• 폴리머
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• 제30권3호
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• pp.271-278
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• 2006

어랙틱 폴리(비닐 알코올)(PVA) 수용액 시스템의 준희박농도에서의 고분자 사슬의 구조 및 거동을 살펴보기 위하여, 온도 $25^{\circ}C$에서 광산란 실험을 실시하였다. 산란 벡터 q에서 얻은 산란광의 세기 I(q)는 Onstein-Zernike 식으로 해석이 불가능하여 단순히 $I(q){\sim}q^{-m}$을 이용하여 fractal 차원 m을 얻었다. 그 결과 농도 3 wt% 이상에서는 $m=2.6{\pm}0.3$으로 일정하게 유지되었다. 동적 광산란으로 얻은 시간상관함수에는 항상 빠른 거동과 느린 거동의 두 종류가 공존하였으며, 빠른 거동의 협동확산계수는 reptation 이론의 농도의존지수 값(=3/4)과 달리 농도 의존성이 거의 나타나지 않았다. 또한 느린 거동은 거대한 크기의 불균일 영역대의 운동으로 해석되며, 이 거동의 농도지수는 -3.0으로써 매우 강한 농도 의존성을 보여 주었다. 이 불균일 영역대의 형성에는 어택틱 PVA의 -OH기 4개의 메소(meso)가 입체 규칙적으로 배향한 부분이 매우 중요한 역할을 하는 것으로 생각되어진다.

• 한국임상보건과학회지
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• 제3권2호
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• pp.372-377
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• 2015

Purpose: The aim of this study is to compare total high order aberrations between surgery which uses TransPRK and general laser assisted sub-epithelial keratomileusis. Methods: The patients who had general laser assisted sub-epithelial and TransPRK laser assisted sub-epithelial by visiting ophthalmic clinic in Ulsan from January 2014 to August 2014 was researched. Results: When comparing total high order aberrations before and after operation, it was found that total high order aberration in general laser assisted sub-epithelial group increased to $0.222{\pm}0.078{\mu}m$ from $0.074{\pm}0.019{\mu}m$ while that in TransPRK assisted sub-epithelial group increased to $0.179{\pm}0.045{\mu}m$ from $0.076{\pm}0.032{\mu}m$. When comparing the increment in total high order aberrations between two groups after surgery, it was found that the increments of TransPRK assisted sub-epithelial group were statistically smaller than that of general laser assisted sub-epithelial group (p<0.05). Conclusions: This study made a comparative analysis of total high order aberrations between general laser assisted sub-epithelial and TransPRK assisted sub-epithelial which was introduced recently and the result showed a significant difference. The findings of this study suggest that TransPRK assisted sub-epithelial can be used widely in simply improving eye sight and quality of vision by reducing an increase in high order aberration caused by orthokeratology surgery. It is expected that TransPRK assisted sub-epithelial will be helpful for improving the understanding quality of eye sight which occurs by several methods of vision correction surgery.