• 멤브레인
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• 제4권2호
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• pp.106-112
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• 1994

$ZnSo_4{\cdot}7H_2O$에 의한 모델폐수에서 Zn 농도 및 pH를 변화하여 역삼투 실험하였고, Zn용액의 pH에 따라 아연의 제거율은 상당히 변화하였고, pH 3.0~11.5 범위에서 실험한 바 pH 8.3일 때가 아연제거율은 99.9% 이상, 투과 속도는 $1.49 {\times} 10^{-3}cm/sec$로 가장 큰 값을 보였다. 아연모델폐수에 Cyanide를 아연농도와 동량으로 첨가하였을 때, 아연은 99%, Cyanide는 93% 정도 제거가 가능하였다. 또한 첨가제로 음이온계면활성제 등을 첨가하여 실험한 결과, Membrane에서의 투과속도가 $0.76 {\times} 10^{-3}cm/sec$로 현저히 감소하였다.

• 한국융합학회논문지
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• 제8권11호
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• pp.307-312
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• 2017

산업계에서는 희생양극의 원리를 이용한 아연도금이 사용되고 있다. 순수아연도금보다 내식성을 증가시키기 위한 방안의 하나로 Zn-Ni 합금도금이 개발되었다. 합금 도금층은 순 아연 도금층에 비하여 4-5배의 내식성을 가지고 있어서 도금 단가가 높음에도 불구하고 고내식성을 요구하는 자동차 부품 등에 적용이 증가되고 있다. Zn-Ni 합금도금액은 황산욕, 염화욕, 알칼리욕과 암모니아욕 등이 사용되고 있다. 여기에서는 염화욕에서 합금도금의 조성에 미치는 전해조건의 영향을 조사하였다. 그 결과는 음극 과전압 및 확산계수에 의해 설명하였다. 일반적으로 음극의 과전압이 증가함에 따라 활성화분극보다 농도분극이 중요하게 된다. 농도분극은 확산 층 내의 원소 확산에 의해 결정된다. 즉 음극의 과전압이 증가함에 따라 확산계수가 큰 Zn 함량이 증가한다.

• 한국표면공학회지
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• 제44권6호
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• pp.239-245
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• 2011

Magnesium alloys is the lightest by structural metals, but it is not good corrosion resistant because of pit, void. Particularly, AZ31B magnesium alloy sheets that have slag, scratch by rolling process indicate some defects. The objective of this research is to perform uniform plating on AZ31B by studying etching and zincate process. Especially, zincate treatment by zinc salt and pyrophosphate is the most important in the decoration plating. Dissolution of magnesium is reduced by the formation of uniform zinc conversion layer during strick and post process, which decreases defects for plating process.

• 한국표면공학회지
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• 제36권5호
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• pp.393-397
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• 2003

The effects of the composition and additives on the blackening and deposition rate of electroless Ni-Zn plating have been examined. Hydrazine resulted in lower sheet resistance of the deposit than sodium hypophosphite. Zinc concentration more than 15 wt% and small amount of ammonium sulfate in the deposits were needed in obtaining Ni-Zn deposit with a black color. An optimum condition was obtained for the black Ni-Zn deposit at an appreciable deposition rate.

• 한국표면공학회지
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• 제13권1호
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• pp.30-37
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• 1980

• 한국표면공학회지
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• 제33권5호
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• pp.356-364
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• 2000

Factors that affect the hardness of the zinc electrodeposits in the sulfate electrolyte were investigated. The hardness of zinc deposit was enhanced by increasing the concentration of impurities such as iron and nickel in the bath that changed the crystallographic orientation of the zinc deposit from the strong basal plane to the random orientation. The increase of the concentration of sodium sulfate and current density in iron contained bath improved the hardness of zinc deposit because those were easily codeposited in zinc layer. However the increase of the concentration of sodium sulfate up to 80g/$\ell$ in the bath darkened the surface of zinc electrodeposits due to change of morphology by the codeposition of iron.

• 한국마이크로전자및패키징학회:학술대회논문집
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• 한국마이크로전자및패키징학회 2003년도 기술심포지움 논문집
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• pp.118-121
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• 2003

The electrochemical behaviors of UBM nickel were investigated. Electrode potential has been changed with the surface composition. Zinc is dissolved into the solution immediately after immersion. Electrode potential has three distinct regions: Zinc dissolution region, transient region and nickel plating region. The effects additives on electrode potential and polarization curves were also investigated. The addition of suppressor lowered the current density which is related with deposition rate.

• 설비공학논문집
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• 제21권4호
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• pp.260-265
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• 2009

The aim of this study is to remove crack on a ventilation device at the suction part of zinc plating factory, and the main point is making optimum configuration by improving an existing hood system. The result shows that existing hood system has problem with duct configuration, angle and reducer. Model-5 shows lowest pressure difference as meaning of suction capability. The hood inlet surface has most uniform suction capability.

• 한국안전학회지
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• 제18권4호
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• pp.148-154
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• 2003

There are now the plating process that have many hazardous factor cause of the using numerous noxious chemical and bad working environments. The purpose of the study is to make a selection of suitable safety evaluation method that can analyze and righteously find with numerous hazardous factor of the plating process. And another purpose is to systematically adjust the risk of plating process by comprehension of the role of process, equipment, and source material. Therefore, these studies are carried out in the following three investigations of this report. The first research understands the injurious human health and environment by analyzing hazardous material based on the MSDS. To evaluate the safety of process and compartment, the second research is proposed the security secure counterproposal by using the FMEA and the HAZOP. The final research is devoted to systematically analyze the hazard by applying for reasonable guide word and doing the HAZOP for hazardous factor in specific process.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2000년도 춘계학술발표회 초록집
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• pp.37-37
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• 2000