• Title/Summary/Keyword: Y-type Ba ferrite

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Formation Mechanism of Y-type Barium Ferrite Prepared by the Glass-ceramic Method

  • Hori, Chinatsu;Miki, Hiroki;Nagae, Masahiro;Yoshio, Tetsuo
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1181-1182
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    • 2006
  • Y-type barium ferrite $(Ba_2Zn_2Fe_{12}O_{22})$ was prepared by the glass-ceramic method. Glasses with composition of $0.1ZnO{\cdot}0.9(0.3Fe_2O_3{\cdot}0.5BaO{\cdot}0.2B_2O_3)$ were prepared, and the precipitation behavior of Y-type ferrite from the glass matrix was investigated by heating glass specimens at various temperature. $\alpha-BaFe_2O_4$ which is a precursor of M-type ferrite $(BaFe_{12}O_{19})$ was precipitated at about 813 K and an unknown compound, phase X, was precipitated at about 850 K. M-type ferrite and Y-type ferrite started to form at about 923 K and 1103 K, respectively. The formation of Y-type ferrite was int erpreted as the result of the reaction of M-type ferrite with a melt of phase X.

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The Effect of Ba and Fe Concentration on Soft Magnetic Properties of Z-Type Barium Ferrite (Z-Type 바리움 페라이트 분말의 연자성 특성에 미치는 Ba 및 Fe 농도의 영향)

  • Cho, Kwang-Muk;Nam, In-Tak
    • Journal of the Korean Magnetics Society
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    • v.19 no.1
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    • pp.12-16
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    • 2009
  • Z-type barium ferrite [($Ba_{3}Co_{0.8}Zn_{1.2}Fe_{24}O_{41}$, $Ba_{3+{\delta}}Co_{0.8}Zn_{1.2}Fe_{24}O_{41}$ ${\delta}$ = 3, 5, 7, 13 wt%. $Ba_{3}Co_{0.8}Zn_{1.2}Fe_{24+{\delta}}O_{41}$ ${\delta}$ = 5, 7, 10 wt% )] were synthesized using co-precipitation method. The microstructure and magnetic properties of synthesized particles were investigated. In all prepared particles M-type Ba ferrite is identified with Z-type Ba ferrite together. It is found that particles having 7 wt% for Ba and 5 wt% for Fe excess addition revealed high saturation magnetization, respectively. All synthesized particles showed relatively high coercivity for device application. This result may be attributed to the contribution of M-type Ba ferrite. Ba and Fe excess addition was not affected to the structural change of CoZnZ Ba ferrite. The certain amount of excess additions of Ba and Fe and the 2 step heat-treatment may be beneficial to the improvement of soft magnetic properties of Z-type barium hexa-ferrite

Magnetic Properties of Hard/Soft Nanocomposite Ferrite Synthesized by Self-Combustion Precursors (자전 연소 전구체로 합성한 나노 크기 경/연 복합페라이트의 자기 특성)

  • Oh, Young Woo;Ahn, Jong Gyeon
    • Journal of the Microelectronics and Packaging Society
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    • v.22 no.3
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    • pp.45-50
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    • 2015
  • The goal of this research is the create novel magnets with no rare-earth contents, with larger energy product by comparison with currently used ferrites. For this purpose we developed nano-sized hard-type/soft-type composite ferrite in which high remanent magnetization (Mr) and high coercivity (Hc). Nano-sized Ba-ferrite, Ni-Zn ferrite and $BaFe_{12}O_{19}/Ni_{0.5}Zn_{0.5}Fe_2O_4$ composite ferrites were prepared by sol-gel combustion method by use of glicine-nitrate and citric acid. Nanocomposite ferrites were calcined at temperature range $700-900^{\circ}C$ for 1h. According to the X-ray diffraction patterns and FT-IR spectra, single phase of NiZn-ferrite and Ba-ferrite were detected and hard/soft nanocomposite ferrite was indicated to the coexistence of the magnetoplumbite-structural $BaFe_{12}O_{19}$ and spinel-structural $Ni_{0.5}Zn_{0.5}Fe_2O_4$ that agreed with the standard JCPDS 10-0325 data. The particle size of nanocomposite turn out to be less than 120 nm. The nanocomposite ferrite shows a single-phase magnetization behavior, implying that the hard magnetic phase and soft magnetic phase were well exchange-coupled. The specific saturation magnetization ($M_s$) of the nanocomposite ferrite is located between hard ($BaFe_{12}O_{19}$) and soft ferrite($Ni_{0.5}Zn_{0.5}Fe_2O_4$). The remanence (Mr) of nanocomposite ferrite is much higher than that of the individual $BaFe_{12}O_{19}$ and $Ni_{0.5}Zn_{0.5}Fe_2O_4$ ferrite, and $(BH)_{max}$ is increased slightly.

Development of Paint-type EM Wave Absorbers for Radar Used in Ships (선박용 레이다의 허상 방지용 PAINT형 전파흡수체의 개발)

  • Jung, Jae-Hyun;Kim, Dong-Il;Song, Jae-Man;Choi, Jung-Hyun
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2005.06a
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    • pp.423-428
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    • 2005
  • We prepared paint-type and sheet-type EM wave absorbers with Mn-Zn Ferrite, Ni-Zn Ferrite, Ba Ferrite, Sr Ferrite, and Sendust against ghosts of a mater in ships. To prepare the absorbers, enamel paint and epoxy paint were used as binders. The prepared EM wave absorber's absorption properties were investigated. The prepared EM wave absorbers have 6 dB over in 2 GHz ${\sim}$ 4 GHz. We compared properties of wave absorption between paint-type and spray-type

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Preparation and Magnetic Properties of Ba-Ferrite Particles Using the Supercritical Water Crystallization Method

  • Nam, Sung-Chan;Kim, Kun-Joong;Park, Sang-Do
    • Proceedings of the Korean Magnestics Society Conference
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    • 2000.09a
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    • pp.433-440
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    • 2000
  • Barium ferrite particles were synthesized from Ba(NO$_3$)$_2$, Fe(NO$_3$)$_3$ and KOH mixed solutions using hydrothermal crystallization in supercritical water. The experimental apparatus for production of barium ferrite is a flow-type apparatus. Fine barium ferrite particles were produced because supercritical water causes the metal hydroxides to be rapidly dehydrated before significant growth takes place. The effects of Fe/Ba ratio and reaction time on the formation, particle size, and magnetic properties of barium ferrite were studied. When Fe/Ba ratio were varied from 0.5 to 12, single-phase barium ferrite powder was only produced in the range of 0.5〈Fe/Ba〈2. Also, with elevating reaction time, the BaO.6Fe$_2$O$_3$ particle size grew smaller. Especially, uniform barium hexaferrite particles of size 100-200nm were obtained at 80sec. In this study, therefore, single-phase barium ferrite particles are highly stable and can be produced continuously in a reaction time of less then 2min.

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Microwave Properties of Co2 Ferrite for Miniaturization of Antenna (안테나 소형화를 위한 Co2 페라이트의 마이크로파 특성)

  • Kim, Jae-Sik;Choi, Eui-Sun;Kim, Kang;Lee, Young-Hie;Song, Sung-Ho;Ahn, Jong-Bok;Kim, Byung-Hwan;Choi, Ji-Young
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.60 no.12
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    • pp.2270-2275
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    • 2011
  • The sintering behavior and microwave properties of ferrite ($Ba_3Co_{2-2x}Zn_{2x}Fe_{24}O_{41}$ ceramics) were investigated for microwave applications. Also PIFA type antenna with ferrite was simulated. All samples were prepared by the solid state reaction method and sintered at $1350^{\circ}C$. All ceramics had relatively density above of 92% compare with theoretical density of $Ba_3Co_2Fe_{24}O_{41}$ ceramics. From the XRD pattens, the Z-type phase was existed as main phase in $Ba_3Co_{2-2x}Zn_{2x}Fe_{24}O_{41}$ ceramics. The permittivity and permeability of $Ba_3Co_{2-2x}Zn_{2x}Fe_{24}O_{41}$ ceramics were increased with Zn additions and decreased rapidly over frequency of 200~600 MHz. Several PIFA type antennas with ferrite and FR4 were simulated. All antenna structure had return loss of less than -10 dB at each resonant frequency. Simulated antenna using both ferrite and FR4 showed size reduction of 25% without a significant decrement of efficiency.