• Title/Summary/Keyword: X-ray 회절분석

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Simulation of amorphous selenium considering diffraction and interference models (간섭과 회절 모델을 고려한 비정질 셀레늄(a-Se) 시뮬레이션)

  • Kim, Si-hyung;Song, Kwang-soup
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2012.10a
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    • pp.997-999
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    • 2012
  • Digital X-ray image detector is widely used for radiodiagnosis. Amorphous selenium has been received attention as one of the major material that confirmed photoconductor of direct methode detector. We analysis the photocurrent using 2-dimensional device simulator when blue-ray (${\lambda}=486nm$) is irradiated and high voltage is biased. We evaluate electron-hole generation rate, electron-hole recombination rate, and electron/hole distribution in the amorphous selenium. This simulation methode is helpful to the analysis of digital X-ray image detector. We expect that many applications will be developed in digital X-ray image detector using 2-dimensional device simulator.

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Mossbauer Effect on the Influences of Substituted $Al^{3+}$ of Goethit in Clay Cheju Island (제주도 찰흙에 함유된 Goethite에서 $Al^{3+}$ 치환 영향에 대한 Mossbauer 효과)

  • 강동우;김두철;고정대;홍성락;송관철
    • Journal of the Korean Magnetics Society
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    • v.7 no.4
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    • pp.196-204
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    • 1997
  • In order to study the effect of substituted $Al^{3+}$ of goethite, which was collected from Shinpyeongli in Cheju Island, we used X-ray diffractometer and Mossbauer spectrometer. In X-ray diffraction analysis, the X-ray diffraction peaks of goethite are not detected due to the high substituted Al contents of goethite. Isomer shifts indicated that the valence of Fe ions is almost oxidized trivalent of high spin state. It is believed that the contents of substituted diamagnetic $Al^{3+}$ for $Fe^{3+}$ is about 15.5 mol%. It seems that Neel temperature and saturated magnetic hyperfine field of the clay goethite are about 250 K and 498 kOe, respectively. For the temperature lower than Neel temperature, quadrupole splittings of the clay goethite are greatly influenced by $Al^{3+}$ substitution. It is believed that the high decrease of Neel temperature and magnetic hyperfine field of the clay goethite results from the magnetic dilution produced by substituting the diamagnetic $Al^{3+}$/TEX> for $Fe^{3+}$.

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Dioctahedral Chlorite-Smectite Mixed-Layer Minerals in the Sandstones of the Ulleung Basin, Offshore SE Korea (울릉분지 사암 내에 발달된 이팔면체 녹니석 - 스멕타이트 혼합층 광물)

  • Son Byeong-Kook
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.2
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    • pp.73-81
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    • 2005
  • Mineralogical and chemical examinations were performed on chlorite-smectite mixed layer minerals that occur in the sandstones from a petroleum exploration well in the southern part of the Ulleung Basin. X-ray diffraction and chemical analyses show that the chlorite-smectite mixed layer mineral is tosudite, a 1 : 1 R1 ordered interstratification of chlorite and smectite with an overall dioctahedral character. This mineral is almost the same as the tosudite reported from hydrothermally-altered regions, which is rich in Li. This fact indicates that the tosudite area may be affected by hydrothermal events, because the studied well is located in the tectonically-deformed area, in which lots of trust faults and folds are present. In these respects, the formation of tosudite is probably due to the variable effect of hydrothermal fluids from the deeper part of the area.

The Morphological Properties of Acorn Starch Granules and Starch Gels (도토리 전분 및 전분겔의 형태학적 특성 연구)

  • 김영아
    • Korean journal of food and cookery science
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    • v.8 no.1
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    • pp.9-14
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    • 1992
  • The morphological properties of acorn starch granules and starch gels were examined with scanning electron microscope and X-ray diffractometer. The shape of acorn starch granule was rounded triangular and some elliptical. The size distribution of starch granule was also analyzed. The mean value of minor axis, major axis and the ratio of those were 4.785 $\mu\textrm{m}$, 7.30 $\mu\textrm{m}$ and 0.68, respectively. The surface micro-structure of acorn starch gels were investigated by SEM. Acorn crude and refined starch gel were very different in surface micro-structure. X-ray diffraction pattern of acorn starch was C-type, and the pattern of acorn starch gels were extremely different because of disintegration of starch granules by gelatinization. The diffraction intensity of acorn refined starch gel was slightly higher than crude starch gel.

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Nonstoichiometry and Physical Properties of the Perovskite $CaGa_{1-x}Fe_xO_{3-y}$ System (페롭스카이트 $CaGa_{1-x}Fe_xO_{3-y}$계의 비화학량론과 물리적 성질)

  • Rho, Kwon Sun;Ryu, Kwang Hyun;Chang, Soon Ho;Yo, Chul Hyun
    • Journal of the Korean Chemical Society
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    • v.40 no.5
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    • pp.295-301
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    • 1996
  • A series of solid solutions of the $CaGa_1-xFexO_3-y$ system with the compositions of x=0.25, 0.50, 0.75, and 1.00 has been prepared at $1150^{\circ}C$ under an atmospheric air pressure. The structure, nonstoichiometric chemical formula, and the distribution of cations for the solid solutions are determined by X-ray diffraction analysis, Mohr salt titration, Mossbauer spectroscopic analysis. Their physical properties are discussed with electrical conductivity and magnetic measurements. The crystal system of all the compositions is a brownmillerite orthorhombic system from the X-ray diffraction analysis and the reduced lattice volume increases linearly with x value except that of the composition of x=0.25. All the solid solutions do not contain $Fe^{4+}$ ion and the mole number of oxygen vacancies or y value is 0.50 from Mohr salt analysis. The oxidation state of Fe ion, the coordination state, the structure change in the Brownmillerite-type structure, and the distribution of $Ga^{3+}$ and $Fe^{3+}$ ions are discussed with Mossbauer spectroscopic analysis. The electrical conductivity increases and activation energy decreases, as x value increases. The traditional semiconducting property of this system is described in terms of band theory. The compositions of x=0.50∼1.00 show a thermal magnetic hysteresis in the magnetic measurement with the cooling conditions, which is discussed in terms of the space group and Dzyaloshinsky-Moriya interaction.

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Pulsed Laser Deposition $Na_{0.5}K_{0.5}NbO_3$ Thin Film (PLD 기법에 의한 $Na_{0.5}K_{0.5}NbO_3$ 박막 제작)

  • 최원석;문병무;조중래
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2000.11a
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    • pp.33.1-35
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    • 2000
  • Na-K-Nb system showed a number of ferroelectric phases in bulk ceramic. [001]-axis oriented single-phase $Na_{0.5}/K_{0.5}NbO_3$(NKN) thin film have been grown on $LaA1O_3$substrates using KrF excimer laser. X-ray diffraction $\theta$-2$\theta$ scan, rocking curves, and $\varphi$ scan data evidence highly c-axis oriented along the [001] direction.

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Pulsed Laser Deposition $Na_{0.5}K_{0.5}NbO_{3}$ Thin Film (PLD 기법에 의한 $Na_{0.5}K_{0.5}NbO_{3}$ 박막 제작)

  • 최원석;문병무;조중래
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.33-35
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    • 2000
  • Na-K-Nb system showed a number of ferroelectric phases in bulk ceramic. [001]-axis oriented single-phase Na$_{0.5}$K$_{0.5}$NbO$_3$ (NKN) thin film have been grown on LaA1O$_3$ substrates using KrF excimer laser. X-ray diffraction $\theta$-2$\theta$ scan, rocking curves, and $\phi$ scan data evidence highly c-axis oriented along the [001] direction.ion.

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Crystal Structure and Magnetic Properties of $(LaS)_xCrS_2(x{\approx}1.20)$ ($(LaS)_xCrS_2(x{\approx}1.20)$의 결정구조와 자기적 특성)

  • Jo, Nam-Ung;Yu, Gwang-Su;Jeong, Hyeong-Jin
    • Korean Journal of Materials Research
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    • v.4 no.6
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    • pp.704-709
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    • 1994
  • The $(LaS)_xCrS_2(x \approx 1.20$) of the incommensurate misfit layer was systhesized from reactant mixture of$La_S_3$,Cr and S at 1273K. Powder X-ray diffration of $(LaS)_xCrS_2(x \approx 1.20$) was indexed as a complex structure consisted with a monoclinic LaS-sublattice, a triclinic $CrS_{2}$-sublattice and their superlattice. The temperature dependence of sublattice dimension was investigated by the X-ray diffraction analysis at low temperature. The magnetic susceptibility of $(LaS)_xCrS_2(x \approx 1.20$) was measured between 77K and room temperature using a Faraday balance method. $(LaS)_xCrS_2(x \approx 1.20$) was paramagnetic on a $\sigma$-H plot at room temperature. The observed effective magnetic moment( p dr) was in fair agreement with the value calculated by spin-only contribution for $Cr^{3+}$ and spin and orbital contribution for $La^{3+}$.

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Mineralogy of Cu-Co Ores from Democratic Republic of Congo (콩고민주공화국 동-코발트 광석의 광물학적 특정)

  • Cho, Hyen-Goo;Seo, Hye-Min;Kim, Soon-Oh;Kim, Young-Ho;Kim, Sang-Bae
    • Journal of the Mineralogical Society of Korea
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    • v.23 no.4
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    • pp.305-313
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    • 2010
  • Mineralogical characteristics of Cu-Co ores from the Central African Copperbelt in the Democratic Repblic of Congo are studied using powder X-ray diffractometer, general area detector X-ray diffractometer, and electron proble microanalyzer. Black ores are mainly composed of heterogenite (cobalt oxide/hydroxide mineral) and malachite (copper carbonate mineral), whereas green ores are only composed of malachite. Heterogenite shows very bright white color under the reflected microscope, and belongs to 3R polytype, because it has d-spacings at $4.39{\AA}$ and $2.316{\AA}$. Since NiO and $Fe_20_3$ content of heterogenite are lower than those of 3R polytype from other localities, it cannot completely exclude the presence of 2H polytype in heterogenite from this study. Malachite is light grey color under the reflected microscope with approximate chemical formula of $Cu_{1.97}Co_{0.02}Fe^{2+}{_{0.01}}CO_3(OH)_2$. Heterogenite and malachite were probably formed at the supergene emichment stage, the last mineralization stage in the Central African Copperbelt. Cobalt seems to be much more emiched in the black supergene (oxy)hydroxide ore than those in the primary sulfide ore.

The electron density distribution and the structure of semiconductor HgCdTe (반도체 HgCdTe의 전자 밀도 분포와 결정 구조)

  • Kook-Sang Park;Ky-Am Lee
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.4 no.4
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    • pp.388-394
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    • 1994
  • A Hg(0.79)Cd(0.21)Te single crystal has been grown by the Traveling Heater Method(THM). Its zinc blend cubic structure is identified from the X-ray diffraction patterns and its lattice constant is determined to be $6.464 {\AA}$ using the least-square method of Cohen. From the values of the lattice constant, the composition x is determined to be 0.21. The electron density is calculated from the relative intensities of the scattered X-ray and compared with the theoretically calculated values. From the electron density distribution, it is shown that the crystal binding of Hg(1-x)Cd(x)Te(MCT) is mainly covalent and has tetrahedron bonds between adjacent atoms.

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