• 한국환경과학회지
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• 제24권11호
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• pp.1331-1341
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• 2015

The removal of Sr ion and Cs ion was investigated to evaluate adsorption properties by using SAN-Zeolite beads immobilized with styrene acrylonitrile (SAN). The adsorption capacities increased with the decrease of SAN/zeolite ratio (SAR) from 2.5 to 0.83. The relationship of adsorption capacity ($q_e$) and SAR was described by experimental equation such as $q_e=20.88+137.81e^{-1.96SAR}$ ($r^2=0.9980$). The adsorption kinetics of Sr ion and Cs ion with SAN-Zeolite beads were fitted well by the pseudo-second-order model. The maximum adsorption capacities of Sr ion and Cs ion calculated from Langmuir isotherm model were 66.97 mg/g and 81.97 mg/g, respectively.

• 환경위생공학
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• 제12권1호
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• pp.49-58
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• 1997

A study on the synthesis of zeolite from bituminous coal ESP fly ash as a raw material, which was emitted from the power plant, was carried out to reduce environmental problems and reuse of the industrial wastes. Bituminous coal fly ash was used as the source of silica and alumina. Zeolite was synthesized by hydrothermal reaction in aqueous NaOH solution with sodium aluminate as additive. The objective of this study is to elucidate the effect of several experimental variables on the synthesis of zeolite. The effects of preroasting temperature, mixing speed, leaching alkalinity, and molar ratio of Na$_{2}$O/SiO$_{2}$ and SiO$_{2}$/Al$_{2}$O of the products were investigated. The synthesized zeolite was proved to be NaA, which is known as 4A type, by comparing with SEM images, and X-ray diffraction analysis. And also we know that the transformation of zeolite A take places into other types of zeolites, i.e. Hydroxysodalite, zeolite P, with the variation of leaching alkalinity.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2004년도 임시총회 및 추계학술발표회
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• pp.195-198
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• 2004

This study applied EK method to remediate contaminated soil by heavy metal(Pb), tried to increase the efficiency of remediation using zeolite as enhanced EK remediation method to overcome the limit of traditional EK remediation method. Adsorption tests on Pb were conducted to apply the EK extraction and test conditions which contained the electrode reversal, operating time were established. After tests, lead-ions were transported into the specific position of zeolite by EK phenomena, then the immobilization of lead-ions at zeolite was developed. Based on these tests, the efficiency of remediation is different with its test conditions. In addition, the efficiency of remediation was improved dramatically by adding zeolite without electrode reversal and satisfied TCLP regulation of EPA in USA through the whole sample range. Finally, absorption and immobilization capacity of zeolite were proved its excellence and confirmed the possibility of application as enhanced EK remediation method.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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• pp.175-176
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• 2006

Zeolite의 이온교환 특성과 균일한 기공과 결정 모양을 가지는 구조적 특성을 이용하여 CdS 양자점 클러스터를 합성하였다. 합성된 CdS-Zeolite는 구조적으로 안정된 나노 크기의 새로운 반도체 물질이 된다. 또한 Zeolite 결정들이 유리판에 밀집하여 배열되는 경향을 이용하므로 CdS 양자점이 합성된 제올라이트를 기판에 정렬, 박막을 형성한다. CdS-Zeolite 결정 박막은 SEM 측정을 통해 구조와 표면 정렬 상태를 알고, photoluminescence 측정으로 양자점 특성의 발광 파장을 가짐을 알 수 있다.

• Journal of Photoscience
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• 제12권1호
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• pp.17-23
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• 2005

Application of a new photocatalyst has been attempted to improve the efficiency and rates of photocatalytic degradation of azo dyes by using a model dye such as Methyl Orange. As a new photocatalyst, $TiO_2$ encapsulated EFAL-removed zeolite Y ($TiO_2$ /EFAL-removed zeolite Y) has been synthesized by ion-exchange in the mixture of EFAL-removed zeolite Y with 0.05 M aqueous [$(NH_4)_2 TiO(C_2O_4)_2.H_2O$] [$TiO(C_2O_4)_2.H_2O$]. This new photocatalyst has been characterized by measuring XRD, IR and reflectance absorption spectra as well as ICP analysis, and it was found that the framework structure of $TiO_2$ /EFAL-removed zeolite Y is not changed by removing the extra-framework aluminum (EFAL) from the normal zeolite Y and the $TiO_2$ inside the photocatalyst exists in the form of $(TiO^{2+})_n$ nanoclusters. Based on the ICP analysis, the Si/Al ratio of the $TiO_2$ /EFAL-removed zeolite Y and the weight of $TiO_2$ were determined to be 23 and 0.061g in 1.0g photocatalyst, respectively. It was also found that adsorption of the azo dye in the $TiO_2$ /EFAL-removed zeolite is very effective (about 80 % of the substrate used). This efficient adsorption contributes to the synergistic photocatalytic activities of the $TiO_2$ /EFAL-removed zeolite by minimizing the required flux diffusion of the substrate. Thus, the photocatalytic reduction of methyl orange (MO) was found to be 8 times more effective in the presence of $TiO_2$ /EFAL-removed zeolite Y than in the presence of $TiO_2$ /normal zeolite Y. Furthermore, the photocatalytic reduction of MO by using 1.0 g of the $TiO_2$ /EFAL-removed zeolite Y containing 0.061g of $TiO_2$ is much faster than that carried out by using 1.0 g of Degussa P-25.

• 대한환경공학회지
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• 제37권8호
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• pp.450-457
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• 2015

본 연구에서는 제올라이트를 PVA에 고정화시켜 새로운 흡착제인 PVA-Zeolite 비드를 제조하고, XRD 및 SEM 분석을 통해 제조한 PVA-Zeolite 비드는 내부에 제올라이트가 잘 고정화된 다공성 구조를 가지고 있는 것을 확인할 수 있었다. 제조한 흡착제에 의한 Cs 이온과 Sr 이온에 대한 흡착특성을 살펴보기 위하여 pH의 영향, 흡착속도, 흡착등온을 검토하였다. Sr 및 Cs 이온에 대한 평형흡착시간은 약 540 min으로 나타났으며, 흡착속도는 유사 1차 속도식 보다는 유사 2차 속도식에 더 잘 부합하였다. 흡착평형 실험결과는 Langmuir 등온식에 잘 적용되었으며, Langmuir 등온식으로부터 구한 Sr 이온과 Cs 이온의 최대 흡착량은 각각 52.08 mg/g와 58.14 mg/g이었다. PVA-Zeolite 비드에 의한 Sr 이온과 Cs 이온의 흡착공정은 외부물질전달단계는 매우 빠르게 이루어지며, 내부입자확산에 의한 흡착반응은 느리게 진행되어 내부입자확산 단계가 흡착속도 결정단계인 것으로 판단된다.

• Applied Biological Chemistry
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• 제31권1호
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• pp.86-91
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• 1988

경북(慶北) 월성산(月城産) Zeolite광석으로 조제(調製)한 $1{\sim}0.5,\;0,5{\sim}0.25,\;0.25{\sim}0.1$ 및 <0. 1mm의 4종류의 Zeolite 획분(劃分)의 비표면적(比表面積)이 수증기(水蒸氣) 및 EGME흡착법(吸着法)에 의(依)해 측정(測定)되었다. 수증기(水蒸氣) 및 EGME에 의(依)한 Zeolite의 비표면적(比表面積)은 각각 평균(平均) 106 및 $161m^2/g$으로 측정물질(測定物質)에 따라 약간의 차이(差異)가 있었으나 두방법(方法) 공히 입경(粒徑)의 대소(大小)에 따른 비표면적(比表面積)의 차이(差異)는 거의 없었다. $H_2O$ 분자경(分子徑)과 Mordenite공경(孔徑)을 근거(根據)하여 비교검토(比較檢討)한 결과측정(結果測定)된 비표면적(比表面積)은 실제표면적(實際表面積)의 일부분(一部分)으로 추정(推定)되었다. 따라서 Zeolite의 표면적(表面積)을 정확(正確)히 측정(測定)하기 위해서는 새로운 측정법(測定法)의 개발(開發) 필요성(必要性)이 인정(認定)된다.

• 한국산학기술학회논문지
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• 제1권2호
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• pp.33-40
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• 2000

본 연구는 반도체 크린룸에서 VOC(volatile organic compound)과 수분을 제거하기 위한 흡착로타에 관한 것이다. 흡착로타는 세라믹 페이퍼 허니컴 기질에 NaX 제올라이트와 TS-1 제올라이트로 만들어졌다. NaX 제올라이트는 수열합성법으로 합성되어졌으며, NaX 제올라이트 결정(2∼3 ㎛)을 seed로 합성 조성에 3∼5 wt%까지 첨가하여 5 ㎛의 균일한 NaX 제올라이트를 성장시켰다. Seed의 첨가는 seed를 첨가하지 않은 합성용액과 비교하여 결정의 크기가 크며, 균일한 NaX 제올라이트 결정을 성공적으로 합성하였다. TS-1 제올라이트는 초기 반응액의 pH를 변화시켜 합성하였다. 반응물의 pH는 10.0에서 11.5 까지의 범위를 가지며, PH 10.4에서 큰 기공(8∼10 (equation omitted))을 가진 TS-1 제올라이트(ETS-10)가 합성되는 반면 pH가 11.5에서는 작은 기공 (3∼5 (equation omitted))을 갖는 TS-1 제올라이트(ETS-4)가 합성되었다.

• 한국토양비료학회지
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• 제48권3호
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• pp.218-224
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• 2015

Zeolite may help crop growth, yield increase, and salt removal. Field experiment under greenhouse cultivation was conducted to study the effect of zeolite application on growth and yield of Chinese cabbage (Brassica campestris L.) and soil. Soil was classified as Gyuam series (coarse silty, mixed, nonacid, mesic family of Aquic Fluvaquentic Eutrudepts). Six zeolite rates were 0, 3, 5, 10, 20 and $40Mg\;ha^{-1}$. Experimental design was a completely randomized design. Chinese cabbage was grown three times consecutively. Established plant number of plant and yield as fresh weight (F.W.) were measured and soil samples were taken before and after harvesting. Chinese cabbage yield was $76.9Mg\;ha^{-1}$ at a rate of $20Mg\;zeolite\;ha^{-1}$, $54.3Mg\;ha^{-1}$ at a rate of $5Mg\;zeolite\;ha^{-1}$, and $51.3Mg\;ha^{-1}$ at control (no zeolite), respectively. Second order regression analysis using zeolite rate and yield showed that optimum zeolite application rate was between 24 and $26Mg\;ha^{-1}$. The regression equation explained about 88% of the yield variability. The electrical conductivity (EC) decreased from 3.2 to $1.0dS\;m^{-1}$ for all treatments so that salt accumulation was not a concern. Based on the results, we recommend that optimum zeolite application rate is between 20 and $24Mg\;ha^{-1}$ for Chinese cabbage under greenhouse cultivation.

• 한국토양비료학회지
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• 제18권4호
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• pp.352-358
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• 1985

1~0.5mm모래로 충전(充塡)한 sand column을 통해서 Zeolite가 수직(垂直) 유실(流失)과 수리전도도의 변화(變化)에 미치는 양이온의 영향(影響)을 조사(調査)한 결과(結果)는 다음과 같다. 1. Zeolite의 유실량(流失量)의 정도(程度)는 Na->K->$NH_4-$ Zeolite 순이었고 Mg-과 Ca-Zeolite는 유실(流失)되지 않았다. 2. Zeolite의 수직유실(垂直流失)은 주로 입자(粒子)들의 분산(分散)에 기인(基因)하였으며 투과용액(透過溶液)이 0.01N 농도(濃度)의 염용액(鹽溶液)에서 증류수(蒸溜水)로 바뀔때 분산(分散)이 가장 잘 일어났다. 3. 수리전도도(水理傳導度)의 변화(變化)가 심한 column 일수록 Zeolite 유실량(流失量)이 많았다.