• Corrosion Science and Technology
• /
• v.9 no.1
• /
• pp.29-33
• /
• 2010

Laser machining technique, which is used focusing pulse YAG laser beam irradiation was applied to form area ratio controlled model cut-edge on pre painted Zn coated steels. A corrosion behavior of formed model cut-edge was investigated by rest potential measurement in 1 mol $m^{-3}$ NaCl with and without 0.5 kmol $m^{-3}$ $H_3BO_4$/0.05kmol$m^{-3}$ $Na_2B_4O_7$. The rest potential showed almost constant value with fluctuations. The amplitude of fluctuations increased with exposed area of steel surface. White corrosion products of zinc oxide and simonkollite was formed after the experiments at the formed model cut-edge.

• Structural Engineering and Mechanics
• /
• v.82 no.2
• /
• pp.163-172
• /
• 2022

Zinc-rich epoxy (ZRE) is used to overcome corrosion problems in reinforced concrete (RC) beams and coat steel rebars to protect them from humidity and chlorides. An extra coating layer of Sikadur-31 epoxy (SDE) is utilised to increase bond strength because the use of ZRE reduces the bond strength between concrete and steel rebars. However, the low melting point of SDE indicates that concrete specimens are vulnerable to fire. An experimental investigation on flexural performance of RC beams incorporating ZRE-SDE coating of steel rebars that were destroyed by fire is performed in this study. Twenty beams of five concrete mixes with different cementitious contents were tested to compare fire exposure for coated and uncoated rebars of the same beams at room temperature and determine the optimal cementitious content. Scanning electron microscopy (SEM) was also applied to investigate characteristics of fired mixture samples. Results showed that the use of SDE-ZRE at room temperature improves flexural strengths of the five mixes compared with uncoated rebars with percentages ranging from 8.5% to 12.3%. All beams with SDE-ZRE lost approximately 50% of their flexural strength due to firing. Moreover, the mix incorporating SF (silica fume) of 15% and cement content of 400 kg/m³ introduces optimum behaviour compared with other mixes. All results were supported and verified by the SEM analysis and compressive strength of cubic specimens of the same mixes.

• Journal of Welding and Joining
• /
• v.24 no.4
• /
• pp.27-31
• /
• 2006

Optimization of process parameters for laser-arc hybrid welding process is intrinsically sophisticated because the process has three kinds of parameters-arc, laser and hybrid welding parameters. In this paper, the relationship between weldability and several process parameters such as laser beam-arc distance, electrode height, welding current and welding speed, were investigated by the full factorial experimental design. Weld quality was evaluated by using weight of spatters which is related with the pore area. It was found that the weld quality was increased with the increases in laser beam-arc distance and welding current, and decreased with the increases in electrode height and welding speed.

• Proceedings of the Korean Society of Precision Engineering Conference
• /
• 1994.10a
• /
• pp.163-168
• /
• 1994

Zinc coated steel sheets have been widely used in automotive industry. High power laser welding has been used as an excellent welding means for thin sheets. The welding residual stress, which was brought in laser welding, causes making weak the mechanical strength. The purpose of this study is to get the residual stress distribution in various laser welding condition by FEM and verify the results by X-Ray diffraction. Welding residual stresses have been calculated by thermal elasto-plastic analysis using finite element method. Form the results, it can be known that the laser welding condition affects to distribution of the residual stress.

• Journal of Welding and Joining
• /
• v.24 no.2
• /
• pp.71-78
• /
• 2006

It has been reported that good quality weld beads are not easily obtained during the $CO_2$ CW laser welding of primer coated plate. However, by introducing a small gap clearance in the lap position, the zinc vapor can escape through it and sound weld beads can be acquired. Therefore, this study examines for keyhole behavior by observing the laser-induced plasma and investigates the relation between keyhole behavior and formation of weld defect. Laser-induced plasma has accompanied with the vaporizing pressure of zinc ejecting from keyhole to surface of primer coated plate. This dynamic behavior of plasma was very unstable and this instability was closely related to the unstable motion of keyhole during laser welding. As a result of observing the composition of porosity, much of Zn element was found from inner surface of porosity. But Zn was not found from the dimple structure fractured at the weld metal. By analyzing of vaporizing element in laser welding, a component ratio of Zn was decreased by introducing a small gap clearance. Therefore we can prove that the major cause of porosity is the vaporization of primer in lap position. Mechanism of porosity-formation is that the primer vaporized from the lap position accelerates dynamic behavior of the key hole and the bubble separated from the key hole is trapped in the solidification boundary and romaines as porosity.

• Journal of Korean Society of Steel Construction
• /
• v.12 no.2 s.45
• /
• pp.167-175
• /
• 2000

An experimental research to evaluate the slip coefficient of high-strength slip-critical-type bolt connection of weathering steel plate has been performed in this paper. Experiments were performed with several surface conditions such as clean mill scale with hand or power brush cleaning, shot blast cleaned, inorganic zinc primer coated, and weather coated surfaces. Also, the relaxation of bolt clamping force was estimated during 500 hours. It was ascertained from the experiments that slip coefficients are greater than 0.40 in all faying surface conditions except mill scale surface with power brushing. The quantify of relaxation depended on the surface conditions and was $3{\sim}8%$, i.e., less than 10%.

• Corrosion Science and Technology
• /
• v.16 no.5
• /
• pp.241-246
• /
• 2017

The comparative results of corrosion testing in humid tropical atmosphere in rural and coastal areas for hot dipped zinc coatings are presented below. The test was conducted in outdoor conditions over a period of five years. The mass loss and other performance characteristics of two types of zinc coatings were evaluated, analysed and discussed in relation to the climatic and environmental parameters. The corrosion rates of the coatings exposed to coastal conditions were about three times higher than the corrosion rates appreciated in rural conditions. The data demonstrates that the corrosion process obeys an equation of the form $M=At^n$, where M is the loss of metal and t is the time of exposure. A and n are constants which values depend on the environmental characteristics and the physicochemical behavior of the corrosion products respectively. Corrosion is strongly influenced by atmospheric time of wetness (TOW) and airborne salinity. The nature and composition of corrosion products are also considered. Simonkolleite, a major crystalline phase, was found in the zinc corrosion products exposed to coastal conditions, while zinc hydroxide and zinc hydrosulfate are easily found in rural settings.

• Journal of Welding and Joining
• /
• v.34 no.4
• /
• pp.40-47
• /
• 2016

The Zn coating on automotive galvanized steel sheets can improve corrosion resistance. However, the boiling temperature of Zn is lower than the melting temperature of steel and it causes well-known spatter and porosity problem. One of most prominent solutions is a pretreatment of Zn coating by an additional welding arc prior to the main welding process. In this research, GTA and GMA are selected as heat sources for pretreatment and main welding processes, respectively. The authors suggested three possible mechanisms to reduce weld defects by the GTA pretreatment: (1) Formation of gap between the sheets; (2) Evaporation of Zn layer; (3) Oxidation of Zn layer. Among them, Zn Oxidation is the most important mechanism to reduce weld defects in the GTA-GMA hybrid process.

• Journal of the Korean institute of surface engineering
• /
• v.46 no.3
• /
• pp.116-119
• /
• 2013

To improve the corrosion resistance of an electrogalvanized steel sheet, we deposited magnesium film on it using a vacuum evaporation method and annealed the films at $250-330^{\circ}C$. The zinc-magnesium alloy is consequently formed by diffusion of magnesium into the zinc coating. From the anodic polarization test in 3% NaCl solution, the films annealed at $270-310^{\circ}C$ showed better corrosion resistance than others. In X-ray diffraction analysis, $ZnMg_2$ was detected through out the temperature range, whereas $Mg_2Zn_{11}$ and $FeZn_{13}$ were detected only in the film annealed at $310^{\circ}C$. The depth composition profile showed that the compositions of Mg at $270-290^{\circ}C$ are evenly and deeply distributed in the film surface layer. These results demonstrate that $270-290^{\circ}C$ is a proper temperature range to produce a layer of $MgZn_2$ intermetallic compound to act as a homogeneous passive layer.

• International Journal of Advanced Culture Technology
• /
• v.3 no.1
• /
• pp.153-160
• /
• 2015

This article is aimed to study the effects of resistance spot welding (RSW) on the lap joint properties between AA1100 aluminum alloy and SGACD zinc coated steel and its properties. The summarized experimental results are as follows. The summarized experimental results are as follows. The optimum welding parameters that produced maximum tensile shear strength of 2200 N was a welding current of 95 kA, a holding time of 10 cycles, and a welding pressure of 0.10 MPa. Increasing of welding current, increased the tensile shear strength of the joint and also increased the amount of aluminum dispersion at the joint interface. The lap joint of steel over the aluminum (Type I) showed the higher joint tensile shear strength than a lap joint of aluminum over the steel (Type II). The indentation depth and the ratio of the indentation depth to the plate thickness decreased when the welding current was increased in the type I lap joint and also decreased when the welding current was decreased in the type II lap joint. The interface structure showed the formation of the brittle $FeAl_3$ intermetallic compound that deteriorated the joint strength.