• Title/Summary/Keyword: Yttrium

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Application of Response Surface Method for Modeling of Room Temperature Resistivity of $(Ba_{0.8-x}Sr_{0.2})Y_xTiO_3$ ($(Ba_{0.8-x}Sr_{0.2})Y_xTiO_3$의 상온비저항을 모델링하기 위한 반응표면분석법의 적용)

  • Moon, Hyung Chul;Noh, Tae Yong;Kim, Seung Won;Lee, Chul
    • Journal of the Korean Chemical Society
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    • v.42 no.6
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    • pp.652-656
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    • 1998
  • $(Ba_{0.8-x}Sr_{0.2})Y_xTiO_3\;(BSYT)$ powders were prepared by the calcination of metal-oxalate precipitates, which were obtained by wet chemical method using Ba, Sr, Y and Ti-nitrates and oxalic acid. Yttrium content, sintering temperature and cooling rate were taken as experimental factors. Response surface method was applied to modelling of the room temperature resistivity of BSYT. The results indicated that the Yttrium content had larger effect on the room temperature resistivity and minimum room temperature resistivity was at Yttrium content of 0.24 mol%. The validity of a modelling equation was confirmed by comparing the measured room temperature resistivity with the calculated one.

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Electrical Properties of $(Ba,Sr)_{1-x}Y_xTiO_3$ with Variation of Yttrium Content (이트륨 혼입량 변화에 따른 $(Ba,Sr)_{1-x}Y_xTiO_3$의 전기적 특성)

  • Noh, Taeyong;Sung, Hyun Je;Kim, Seungwon;Lee, Chul
    • Journal of the Korean Chemical Society
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    • v.39 no.10
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    • pp.806-811
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    • 1995
  • The electrical properties for $(Ba,Sr)_{1-x}Y_xTiO_3$(x=0.001∼0.009, BSYT) with a positive temperature coefficient of resistivity(PTCR) effect were investigated. The BSYT powder was prepared by oxalate coprecipitation method. It was found that the large PTCR effect was appeared up to 0.3 mol% and decreased above 0.5 mol% of the yttrium concentration. The plot of temperature vs. $1{\varepsilon}$m(T) above Curie temperature($T_c$) was agreed with Curie-Weiss law. The potential barrier calculated from measured resistivity and dielectric constant of specimens was high up to 0.3 mol% and reduced above 0.5 mol% of yttrium concentration as the curve of PTCR effect.

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Comparison of the marginal fit of milled yttrium stabilized zirconium dioxide crowns obtained by scanning silicone impressions and by scanning stone replicas

  • Yus, Estefania Aranda;Cantarell, Josep Maria Anglada;Alonso, Antonio Minarro
    • The Journal of Advanced Prosthodontics
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    • v.10 no.3
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    • pp.236-244
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    • 2018
  • PURPOSE. To determine the discrepancy in monolithic zirconium dioxide crowns made with computer-aided design and computer-aided manufacturing (CAD/CAM) systems by comparing scans of silicone impressions and of master casts. MATERIALS AND METHODS. From a Cr-Co master die of a first upper left molar, 30 silicone impressions were taken. The 30 silicone impressions were scanned with the laboratory scanner, thus obtaining 30 milled monolithic yttrium stabilized zirconium dioxide (YSZD) crowns (the silicone group). They were poured and the working models were scanned, obtaining 30 milled monolithic yttrium stabilized zirconium dioxide (YSZD) crowns (the plaster group). Three predetermined points were analyzed in each side of the crown (Mesial, Distal, Vestibular and Palatal), and the marginal fit was evaluated with SEM (${\times}600$). The response variable is the discrepancy from the master model. A repeated measures ANOVA with two within subject factors was performed to study significance of main factors and interaction. RESULTS. Mean marginal discrepancy was $22.42{\pm}35.65{\mu}m$ in the silicone group and $8.94{\pm}14.69{\mu}m$ in the plaster group. The statistical analysis showed significant differences between the two groups and also among the four aspects. Interaction was also significant (P=.02). CONCLUSION. The mean marginal fit values of the two groups were within the clinically acceptable values. Significant differences were found between the groups according to the aspects studied. Various factors influenced the accuracy of digitizing, such as the design, the geometry, and the preparation guidance, as well as the texture, roughness and the color of the scanned material.

Fabrication and characteristics of suspension-plasma-sprayed yttrium oxide coatings (서스펜션 플라즈마 스프레이 코팅법을 이용한 이트리아 코팅막 제조와 특성)

  • Kim, Min Suk;So, Sung Min;Kim, Hyung Soon;Park, Seong Hwan;Ham, Young Jae;Jeon, Min Seok;Kim, Kyoung Hun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.6
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    • pp.359-364
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    • 2019
  • The suspension plasma spraying is a modification of conventional plasma spray techniques that has been developed to overcome the challenge of using fine particles in plasma spray processes. In this study, microstructure developments and mechanical property of yttrium oxide (Y2O3) coatings prepared by the suspension plasma spray coating technique have been investigated to determine the effect of processing parameters including plasma gun current and total gas flow. The results showed that a highly dense Y2O3 coating having low porosity of 0.2 vol% without any lamellar structures can be achieved at the optimum condition of gun current 200 A and total gas flow 220 L/min.

Rare earths from secondary sources: profitability study

  • Innocenzi, Valentina;De Michelis, Ida;Ferella, Francesco;Veglio, Francesco
    • Advances in environmental research
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    • v.5 no.2
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    • pp.125-140
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    • 2016
  • The paper is focused on the economic analysis of two hydrometallurgical processes for recovery of yttrium and other rare earth elements (REEs) from fluorescent phosphors of spent lamps. The first process includes leaching with sulphuric acid and precipitation of a mixture of oxalates by oxalic acid, the second one includes leaching with sulphuric acid, solvent extraction with D2EHPA, stripping by acid and recovery of yttrium and traces of other rare earths (REs) by precipitation with oxalic acid. In both cases the REEs were recovered as oxides by calcination of the oxalate salts. The economic analysis was estimated considering the real capacity of the HydroWEEE mobile's plant ($420kg\;batch^{-1}$). For the first flow-sheet the cost of recycling comes to $4.0{\euro}kg^{-1}$, while the revenue from the end-product is around $5.40{\euro}kg^{-1}$. The second process is not profitable, as well as the first one, taking into account the composition of the final oxides: the cost of recycling comes to $5.2{\euro}kg^{-1}$, while the revenue from the end-product is around $3.56{\euro}kg^{-1}$. The process becomes profitable if the final RE oxide mixture is sold for nearly $50{\euro}kg^{-1}$, a value rather far from the current market prices but not so unlikely since could be achieved in the incoming years, considering the significant fluctuations of the Res' market.

The Magnetic Properties of Polycrystalline Yttrium Iron Garnet by Ferromagnetic Resonance (강자성공명 현상을 이용한 YIG의 자기적 특성 연구)

  • 김기현;이대하;김영호
    • Journal of the Korean Magnetics Society
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    • v.9 no.1
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    • pp.7-16
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    • 1999
  • Stoichiometric and nonstoichiometric $Y_{3-x}Fe_{5+x}O_{12})$ polycrystalline samples (x=0.00, 0.05, 0.10, 0.30, -0.05, -0.10, -0.30) were prepared by solid state reaction method. The magnetic properties of the sample were investigated by FMR (ferromagnetic resonance) technique at microwave frequency 5.11 GHz (G-band) and 23.39 GHz (K-band) respectively. The spectroscopic splitting factor g were estimated to be 2.04~2.35 from the derivative absorption lines. As the samples became yttrium $(Y^{3+})$ excess and iron $(Fe^{3+})$ excess, Magnetizations were decreased. But resonance linewidth were increased. To investigate the anisotropy, the angular dependence of resonance magnetic fields were measured. Angular dependence of effective magnetizations were measured by FMR from 77 K to 300 K at K-band microwave frequency (23.39 GHz) and the saturation magnetizations were measured by VSM. The Bloch coefficients B and C were determined by fitting. $M_{eff}(0)$ was obtained by the extrapolation from 80 K. From this result, the spin wave stiffness constant D $(about\; 162~206 \;eV{\AA}^2)$and average square range of exchange interaction $$$(about \;5.84~12.13\;{\AA}^2)$ were determined.

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