• Title/Summary/Keyword: Zeolite A

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Influence of Continious Application of Gypsum, Popped Rice Hull, and Zeolite on Soil Aggregation of Reclaimed Sandy Loam Soils (석고, 팽화왕겨 및 제오라이트 연속시용이 간척지 세사양토의 입단화에 미치는 영향)

  • Baek, Seung-Hwa;Kim, Jae-Young;Lee, Sang-Uk;Kim, Seong-Jo
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.5
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    • pp.764-769
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    • 2010
  • We investigated influence of continious application of gypsum (G: $CaSO_4{\cdot}2H_2O$), popped rice hulls (H) and zeolite (Z) on soil aggregation of reclaimed sandy loam soils. The application rates amended to fine sandy loam from reclaimed soils at Kyehwado were varied as follows:1550 (G1), 3100 (G2), 6200 (G3), 1000 (H1), 2000 (H2), 3000 (H3), and 200 (HZ1), 400 (HZ2) and 800 (HZ3) added to 1500(H) kg $10a^{-1}$, respectively. Soil aggregates were analyzed for 60, 90 and 120 days after treatments (DAT). At 60 DAT, The amount of aggregate from soil samples treated with gypsum was slightly increased with G1 while the aggregation was decreased by 4.66% for G3 for soil aggregates than thar of control. The treatments of H or HZ were effective in soil aggregation. The effect of treatment was in the order of H > HZ > G. At 90 DAT, increasing amount of gypsum attributed to decrease in soil aggregates. Therefore, we could conclude that suitable amounts of gypsum for soil aggregation in fine sandy loam might be 1550 kg $10a^{-1}$ or less. H1 increased aggregation by 7% for aggregate size between 1.0 and 2.0 mm. HZ1 was most effective in aggregation by 52.78% among the treatments while H2 and HZ3 51.50% and 48.51% at 120 DAT, respectively. As a result, we found that the effect of the treatment for soil amendments was in order of H > HZ > G.

Effects of Particle Size and Temperature on the Ammonium Ion Exchange by Natural Zeolite (천연제올라이트의 암모늄이온교환에 미치는 입자 크기 및 온도영향에 관한 연구)

  • Song, Chang Soo;Kim, Hee Jun;Chung, Tai Hak
    • Journal of Korean Society of Water and Wastewater
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    • v.12 no.3
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    • pp.75-80
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    • 1998
  • Ammonium ion is notorious for the adverse effects upon many of the important uses of water such as toxcity to fish, corrosion of metals and concrete, and concern over man's consumption. A clinoptilolite, which is a naturally occurring zeolite selective for ammonium ion exchange, has been used. Batch isotherm experiments were conducted for measuring ammonium ion exchange capacity. The ion exchange capacity was well described either by the Langmuir equation or by the Freundlich equation. As the particle size of the clinoptilolite decreased, exchange capacity was increased. The smaller particle size enhaced the exchange of ammonium ion due to the greater surface area and decreased diffusion to the exchange sites within the zeolite. Ammonium ion exchange capacity tended to decrease when the temperature increased from $20^{\circ}C$ to $35^{\circ}C$, and the temperature correction factor was found to be 0.98 in the Langmuir equation.

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Adsorptive Separation of Freon by Microwave Irradiation (마이크로파를 이용한 프레온의 흡착분리)

  • 김윤갑;소림오
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.2
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    • pp.133-142
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    • 1998
  • Gas adsorption on adsorbents depends on temperatures and pressures. When these parameters are fixed, the adsorption capability and selectivity can not be changed. If the gas adsorption is controlled by another factor like electromagnetic field, the adsorption and desorption can be managed by much intentional way. The microwave has characteristics to excite particular components such as water without destroying it. In this study, microwave was irradiated to the adsorbent of an NaY zeolite which is almost transparent to microwave. As vapor of 1, 1, 2- trichloro-1, 2, 2-trifluoroethane (CFC-113) and water flowed simultaneously on the zeolite packed in a column at room temperature, only water was adsorbed. The . adsorbed water was removed from the zeolite and then replaced by CFC-113, since the microwave was irradiated. Greater the power of microwave was, more CFC-113 was adsorbed. The water adsorption took place again after a latent period by stopping the microwave irradiation.

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A Study on the Properties and Fabrications of Eco-Ceramics Paint (친환경 무기질 도료의 제조 및 특성에 관한 연구)

  • Lee, Sang-Jin;Sung, Jin-Kyeong;Kim, Soon-Ho;Bae, Won-Tae
    • Journal of the Korean Ceramic Society
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    • v.42 no.10 s.281
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    • pp.678-684
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    • 2005
  • Sick house syndrome comes from VOCs that is harmful to health. To reduce VOCs, the cause of sick house syndrome, several materials have been developed and use. One of this materials, VOCs absorption paint was developed. VOCs absorption paint contains ceramic binder and zeolite powder. In the present study, eco-ceramics paint has been successfully fabricated by high-speed mixer using ceramic binder and filler powders. The eco-ceramics paint thus obtained have a deodorization rate with about 95.7$ \%$ and the bacteria decreasing rate is about 99.6$\%$. Moreover, the eco-ceramics paint showed excellent VOCs interception properties due to effect of ceramics layer and zeolite which exist in surface of paint.

Optimization of Ni2+ adsorption on 13X zeolite using box-behnken design

  • Jafari, Shoeib;Bandarchian, Farideh
    • Advances in environmental research
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    • v.6 no.3
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    • pp.217-227
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    • 2017
  • In this study, the elimination of $Ni^{2+}$ using 13X sorbent due to an electrostatic interaction was reported. The significant factors including pH, time and 13X sorbent amount were investigated using Box-Behnken design (BBD). In the optimum experimental conditions, the linear rang and limit of detection of the proposed method were 0.1-20 and $0.102mg\;L^{-1}$, respectively. The precision as RSD% was 1.3% for concentration of $2mg\;L^{-1}$. Concerning the excellent recoveries in a short time with highly efficient sample clean-up and removal, this method may be a very powerful and innovative future sample removal technique. To the best of our knowledge, this is the first report on using BBD for optimizing the parameters affected the removal of $Ni^{2+}$ by 13X zeolite sorbent.

The Effect of Additive Catalyst according to Thermal Aging of Vanadia SCR (Vanadia SCR의 열적 열화에 따른 조촉매의 영향)

  • Seo, Choong-Kil
    • Journal of Power System Engineering
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    • v.18 no.3
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    • pp.14-19
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    • 2014
  • The purpose of the study is to investigate the effect of additive catalyst according to the thermal aging of vanadia SCR catalysts. At a fresh condition, the $3V_2O_5-5WO_5-92TiO_2$ SCR showed the highest NOx conversion rate of about 30%, the performance of 5 kinds of SCR to which additive catalysts were added was not improved due to the insignificant effect of acid site control. For catalysts aged for 12h at $700^{\circ}C$, the SCR to which 3wt% Zeolite was added decreased in NOx conversion rate by 2.5% on average compared to the fresh SCR, it showed higher thermal durability than other additive catalyst. For 3Zeolite with high performance of NOx conversion rate during thermal aging, the Zeolite with stronger durability at a high temperature than other 5 kinds of SCR catalysts decreased the sintering of catalysts.

The Study on Inner Air Pollutants Absorptional Capability of Functional Mortar using Properties of Zeolite Powder (제올라이트계 분말을 이용한 기능성 모르터의 실내공기 오염물질 흡착 성능에 관한 연구)

  • Shin Yong-Jae;Heo Jae-Won;Kim Hyo-Youl;Lee Jong-Il;Lim Nam-Gi
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2006.05a
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    • pp.63-69
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    • 2006
  • In a traditional society, building materials were developed fulfilling the requirements of conveniences and functionalities such as safety, construction work, durability and economical efficiency. However, as the concern about environmental or users' health issues has been elevated recently, research and development about eco-friendly material are alto vigorously promoted further In addition, thanks to the steady growth of domestic industry, the amount of discharged industrial by-product is getting increasing. However, its recycling rate remain at low level as most industrial by-products are filled up in the land, which worsen the environmental pollution. Zeolite powder is cement admixture and is expected to have constraining effect of factors causing symptoms of inhabitants in a new house and alleviates the amount of discharged harmful elements emitted from hardened cement.

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An Efficient Method for N-Formylation of Amines Using Natural HEU Zeolite at Room Temperature Under Solvent-Free Conditions

  • Bahari, Siavash;Mohammadi-Aghdam, Babak;Mohammad Sajadi, S.;Zeidali, Fereshteh
    • Bulletin of the Korean Chemical Society
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    • v.33 no.7
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    • pp.2251-2254
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    • 2012
  • A rapid and practical green route for N-formylation of primary and secondary amines with formic acid at room temperature under the solvent-free conditions using HEU zeolite as a heterogeneous, reusable and highly efficient catalyst is described. The process is remarkably simple and environmentally benign. Excellent chemoselectivity was observed for the conversion of primary amines in the presence of secondary amines.

Reduction of cement consumption by producing smart green concretes with natural zeolites

  • Trung, Nguyen Thoi;Alemi, Nima;Haido, James H.;Shariati, Mahdi;Baradaran, Seyedata;Yousif, Salim T.
    • Smart Structures and Systems
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    • v.24 no.3
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    • pp.415-425
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    • 2019
  • This study was carried out to evaluate the natural zeolite in producing green concrete as an effort to prevent global warming and environmental impact problems of cement industries. To achieve this target, two types of natural zeolites applied to study physical, chemical and compressive strength of concrete containing different percentages of zeolites. The results in comparison with control samples indicate that compressive strength of zeolites mixes increases with the 15% replacement of zeolite instead of cement in all types of samples. In the water-cement ratio of 0.6, results showed an increase in the compressive strength of all percentages of replacement. This results indicate that using natural zeolites could be produced a green concrete by a huge reduction and saving in the consumption of cement.

Development of a Microbe-Zeolite Carrier for the Effective Elimination of Heavy Metals from Seawater

  • Kim, In Hwa;Choi, Jin-Ha;Joo, Jeong Ock;Kim, Young-Kee;Choi, Jeong-Woo;Oh, Byung-Keun
    • Journal of Microbiology and Biotechnology
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    • v.25 no.9
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    • pp.1542-1546
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    • 2015
  • The purpose of this study was to investigate the potential of zeolite-supported sulfatereducing bacteria (SRB) in enhancing the removal of Cu2+, Ni2+, and Cr6+ in contaminated seawater. Our results show that SRB-immobilized zeolite carriers can enhance the removal of heavy metals. In addition, heavy metals were generally better removed at conditions of 37°C. Cu2+, Ni2+, and Cr6+ were effectively removed by 98.2%, 90.1%, and 99.8% at 100 parts per million concentration of the heavy metals, respectively. These results indicate that SRB-zeolite carriers hold great potential for use in the removal of cationic heavy metal species from marine environment.