• Tribology and Lubricants
• /
• v.26 no.6
• /
• pp.317-321
• /
• 2010

Thin films of tin sulphide (SnS) have been formed by a novel 2-stage process where-in D.C. magnetron sputtering was used to deposit to thin films of tin (Sn) and the layers then sulphidised using 5% hydrogen sulphide ($H_2S$) gas in Argon. Although it was not found possible to deposit high quality thin films of tin directly onto glass substrates, excellent layers of tin were produced by using molybdenum (Mo) coated glass as the substrate material. The chemical and physical properties of the SnS layers formed were determined using scanning electron microscopy, energy dispersive x-ray analysis, x-ray diffraction studies and using reflectance versus wavelength measurements and these related to the conditions of synthesis. The data shows that it should be possible to produce conventional "substrate structure" devices based on the use of this technology.

• Journal of the Korean Chemical Society
• /
• v.39 no.8
• /
• pp.627-634
• /
• 1995

Layered double hydroxides ($Mg-Al-CO_3$ systems, LDH), which are hydrotalcite-like anionic clay minerals, having different $Mg^{2+}\;to\;Al^{3+}$ ratio were synthesized by coprecipitation method. The subsequent products were characterized by the following methods; elemental analysis, X-ray powder diffraction, thermal analysis (DSC and TGA), FT-IR and $^{27}$Al-MAS NMR. X-ray powder patterns showed that the products formed were layered structure materials. Two heat absorption peaks were observed around 20 ∼280$^{\circ}C$ (surface water and interlayer water) and 280∼500$^{\circ}C$ (water from lattice hydroxide and carbon dioxide from interlayer carbonate) in DSC diagrams, and they were quantitatively analyzed by TGA diagrams (in case LDH4 16.2% and 28.6% respectively). FT-IR spectra indicate that the interlayer carbonate ions occupied symmetrical sites between two adjacent layers in a parallel direction. $^{27}$Al-MAS NMR spectra show only single resonance (8.6 ppm) of the octahedrally coordinated aluminum similar magnesium. When LDH4 was calcined at 560$^{\circ}C$ for 3 hours in air, its layered structure was destroyed giving a mixed metal oxide. However it readily became rehydrated in aqueous chromate solution to its original structure.

• Journal of the Mineralogical Society of Korea
• /
• v.22 no.1
• /
• pp.49-61
• /
• 2009

We studied the mineral composition and mineral distribution pattern of 131 surface sediments collected at the cruise in 2000 and 2007 from Southeastern Yellow Sea, South Sea of Korea and Southern part of Jeju Island. Mineral compositions of surface sediments were determined using the quantitative X-ray diffraction analysis. Surface sediments were composed of rock forming minerals (quartz 37.4%, plagioclase 11.7%, alkali feldspar 5.5%, hornblende 3.1%), clay minerals (illite 19.2%, chlorite 4.7%, kaolinite 1.8%) and carbonate minerals (calcite 10.7%, aragonite 3.4%). Distribution of clay minerals is very similar with fine-grained sediments, and especially same as the distribution of HSMD (Hucksan Mudbelt Deposit), SSKMD (South Sea of Korea Mudbelt Deposit) and JJMD (Jeju Mudbelt Deposit). The coarse sediment seemed to be relic sediment during the last glacial maximum and mainly consisted of rock forming minerals. Whereas the fine sediments mainly composed of clay minerals. Based on the clay mineral composition, main ocean current and geographical factor, HSMD and SSKMD might have derived from the rivers around the Korean Peninsula. However, JJMD is complex mudbelt deposit, which formed by Korean rivers and oceanic sediments.

• Journal of the Mineralogical Society of Korea
• /
• v.27 no.3
• /
• pp.107-114
• /
• 2014

In this study, we tried to determine the origin of fine-grained sediments in Southeastern Yellow Sea Mud patch (SEYSM) using principal component analysis coupled with semi-quantitative X-ray diffraction analysis for 4 major clay minerals. We used 51 marine surface sediments from SEYSM and 33 surface sediments of rivers flowing into the Yellow Sea. We made bioplot diagram using R program with principal component 1 and component 2 because the two components might contain about 98% of all data. The content of each clay mineral in the south and north regions of SEYSM are almost similar. In the biplot, SEYSM sediments distribute close to Korean rivers sediments than Huanghe and Changjiang sediments. Based on these results, we suggest that SEYSM is originated from the Korean rivers sediments. The higher accumulation rate in the SEYSM compared to the sediment discharge from neighboring Korean rivers can be explained by erosion and reworking of surface sediments in this area. The principal component analysis can be used for the provenance research of marine sediments around the Korean Peninsula.

• Journal of the Mineralogical Society of Korea
• /
• v.26 no.3
• /
• pp.189-196
• /
• 2013

In this study, we tried to define the origin of fine-grained sediments in Southwestern Cheju Island Mud (SWCIM) using principal component analysis. We used relative clay mineral compositions using 138 marine surface sediments, 4 Huanghe sediments and 3 Changjiang river sediments by the semi-quantitative X-ray diffraction analysis. We made bioplot diagram using R program with principal component 1 and component 2 because they might contain more than 90% of all data. Although the distribution pattern of each clay minerals in SWCIM is so intricate, smectite and kaolinite contents are high in the west region, but illite and chlorite contents are rich in the east region. In the biplot, the east region of SWCIM distribute around Changjiang river, whereas west region of SWCIM disperse around Huanghe. Our results might reveal that west region of SWCIM is mainly originated by Huanghe, but east region of SWCIM by Changjiang River.

• Journal of the Mineralogical Society of Korea
• /
• v.23 no.1
• /
• pp.15-23
• /
• 2010

The absolute clay mineral compositions and regional distribution of the 131 bulk marine surface sediments around the Jeju Island was compared to their relative compositions and distribution using quantitative X-ray diffraction analysis. Average absolute clay mineral composition is illite 15.3% (0.5~40.5%), chlorite 2.6% (0~7.9%), and kaolinite 1% (0~5.6%). Total contents of the clay minerals are very high in the South Sea of Korea, northwestern part and southern offshore of Jeju Island. The average relative composition is illite 70.9% (16.7~89%), chlorite 21.5% (8.4~68.5%), and kaolinite 7.6% (0~29.3%). Relative illite contents are high in the northwestern and southeastern part of study area, and southern part of Jeju Island. Chlorite contents are high in the eastern part of study area and western part of Jeju Island. Kaolinite contents are high in the western and southern part of Jeju Island, and southern offshore of Jeju Isand. Absolute Distribution patterns are very similar to those of fine-grained (from clay to silt) sediment, whereas relative distribution patterns do not show any relationship with those of fine-grained sediment.

• Journal of the Korean Ceramic Society
• /
• v.36 no.2
• /
• pp.151-158
• /
• 1999

$\varepsilon$-Caprolactame as organic monomer was intercalated in the interlayer space of montmorillonite and polymerized by polymerization reaction so that the inorganic polymer and organic polymer could be combined each other by chemical bonding. The results of X-ray and IR analysis showed that the polymerization reaction of $\varepsilon$-caprolactame between the interlayer spaces has been performed sucessfully. In order to study polymeric reaction product in detail we have isolated the polymerized material from the interlayer space and analyzed it by X-ray diffractometer and IR-Spectrocopy. The comparison of these results with them of the analyses for thee pure polymer which has been synthesized by polymeric reaction of $\varepsilon$-carolactame without montmorillonite showed that the obtained both polymeric materials are the same compounds.

• Korean Journal of Food Science and Technology
• /
• v.4 no.2
• /
• pp.77-83
• /
• 1972

In order to study the processing adaptability of naked barley, SEDOHADAKA variety produced in Cheolanam-do(1971) was milled after polishing and examined with respect to its proximate principles, amino acid composition, viscosity, raising power, and amylose content, alkali number, blue value and X-ray diffraction pattern of its starch. The results are summarized as fllows: 1) Crude fiber content of naked barley which was milled at 81.6% (A), 79.2% (B) and 74.1% (C) was $2.48{\sim}2.36%$, indicating higher level than wheat flour. 2) Whereas the initial gelatinization temperature of naked barley flour was similar to that of wheat flour, the value of naked barley starch was $89.5^{\circ}C$, higher than that of wheat starch, Amylose content of naked barley starch was 28.5%, similar to wheat starch. 3) Raising power of naked barley starch was generally lower than that common cereal starches. 4) According to the X-ray diffraction pattern diagram, the degree of crystallization was lower in naked barley starch than in non-glutinous rice starch.

• Journal of the Korean Home Economics Association
• /
• v.41 no.8
• /
• pp.55-62
• /
• 2003

Natural dyes generally fan into two categories; organic dyes coming from animals and plants and inorganic dyes obtained from various minerals such as bengala, loess, ultramarine, prussian blue and etc. The main components of volcanic ash is clay mineral such as kaolinite, illite, quartz. Clay minerals Composing volcanic ash are kaolinite［$Al_4Si_4O_{10}{(OH)_{8}}$］, illite［$K_{X}Al_2(Si,\;Al)_4O_{10}{(OH)}_2$］, quartz［$SiO_2$］, homblende［$Na_{0-1}\;Ca_2{(Mg,\;Fe,\;Al)}_5{(Si,\;Al)}_{8}O_{22}{(OH)}_2$］and etc. And the redish color mainly comes from iron oxide. In this paper, two different classes of dyeing process were tested; dyeing with volcanic ash only and cationic agent pre-treatment followed by dyeing with volcanic ash. The compositions of the volcanic ash powder and the volcanic ash deposited on the cotton knitted fabrics identified by energy dispersive spectrometer and XRD analysis. The major chemical components of volcanic ash deposited on the cotton knitted fabrics were confirmed to be the saicon oxide, iron oxide, and aluminum oxide and etc. According to the analysis by XRD and EDS-SEM, kaolinite, illite and quartz were also identified.

• Journal of the Mineralogical Society of Korea
• /
• v.17 no.2
• /
• pp.169-176
• /
• 2004

The Osaeg hotspring (long. $128^{\circ}$ 56'E, tat. $37^{\circ}$ 06'N) located in the northester part of Kangwon-do, Korea. The pH value of the hot spring water is 8.31, and the EC, $SO_4$, F and Na are 196 ${\mu}\textrm{s}$/cm, 10.88 mg/L, 8.19 mg/L, and 37.07 mg/L, respectively. The ocherous precipitates are precipitated on the stream bottom of Osaeg hot spring drainage. X-ray diffraction analysis (XRD), scanning electron microscopy (SEM) and stereo-microscope were used to analyze the precipitates. X-ray diffraction analysis shows that the precipitates consist mainly of poorly crystalline materials and messelite. Many spherical and rod-shaped bacteria-like forms were observed in the precipitates.