of Welding and Joining
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    • v.21 no.6
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    • pp.20-25
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    • 2003
  • Various welding methods such as Gas Tungsten Arc Welding(GTAW), magnetic force electrical resistance welding and Laser Beam Welding(LBW) are now available for end cap closure of nuclear fuel rods. Even though the resistance and GTA welding processes are widely used in manufacturing commercial fuel rods, they can not be recommended for the remote seal welding of fuel rods in the hot cell Facility due to the complexity of the electrode alignment, the difficulty in replacing parts in a remote manner and the large heat input for the thin sheath. Therefore, the Nd:YAG laser system using optical fiber transmission was selected for the end cap welding of irradiation fuel rods in the hot cell. The remote laser welding apparatus in the hot cell Facility was developed using a pulsed Nd:YAG laser of 500 watt average power with an optical fiber transmission. The weldment quality such as microstructure and mechanical strength was satisfactory. The optimum conditions of laser welding for encapsulating irradiation fuel rods in the hot cell were obtained.

Dynamic Crush Strength Analysis of a Spacer Grid Assembly for a LWR Nuclear Fuel Assembly(II) (경수로 핵연료 지지격자의 동적 좌굴강도 해석(II))

  • Song, Kee-Nam;Lee, S.B.
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.590-592
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    • 2008
  • A spacer grid is one of the most important structural components in a LWR nuclear fuel assembly. The primary considerations are to provide a Zircaloy spacer grid with crush strength sufficient to resist design basis loads, without significantly increasing pressure drop across the reactor core. In this study, the dynamic crush strength analysis and test are carried out for the specimens of a spacer grid assembly.

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A Study on the Micro-Focus X-Ray Inspection for Confirming the Soundness of End Closure Weld of DUPIC Fuel Elements (DUPIC 핵연료봉 봉단 용접부 건전성 확인을 위한 미세초점 X-선 투과시험에 관한 연구)

  • 김웅기;김수성;이정원;양명승
    • Journal of Welding and Joining
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    • v.19 no.1
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    • pp.88-94
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    • 2001
  • DUPIC (Direct use of spent PWR fuel in CANDU reactors) nuclear fuel is a CANDU fuel fabricated remotely from spent PWR fuel materials in a hot cell. The soundness of the end closure welds of nuclear fuel elements is an important factor for the safety and performance of nuclear fuel. To evaluate the soundness of the end closure welds of DUPIC fuel element, a precise X-ray inspection system is developed using a micro-focus X-ray generator with an image intensifier and a real time camera system. The fuel elements made of Zircaloy-4 and stainless steel by an Nd:YAG laser welding and a TIG welding aye inspected by the developed inspection system. The soundness of the welds of the fuel elements was confirmed by the X-ray inspection process, and the irradiation test of DUPIC fuel elements has been successfully completed at the HANARO research reactor.

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Corrosion model for Zircaloy-4 Cladding in PWR

  • Lee, Byung-Ho;Yoo, Yeon-Jong;Kook, Yang-Hyun;Sohn, Dong-Seong
    • Proceedings of the Korean Nuclear Society Conference
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    • 1999.05a
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    • pp.279-279
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    • 1999
  • To improve the corrosion model of the fuel performance analysis code COSMOS, a model was developed considering thermohydraulic phenomena and the effect of water chemistry and low Sn in the alloy composition on the corrosion behavior. It is assumed that the lithium enhancement factor influences the corrosion behavior only if the subcooled void is present in the coolant. The developed model was verified with the database obtained from Grohnde and Ringhals 3 reactors. Comparison of predicted oxide thickness with measured data showed the applicability of COSMOS code to analyze the cladding oxidation. In the future, the effect of the hydride in the cladding and the precipitate changes due to irradiation should be included.cluded.

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