• 한국재료학회지
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• 제11권4호
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• pp.283-289
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• 2001

50/50 vol% LSM-YSZ (La$_{1-x}$Sr$_{x}$MnO$_3$-yttria stabilized zirconia)의 복합공기극이 콜로이드 증착법에 의해 연마된 YSZ 전해질상에 증착되었다. 그 전극 특성은 주사전자현미경, X선회절과 임피던스 분석기에 의해 연구되어졌다. 90$0^{\circ}C$에서 공기/LSM -YSZ/YSZ/Pt/공기 셀에 대해 측정된 전형적인 임피던스 스펙트럼들은 2개의 불완전한 호(depressed arc)로 구성되었다. LSM 전극에 대한 YSZ의 첨가는 전극내의 삼상계(TPB) 영역을 증가시켰으며, 이것이 LSM-YSZ 복합공기극의 비저항을 감소시켰다. 또한 전해질 표면의 불순물 제거와 TPB 길이의 증가를 위한 전해질 표면연마는 공기극의 비저항을 훨씬 더 감소시켰다. LSM-YSZ 공기극의 비저항은 작동온도, 공기극의 조성과 입자크기, 인가전류 및 전해질의 표면거칠기에 의해 큰 영향을 받았다.

• 한국세라믹학회지
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• 제31권5호
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• pp.477-484
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• 1994

The yttria stabilized zirconia(YSZ) thin films for solid oxide fuel cell (SOFC) were fabricated by an electrochemical vapor deposition(EVD) technique using YCl3+ZrCl4+H2O gas system. The YSZ films were deposited under reduced pressure at the temperature of 1000~120$0^{\circ}C$ on the porous alumina substrates. The deposition rate, chemical composition and growth morphology were investigated by SEM, XRD, EDS. The growth rates of the films obeyed a parabolic rate law, representing that the growing process is controlled by an electrochemical transport through the YSZ film. The Y2O3 content of the films was about 10 mol%, equal to the composition of metal chloride reactant gases, approximately. The YSZ films were highly dense, the growing features showed columnar structure and surface morphologies were changed with the EVD conditions.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.924-925
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• 2006

In this study, hydroxyapatite (HAp) and hydroxyapatite-yttria stabilized zirconia (HAp-3YSZ) with 20 vol.%-($ZrO_2+3%mol\;Y_2O_3$) nanopowders were consolidated very rapidly to full density by High-frequency induction heat sintering (HFIHS). Effects of temperature and the addition of 3YSZ on the toughness, hardness and microstructure properties have been studied. 3YSZ second phase toughening HAp composites with higher toughness were successfully developed at relatively low temperatures through this technique. Compared with hardness and toughness obtained for pure HAp, the hardness and toughness for HAp-20vol. % 3YSZ were much higher.

• 한국재료학회지
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• 제4권7호
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• pp.741-749
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• 1994

The planar solid oxide fuel cell(SOFC) contains several ceramic materials depending on its structure and has rdfractory metal parts for manifolds, shrouds and current leads. Among ceramic materials for planar SOFC, joining of lanthanum chromite separator and yttria stabilized zirconia(YSZ) electoyte in planar SOFC stack to give strong gas tight seals is necessary for satisfactory operation and high performance. Nevertheless, for planar SOFC/sub s/, how to seal the cell stack and gas manifold remains as one of the unsolved problems. Therefore, in this study. we investigated the joining of sintered lanthanum chromite and YSZ pellets using unsintered lanthanum chromite green films as sealent. Scanning electron microscopy(SEM) and energy dispersive X-ray analysis(EDX) revealed that Ca in the sealing material diffused and dissolved into YSZ and sintered lanthanum chromite, and unsintered lanthanum chromite green films reacted with YSZ to from a new phase at the interface. Also, the densification of unsintered lanthanum chromite green films was inpeded by the Ca migration.

• 한국세라믹학회지
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• 제34권11호
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• pp.1113-1120
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• 1997

The 2, 4, 6 and 8mol% Y2O3 doped-ZrO2 powders (20 kinds) with the addedtion of Al2O3 upto 8wt% were prepared by coprecipitation method using the zirconium oxyacetate, yttrium chloride and aluminum nitrate as starting materials. The coprecipitated powders were characterized by XRD, TG-DTA, FT-IR and SEM. The sintering properties of zirconia-alumina composites prepared by 2YSZ and 8YSZ powders containing various Al2O3 contents were also investigated. With increasing the yttria stabilizer contents, the amount of exothermic heat for zirconia crystallization decreased. And it was confirmed that the crystallizing temperature of coprecipitated zirconia powders increased and the crystallization process occurred in a wide temperature range, as Al2O3 content increased in 8YSZ.

• 한국막학회:학술대회논문집
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• 한국막학회 2002년도 춘계 총회 및 학술발표회
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• pp.35-41
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• 2002

Dense oxygen ionic conducting materials can be used for oxygen separation membranes at high temperatures. However, they show relatively low permeation flux because of their large resistances. To reduce resistances and improve the oxygen permeation flux, thin dense yttria-stabilized-zirconia (YSZ)/Pd composite dual-phase membranes were fabricated by a new approach that combines the reservoir method and chemical vapor deposition (CVD). A thin porous YSZ layer was coated on a porous alumina support by dip-coating the YSZ suspension. A continuous Pd phase was formed inside pores of the YSZ layer by the reservoir method. The residual pores of the YSZ/Pd layer were plugged with yttria/zirconia by CVD to ensure the gas tightness of the membranes. The oxygen permeation fluxes through these composite membrane were 2.0$\times$10$^{-8}$ mol/cm$^2$.s and 4.8$\times$10$^{-8}$ mol/cm$^2$.s at 105$0^{\circ}C$ when air and oxygen were used as the permeate gases, respectively. These oxygen permeation values are about 1 order of magnitude higher than those of pure YSZ membranes prepared under similar conditions.

• 한국분말재료학회지
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• 제20권6호
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• pp.445-452
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• 2013

Yttria-stabilized zirconia (YSZ) coatings are fabricated via suspension plasma spray (SPS) for thermal barrier applications. Three different suspension sets are prepared by using a planetary mill as well as ball mill in order to examine the effect of starting suspension on the phase evolution and the microstructure of SPS prepared coatings. In the case of planetary-milled commercial YSZ powder, a deposited thick coating turns out to have a dense, vertically-cracked microstructure. In addition, a dense YSZ coating with fully developed phase can be obtained via suspension plasma spray with suspension from planetary-milled mixture of $Y_2O_3$ and $ZrO_2$.

• The Korean Journal of Ceramics
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• 제4권2호
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• pp.114-121
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• 1998

Using Hebb-Wagner's asymmetric cell, partial conductivities of holes and electrons in yttria stabilized zirconia doped with 10 mol% TiO2 have been estimated by a dc polarization measurement. The current interrruption method and ac impedance measurements have been also made to evaluate the ionic conductivity and to examine the consistency of the partial conductivities. Partial conductivities of electrons(σn) and holes (σp) were found to be pro-peortional to -1/4 and 1/4 power of partial pressure of oxygen gas, respectively, except for σn at reducing conditions. In comparison with 5 mol% doped YSZ, σn was found to increase with the increase of TiO2 concentration, but σp stayed at almost a constant value.

• 한국진공학회:학술대회논문집
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• 한국진공학회 1999년도 제16회 학술발표회 논문개요집
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• pp.73-73
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• 1999

• 한국세라믹학회지
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• 제53권6호
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• pp.628-634
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• 2016

The 8 wt% yttria($Y_2O_3$) stabilized zirconia ($ZrO_2$), 8YSZ, a typical thermal barrier coating (TBC) for turbine systems, was fabricated under different starting powder conditions and coating parameters by atmospheric plasma spray (APS) coating process. Four different starting powders were prepared by conventional spray dry method with different additive and process parameter conditions. As a result, large- and small-size spherical-type particles and Donut-type particles were obtained. Dense structure of 8YSZ coating was produced when small size spherical-type or Donut-type particles were used. On the other hand, 8YSZ coating with a porous structure was formed from large-size spherical-type particles. Furthermore, a segmented coating structure with vertical cracks was observed after post heat treatment on the surface of dense structured coating by argon plasma flame at an appropriate gun distance and power condition.