• Bulletin of the Korean Chemical Society
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• 제29권4호
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• pp.795-798
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• 2008

The formation of complex $XeHCl^+$ in the collision-induced reaction of $Xe^+$ with HCl has been studied by use of classical dynamics procedures using the London-Eyring-Polanyi-Sato empirical potential energy surfaces. A small fraction of trajectories on the $Xe^+$ + HCl and Xe + $HCl^+$ surfaces lead to the formation of complex $XeHCl^+$ with life-times of 1-2 ps which is long enough to survive many rotations before redissociating back to the reactant state. The formation of complex $XeHCl^+$ occurs mainly from collision angle of $\Theta$ = ${45^{\circ}}$.