• Bulletin of the Korean Chemical Society
• /
• 제34권7호
• /
• pp.2125-2130
• /
• 2013

A new nickel(II) complex $[NiL^1]^{2+}$ ($L^1$ = 1-(2-aminoethyl)-3-(N-{2-aminoethyl}aminomethyl-1,3-diazacyclohexane) containing one 1,3-diazacyclohexane ring has been prepared selectively by the metal-template condensation of formaldehyde with N-(2-aminoethyl)-1,3-propanediamine and ethylenediamine at room temperature. The complex reacts with nitroethane and formaldehyde to yield the pentaaza macrocyclic complex $[NiL^2]^{2+}$ ($L^2$ = 8-methyl-8-nitro-1,3,6,10,13-pentaazabicyclo[13.3.1]heptadecane) bearing one C-$NO_2$ pendant arm. The reduction of $[NiL^2]^{2+}$ by using Zn/HCl produces $[NiL^3(H_2O)]^{2+}$ ($L^3$ = 8-amino-8-methyl-1,3,6,10,13-pentaazabicyclo[13.3.1]heptadecane) bearing one coordinated C-$NH_2$ pendant arm that is readily protonated in acid solutions. The hexaaza macrocyclic complex $[NiL^4]^{2+}$ ($L^4$ = 8-phenylmethyl-8-nitro-1,3,6,8,10,13-hexaazabicyclo[13.3.1]heptadecane) bearing one N-$CH_2C_6H_5$ pendant arm has also been prepared by the reaction of $[NiL^1]^{2+}$ with benzylamine and formaldehyde. The nickel(II) complexes of $L^1$, $L^2$, and $L^4$ have square-planar coordination geometry in the solid states and in nitromethane. However, they exist as equilibrium mixtures of the square-planar $[NiL]^{2+}$ (L = $L^1$, $L^2$, or $L^4$) and octahedral $[NiL(S)_2]^{2+}$ species in various coordinating solvents (S); the proportion of the octahedral species $[NiL(S)_2]^{2+}$ is strongly influenced by the ligand structure and the nature of the solvent. Synthesis, spectra, and chemical properties of the nickel(II) complexes of $L^1-L^4$ are described.

• 설비공학논문집
• /
• 제3권2호
• /
• pp.123-130
• /
• 1991

The mixed convection heat transfer from vertical inline plates has been studied numerically by the finite difference method and experimentally with Mach-Zehnder interferometer. The dimensionless spacing, $s/L_1$, the relative length, $L_2/L_1$ and the dimensionless temperature ratio, ${\Phi}_2/{\Phi}_1$ are varied parametically. The lower plate mean Nusselt numbers show same values as $s/L_1$, ${\Phi}_2/{\Phi}_1$ and $L_2/L_1$ increase. The upper plate mean Nusselt numbers increase as $s/L_1$ and ${\Phi}_2/{\Phi}_1$ increase, but $L_2/L_1$ decreases. The upper plate mean Nusselt number is higher than the lower plate mean Nusselt for $s/L_1$ 1.8 at Re=100, $Gr=10^4$, Pr=0.71, $L_2/L_1=0.5$ and ${\Phi}_2/{\Phi}_1=1.0$. A comparison between the experimental and numerical results show good agreement.

• 영어어문교육
• /
• 제11권3호
• /
• pp.39-56
• /
• 2005

This study is a small-scale replication study of Kubota (1998). Kubota discovered that L1 rhetoric was not the main cause of L2 writing problems. The conclusion of Kubota's study was in contrast to that of contrastive rhetoric research that claimed that the use of L1 rhetorical styles in L2 writing negatively affects the quality of L2 writing, in particular, at the organizational level. According to Kubota(1998), the use of Japanese rhetorical styles did not deteriorate the quality of English writing. By investigating Korean ESL learners, this replication study examined whether L1 and L2 writings have the same rhetorical styles and how L1 rhetorical styles affect the L2 writing quality. The study analyzed Korean and English persuasive writings written by 12 Korean ESL learners in terms of organization. The results show that Korean learners of English used different rhetorical styles in their L1 Korean writing and L2 English writing. However, there was a positive relationship between L1 Korean and L2 English organization scores.

• Nuclear Engineering and Technology
• /
• 제14권1호
• /
• pp.22-40
• /
• 1982

조화 단진동자 파동함수를 써서 원자핵의 LS에너지 행열요소를 계산하였다. 범위는 1$_1$= $l_{s}$ , $l_2$=lp, $l_3$=ld, 2s, $l_4$=1f, 2p, $l_{5}$ =1g, 2d, 3s라 ( $l_{i}$ $l_{i+1}$｜ $l_{i}$ $l_{i+1}$)의 배치에 대한 것이었다. 계산결과는 Talmi적분 $I_1$과 Slater 적분 $F^{k}$ 를 써서 표시하였다. 또 여러가지 합법칙을 유도하고 이를 써서 계산의 결과를 검산하였다.하였다.

• KSII Transactions on Internet and Information Systems (TIIS)
• /
• 제12권7호
• /
• pp.3194-3216
• /
• 2018

Slow Feature Discriminant Analysis (SFDA) is a supervised feature extraction method inspired by biological mechanism. In this paper, a novel method called Two Dimensional Slow Feature Discriminant Analysis via $L_{2,1}$ norm minimization ($2DSFDA-L_{2,1}$) is proposed. $2DSFDA-L_{2,1}$ integrates $L_{2,1}$ norm regularization and 2D statically uncorrelated constraint to extract discriminant feature. First, $L_{2,1}$ norm regularization can promote the projection matrix row-sparsity, which makes the feature selection and subspace learning simultaneously. Second, uncorrelated features of minimum redundancy are effective for classification. We define 2D statistically uncorrelated model that each row (or column) are independent. Third, we provide a feasible solution by transforming the proposed $L_{2,1}$ nonlinear model into a linear regression type. Additionally, $2DSFDA-L_{2,1}$ is extended to a bilateral projection version called $BSFDA-L_{2,1}$. The advantage of $BSFDA-L_{2,1}$ is that an image can be represented with much less coefficients. Experimental results on three face databases demonstrate that the proposed $2DSFDA-L_{2,1}/BSFDA-L_{2,1}$ can obtain competitive performance.

• 열처리공학회지
• /
• 제21권1호
• /
• pp.20-25
• /
• 2008

Structural studies have been performed on precipitation hardening and microstructural variations found in Ti-Al-Cr ternary $L1_0$- and $L1_2$-phase alloys using transmission electron microscopy. Both the $L1_0$ and $L1_2$ phase alloys harden by aging at 973 K after solution annealing at higher temperatures. The amount of age hardening of the $L1_2$ phase alloy is larger than that of the $L1_0$ phase alloy. The phase separation between $L1_0$ and $L1_2$ phase have not been observed by aging at 973 K. But $Al_2Ti$ was formed in each matrix alloy during aging. The crystal structure of the $Al_2Ti$ phase is a $Ga_2Zr$ type in the $L1_0$ and a $Ga_2Hf$ type in the $L1_2$ phase, respectively. At the beginning of aging the fine coherent cuboidal $Al_2Ti$-phase are formed in the $L1_0$ phase. By further aging, two variants of $Al_2Ti$ precipitates grow along the two {110} habit planes. On the other hand, in the $L1_2$ phase, the $Al_2Ti$ phase forms on the {100} planes of the $L1_2$ matrix lattice. After prolonged aging the precipitates are rearranged along a preferential direction of the matrix lattice and form a domain consisting of only one variant. It is suggested that the precipitation of $Al_2Ti$ in each matrix alloy occurs to form a morphology which efficiently relaxes the elastic strain between precipitate and matrix lattices.

• 한국결정학회지
• /
• 제18권1_2호
• /
• pp.21-25
• /
• 2007

Dipyridyl 리간드 L'(N,N'-bis-(1-pyridin-4-yl-ethylidene)-naphthalene-1,5-diamine)을 함유한 $CH_2Cl_2$ 용액을 $Co(NO_3)_2{\cdot}6H_2O$을 함유한 MeOH 용액 위에 깔았을 때, 배위 고분자가 아닌, 분자성 코발트 화합물 [$CoL_2(MeOH)(NO_3)_2$] (1)이 형성되었다. 화합물 1의 X-ray 구조 분석 결과, 이 화합물은 pyridyl-amine 리간드 L(N1-(4-Imino-1-methyl-but-2-enylidene)-naphthalene-1,5-diamine)을 함유하고 있었다. 반응 중에 리간드 L'이 리간드 L로 가수분해되었다는 것을 화합물 1의 구조가 강하게 암시하고 있다.

• 제어로봇시스템학회논문지
• /
• 제17권3호
• /
• pp.283-288
• /
• 2011

In this paper, an adaptive signal tracking loop for a GPS L1/L2C/L5 receiver is designed. The design parameters is adjusted according to the receiver's operating conditions such as the signal strength and the receiver dynamics by using the different characteristics of GPS L1, L2C and L5 signal. Simulation results show that the tracking accuracy of the proposed signal tracking loop is better than those of L1, L2C and L5 only signal tracking loop.

• 한국전자파학회논문지
• /
• 제25권6호
• /
• pp.628-636
• /
• 2014

본 논문은 재밍 대응 위성 항법 장치의 5소자 평면 배열 안테나 설계에 대해 기술한다. GPS $L_1/L_2$ 대역에서 공진하는 적층 구조의 패치 안테나 설계를 제안한다. 제안된 안테나는 광대역 및 원형 편파 특성을 구현하기 위해 칩 커플러를 이용한 이중 급전을 사용한다. 배열안테나 측정 결과, 중앙안테나의 전면 방향 이득은 $L_1$과 $L_2$ 대역에서 각각 1.10 dBic, 0.37 dBic, 측면안테나는 $L_1$과 $L_2$ 대역에서 0.99 dBic, -0.57 dBic를 갖는다. 고각 $30^{\circ}$에서 방위각의 이득은 중앙안테나 $L_1$과 $L_2$ 대역에서 평균 -2.08 dBic, -5.33 dBic의 측정 결과를 갖는다. 측면안테나는 $L_1$과 $L_2$ 대역에서 평균 -0.40 dBic, -2.09 dBic의 측정 결과를 갖는다. 제안된 5소자 평면 배열 안테나는 GPS 재밍 대응 장치에 적합함을 확인한다.

• 설비공학논문집
• /
• 제4권4호
• /
• pp.243-252
• /
• 1992

A mixed convection heat transfer from two vertical parallel plates has been studied numerically by the finite difference method. Effects of the Grashof number, the relative length, $L_2/L_1$. the dimensionless temperature ratio, ${\Phi}_2/{\Phi}_1$ and the dimensionless plate spacing, $b/L_1$ are examined for the heat transfer. Independent of the Grashof numbers and $L_2/L_1$, the dimensionless vertical velocity distributions skewed on the left plate as ${\Phi}_2/{\Phi}_1$ decreased. The dimensionless vertical velocity distribution for $Gr/Re^2=1$ and ${\Phi}_2/{\Phi}_1=1.0$ is skewed to the right plate $L_2/L_1=0.5$, symmetric at $L_2/L_1=1.0$ and skewed to the left plate at $L_2/L_1=1.5$. But for $Gr/Re_2=10.0$ and ${\Phi}_2/{\Phi}_1=1.0$ reversed velocity patterns are obtained. Regardless of the Grashof numbers and $L_2/L_1$, the mean Nusselt nembers on the inside surface of the left plate decreases and those of the right inside surface increases as ${\Phi}_2/{\Phi}_1$ increases. Temperature, velocity and mean Nusselt number distributions are apparently not affected by $L_2/L_1$.