• Title/Summary/Keyword: Yield curve

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Synthesis of Electrode Catalyst for Polymer Electrolyte Membrane Fuel Cells Using Colloidal Method (콜로이드법을 이용한 고분자전해질 연료전지용 백금전극 촉매의 제조)

  • Park, Jin-Nam
    • Clean Technology
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    • v.19 no.1
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    • pp.59-64
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    • 2013
  • Pt/carbon Electrode catalysts for PEMFC were synthesized using colloidal method. PSA (platinum sulfite acid) was used as a Pt precursor and CPA (chloroplatinic acid) was also used to replace relatively expensive PSA. Electrode catalysts prepared using PSA showed Pt particle size less than 3.5 nm and Pt yield higher than 90% in 10~40 wt% Pt loading. Electrode catalysts prepared using CPA also showed Pt particle size less than 4.4 nm and Pt yield higher than 80% in 10~40 wt% Pt loading. The MEA (membrane electrode assembly) using 20 wt% Pt/VXC72 showed equivalent I-V curve comparing with commercial electrode catalyst in single cell test.

Preliminary Study on the Toxicity and Transfer of Heavy Metals and Tributyltin to Seagrass Zostera marina (잘피의 광합성에 대한 중금속 및 TBT의 독성 영향과 중금속 흡수에 대한 연구)

  • Choi, Tae-Seob;Kim, Kwang-Young;Lee, Byeong-Gweon;Lee, Jung-Suk
    • ALGAE
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    • v.20 no.2
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    • pp.157-166
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    • 2005
  • Uptake kinetics of Cd and Zn by leaves and rhizome of the seagrass Zostera marina were examined in controlled laboratory radiotracer experiments. Subsequently, acute toxicity of Cd, Cu and TBT on photosynthetic quantum yield (ΔF/Fm’ of Z. marina were determined, and the differential sensitivities of rapid light curve (RLC) to those harmful substances were also compared. All measurements on photosynthetic activity were determined by chlorophyll a fluorescence method using pulse amplitude modulation (PAM). Metal uptake by Z. marina was saturated with increasing exposure time in leaves and rhizomes. Uptake of Zn by Z. marina was faster than that of Cd. Metal uptake rates in Z. marina decreased with the increase of dissolved metal concentrations and also with the increase of biomass. The adverse effect of TBT on effective quantum yield was stronger than other pollutants. Average acute toxicity on the RLC of the seagrass exposed to TBT and two heavy metals (Cd and Cu) was going to decrease as follows: TBT > Cd > Cu. Our preliminary results in this study suggested that Z. marina potentially can be used as a biomonitor of harmful substances contamination in coastal waters.

A Comparative Study on Field Tests for Driven Pile in Static Load Tests (말뚝의 정재하시험을 통한 현장시험 결과 분석)

  • Chun, Byung-Sik;Youn, Hwan-Ho;Youn, Byung-Tae;Kim, Young-Hun
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.03a
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    • pp.1117-1124
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    • 2008
  • In This paper, load-settlement curves that obtained from 11 sites were analyzed. At all tests, the load is applied until apparent failure is observed. The validity of the ultimate and yield load estimation method and load calculated from the settlement criterion was investigated through comparison with the measured data. The result indicated that B. Hansen 80% criterion and Stability Plot in ultimate loading decision law almost have been regared as same by comparing measured date and ultimate bearing capacity decided in depending yield loading decision law from 13% to 46% difference have taeyaeen came out when measured data and Davisson was compared, and S-log t from 5% to 41% log P-log S from 14% to 50% difference have been came out. When Settlement standard and measured data was compared difference had been came out about 3% in total settlement 0.1D criterion and from 12% to 35% difference had been came out in net settlement.

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A Comparative Study on the Evaluation of Bearing Capacity for Driven Pile in Static Load Test (현장정재하시험 결과를 통한 타입말뚝 지지력 판정법 비교 연구)

  • Chun, Byung-Sik;Seo, Deok-Dong;Choi, Heon-Kil;Yoon, Hwan-Ho
    • Proceedings of the Korean Geotechical Society Conference
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    • 2005.03a
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    • pp.677-686
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    • 2005
  • The allowable bearing capacity of a pile, the most important factor in stability estimation, is determined by applying safety factor to the ultimate load or yield load. There are several but contradictory methods available in current design codes to estimate the allowable bearing capacity and the safety factor. This paper analyzes load-settlement curves obtained from 19 static load tests measured from 11 sites. At all tests, the load is applied until apparent failure is observed. The validity of the ultimate and yield load estimation method and load caculated from the settlement criterion is investigated through comparison with the measured data. In addition, a new procedure to estimate allowable load and safety factor is proposed. Additional data from field static load tests, such as those incorporated in this study, are needed to more reliably apply the proposed method in design practice.

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Evaluation of fatigue poperties of base and weld metal for API 5L X65 pipeline (API 5L X65 배관 모재 및 용접부 피로특성 평가)

  • Kim, Cheol-Man;Baek, Jong-Hyun;Kim, Woo-Sik
    • Proceedings of the KSME Conference
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    • 2001.11a
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    • pp.44-48
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    • 2001
  • The pipelines for natural gas transmission were buried in the ground of 1.5m depth. The pipelines were continuously subjected to vehicle load and internal pressure change by the quantity consumed of natural gas. In this paper, high cycle fatigue properties of natural gas transmission pipelines were studied. Fatigue specimens were obtained from the base and weld metal of circular pipe. Fatigue strength increased with increasing yield strength. Especially, the fatigue strength of base metal was higher than the yield strength of base metal and the fatigue strength of weld metal by manufactured process of TMCP.

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Spherical Indentation Testing to Evaluate Mechanical Properties In 1Cr-1Mo-0.25V Steel (Spherical Indentation Testing에 의한 1Cr-1Mo-0.25V 강의 기계적 물성 평가)

  • Lee, J.M.;Nam, Y.H.;Nham, S.H.;Lee, S.S.;Lee, O.S.
    • Proceedings of the KSME Conference
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    • 2001.11a
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    • pp.266-271
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    • 2001
  • Spherical indentation technique was developed to evaluate the flow properties of metallic materials in carbon steel, stainless steel and alloys, etc. Through the spherical indentation test, differently degraded 1Cr-1Mo-0.25V steel's mechanical properties were observed and compared with conventional standard test data. The flow properties of 1Cr-1Mo-0.25V steels were estimated by analyzing the indentation load-depth curve. To characterize the flow property, we used material yield slope and constraint factor index rather than strain-hardening exponent because the variation of strain-hardening exponent was very little and the data showed irregularly. And the constraint factor's effect was small when the material yield slope was taken into account.

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Effects of Inclusions on Fracture Toughness for 1%CrMoV Rotor Steel (1%CrMoV 로터강의 파괴인성에 미치는 개제물의 영향)

  • Jeong, Sun-Eok
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.9 s.180
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    • pp.2319-2325
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    • 2000
  • This thesis studied that seven kinds of residual elements(inclusions) had influenced on fracture toughness($K_{IC}$) obtained by Begley-Logsdon and Rolfe-Novak model equation using tensile an d impact test data of I%CrMoV HP(high pressure) rotor steel. $K_{IC}$ design curve of ASME and fracture surface by SEM were also considered, obtained results are summarized as follows $K_{IC}$ was linearly increased with increase of temperature, effect of the inclusions was significantly over FATT. $K_{IC}$ at lower shelf temperature was quantitatively related to yield strength and was agreed well with Begley's equation. It was difficult to determine $K_{IC}$ because of specimen size and tester capacity at upper shelf temperature, but for this view point Rolfe-Novak's equation was useful. The degree of brittle fracture was dependent on FATT fundamentally, adding S, Sb to matrix decreased impact energy and adding Cu, As increased yield(tensile) strength, and the influence of the others minority inclusion was comparatively insignificant.

The Changes of Microstructure, Morphology, and Mechanical Properties of Solvent Treated PET POY (Partially Oriented Yarn) (폴리에스테르 부분배향사의 용매처리에 따른 내부구조 및 인장성질의 변화)

  • Shin, Hae Won;Ryu, Hyo Seon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.17 no.1
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    • pp.63-75
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    • 1993
  • Partially oriented polyester yarn (PET POY) was treated in the unrestrained state using various solvents at different temperatures. Interactions between PET POY & solvents were estimated by the changes of microstructure, morphology and mechanical properties. The correlation between the changes of microstructure & morphology and the changes of mechanical properties was also studied. TCE, Dioxane, O-DCB, DMF, and BA were found to be active solvents, while Iso-AA and water were found to be weak solvents. PET POY was affected mainly by the solvents when treated with active solvents and affected mainly by heat when treated with weak solvents. Changes by the solvent treatment in microstructure and morphology were : an increase in crystallinity, a change in birefringence, a shrinkage in length, and a change in DSC curve. As for the changes in mechanical properties, findings in the PET POY when treated with solvents were : a decrease in stress-at-break, a change in yield stress, an increase in strain-at-break & yield strain, and a decrease in initial modulus. Changes in microstructure and morphology directly affected the mechanical properties.

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Effect of $Al_2O_3/Fe$ Ratio on Characteristics of Carbon Nanotubes Prepared by Catalytic Chemical Vapor Deposition

  • Jung, Sung-Sil;Lee, Dae-Yeol;Chung, Won-Sub;Park, Ik-Min
    • Carbon letters
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    • v.5 no.2
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    • pp.81-87
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    • 2004
  • The effect of compositions of $Al_2O_3$ in the mixed $Fe/Al_2O_3$ catalysts on the synthetic behaviors of carbon nanotubes (CNTs) by catalytic chemical vapor deposition (CCVD) process was investigated in wide range of the mixture ratios of support materials. CNTs were synthesized with $Fe/Al_2O_3$ catalysis under the condition of 40 min in synthetic time, and 923 K of synthetic temperature using $C_2H_4$ and $H_2$ as synthetic and carrier gas, respectively. The carbon yield with the content of $Al_2O_3$ showed in a parabolic curve and the maximum carbon yield was 40 wt.% of $Al_2O_3$. As the mixture ratio of $Al_2O_3$ increased, decreasing tendency was observed in the diameter of CNTs. Specific surface areas of CNTs were increased with the increase of the mixture ratio of $Al_2O_3$.

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Study on Mechanical Behavior of a Pre-Heat Treated Steel of ESW95 (선조질강 ESW95의 기계적 성질에 관한 연구)

  • Park, J.T.;Eom, J.G.;Kim, J.H.;Youn, D.J.;Joun, M.S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.05a
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    • pp.439-443
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    • 2008
  • We investigate the mechanical behavior of a pre-heat treated steel of ESW95, which is being used for automotive parts including tie-rods to save manufacturing cost and enhance product quality. SCM435 is also investigated to reveal the characteristics of the pre-heat treated steel tested. AFDEX/MAT is used to extract the true stress-strain curve over the large strain with higher accuracy. It has been found that ESW95 has very week strain-hardening behavior which can be negligible compared with SCM435 and that the initial yield strength is quite high and the toughness of ESW95 reaches nearly 75% of SCM435. ESW95 is characterized by the weak strain-hardening behavior and high yield strength that can be lead to minimization of post-processing including heat treatment and straightening. ESW95 and SCM435 are also compared by applying them to ball-stud forging by computer simulation. It is expected that a great deal of change may take place in production as well as in service if the pre-heated steels are adopted.

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