• Title/Summary/Keyword: Zinc plating

Search Result 55, Processing Time 0.031 seconds

Separation of Zinc Ion from Metal Plating Wastewaters by Reverse Osmosis Membrane (Membrane을 이용한 도금폐수 중 아연이온의 분리에 관한 연구)

  • 장자순;이효숙;정헌생;이원권
    • Membrane Journal
    • /
    • v.4 no.2
    • /
    • pp.106-112
    • /
    • 1994
  • The ultrafiltration(UF) and reverse osmosis(RO) tests for a model metal plating wastewater prepared with zinc sulfate, showed the zinc ion rejection coefficient of over 99% and the permeate flux of $1.49 {\times} 10^{-3}cm/sec$ at pH = 8.3. The effect of cyanide on the zinc removal was investigated. When the amount of cyanide addition was same the zinc content, the zinc was removed over 99% and the cyanide was excluded about 93%. The addition of the surfactants such a LAS-Na and EDTA-Na was found to reduce the permeate flux down to $0.76 {\times} 10^{-3}cm/sec$ at the RO membrane.

  • PDF

Effect of current density, temperature and electrolyte concentration on Composition of Zn-Ni Electrodeposits (Zn-Ni도금의 합금화에 미치는 전류밀도, 온도와 전해액농도의 영향)

  • Kang, Soo Young
    • Journal of the Korea Convergence Society
    • /
    • v.8 no.11
    • /
    • pp.307-312
    • /
    • 2017
  • In the industry, galvanizing using the principle of sacrificial anode is used Zn-Ni alloy plating was developed as one of the measures to increase the corrosion resistance rather than pure zinc plating. The alloy plating layer has a corrosion resistance of 4-5 times that of the pure zinc plating layer, so that it is applied to automotive parts requiring high corrosion resistance even though the plating cost is high. The amount of Zn-Ni alloy plating solution is a sulfuric acid bath, a chlorinated bath, an alkali bath, and an ammonia bath. Here, the influence of the electrolytic conditions on the composition of the alloy plating in the chloride bath was investigated. The results are explained by the cathode overvoltage and the diffusion coefficient. In general, as the overvoltage of the cathode increases, the concentration polarization becomes more important than the activation polarization. The concentration polarization is determined by element diffusion in the diffusion layer. That is, as the overvoltage of the cathode increases, the Zn content having a large diffusion coefficient increases.

Study of Plating Layer Formation of Lightweight Magnesium Alloy (AZ31B) (경량 마그네슘 합금(AZ31B)의 도금층 형성 연구)

  • Choi, Kyoung-Su;Choi, Soon-Don;Min, Bong-Ki;Lee, Seung-Hyeon;Sin, Hyeon-Jun
    • Journal of the Korean institute of surface engineering
    • /
    • v.44 no.6
    • /
    • pp.239-245
    • /
    • 2011
  • Magnesium alloys is the lightest by structural metals, but it is not good corrosion resistant because of pit, void. Particularly, AZ31B magnesium alloy sheets that have slag, scratch by rolling process indicate some defects. The objective of this research is to perform uniform plating on AZ31B by studying etching and zincate process. Especially, zincate treatment by zinc salt and pyrophosphate is the most important in the decoration plating. Dissolution of magnesium is reduced by the formation of uniform zinc conversion layer during strick and post process, which decreases defects for plating process.

Study on Electroless Black Ni-Zn Plating Using Hydrazine as a Reducing Agent (히드라진에 의한 무전해 흑색 니켈-아연 합금 도금에 대한 연구)

  • 오영주;정원용;이만승
    • Journal of the Korean institute of surface engineering
    • /
    • v.36 no.5
    • /
    • pp.393-397
    • /
    • 2003
  • The effects of the composition and additives on the blackening and deposition rate of electroless Ni-Zn plating have been examined. Hydrazine resulted in lower sheet resistance of the deposit than sodium hypophosphite. Zinc concentration more than 15 wt% and small amount of ammonium sulfate in the deposits were needed in obtaining Ni-Zn deposit with a black color. An optimum condition was obtained for the black Ni-Zn deposit at an appreciable deposition rate.

Effect of the electrolyte composition and the plating condition on the hardness of zinc deposit in the sulfate bath (황산아연욕에서 도금층 경도에 미치는 욕조성 및 도금조건의 영향)

  • 김명수;김영근
    • Journal of the Korean institute of surface engineering
    • /
    • v.33 no.5
    • /
    • pp.356-364
    • /
    • 2000
  • Factors that affect the hardness of the zinc electrodeposits in the sulfate electrolyte were investigated. The hardness of zinc deposit was enhanced by increasing the concentration of impurities such as iron and nickel in the bath that changed the crystallographic orientation of the zinc deposit from the strong basal plane to the random orientation. The increase of the concentration of sodium sulfate and current density in iron contained bath improved the hardness of zinc deposit because those were easily codeposited in zinc layer. However the increase of the concentration of sodium sulfate up to 80g/$\ell$ in the bath darkened the surface of zinc electrodeposits due to change of morphology by the codeposition of iron.

  • PDF

Electrochemical Study of UBM Ni Prepared by Electroless Plating (무전해 도금법을 이용한 UBM 니켈 형성의 전기화학적 고찰)

  • Lee Jae Ho;Lee In Geon;Gang Tak;Kim Nam Seok;O Se Yong
    • Proceedings of the International Microelectronics And Packaging Society Conference
    • /
    • 2003.11a
    • /
    • pp.118-121
    • /
    • 2003
  • The electrochemical behaviors of UBM nickel were investigated. Electrode potential has been changed with the surface composition. Zinc is dissolved into the solution immediately after immersion. Electrode potential has three distinct regions: Zinc dissolution region, transient region and nickel plating region. The effects additives on electrode potential and polarization curves were also investigated. The addition of suppressor lowered the current density which is related with deposition rate.

  • PDF

Numerical Analysis on Hood Shape Improvement of Local Ventilation System (국소환기시스템의 후드형상 개선에 따른 수치해석)

  • Yi, Chung-Seub;Jang, Sung-Cheol;Choi, Joo-Hong
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
    • /
    • v.21 no.4
    • /
    • pp.260-265
    • /
    • 2009
  • The aim of this study is to remove crack on a ventilation device at the suction part of zinc plating factory, and the main point is making optimum configuration by improving an existing hood system. The result shows that existing hood system has problem with duct configuration, angle and reducer. Model-5 shows lowest pressure difference as meaning of suction capability. The hood inlet surface has most uniform suction capability.

A Study on the Safety Assessment of Zinc Plating Process (아연도금공정의 안전성평가)

  • Rhie, Kwang-Won;Park, Moon-Hee
    • Journal of the Korean Society of Safety
    • /
    • v.18 no.4
    • /
    • pp.148-154
    • /
    • 2003
  • There are now the plating process that have many hazardous factor cause of the using numerous noxious chemical and bad working environments. The purpose of the study is to make a selection of suitable safety evaluation method that can analyze and righteously find with numerous hazardous factor of the plating process. And another purpose is to systematically adjust the risk of plating process by comprehension of the role of process, equipment, and source material. Therefore, these studies are carried out in the following three investigations of this report. The first research understands the injurious human health and environment by analyzing hazardous material based on the MSDS. To evaluate the safety of process and compartment, the second research is proposed the security secure counterproposal by using the FMEA and the HAZOP. The final research is devoted to systematically analyze the hazard by applying for reasonable guide word and doing the HAZOP for hazardous factor in specific process.