• Journal of the Korean Wood Science and Technology
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• 제2권3호
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• pp.3-16
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• 1974

One of the disadvantages of. wood and wood products is their hydroscopicity or dimensional instability. This is responsible for the loss of green volume of lumber as seasoning degrade. Dimensional stabilization is needed to substantially reduce seasoning defects and degrades and for increasing the serviceability of wood products. Recently, considerable world-wide attention has been drawn to the so-called Wood-Plastic Composites by irradiation-and heat-catalyst-polymerization methods and many research and developmental works have been reported. Wood-Plastic Composites are the new products having the superior mechanical and physical properties and the combinated characteristics of wood and plastic. The purpose of this experiment was to obtain the basic data for the improvement of wooden materials by manufacturing WPC. The species examined were Mulpurae-Namoo (Fraxinus, rhynchophylla), Sea-Namoo (Carpinus laxiflora), Cheungcheung-Namoo (Cornus controversa), Gorosae-Namoo (Acermono), Karae-Namoo(Juglans mandshurica) and Sanbud-Namoo (Prunus sargentii), used as blocks of type A ($3{\times}3{\times}40cm$) and type B ($5{\times}5{\times}60cm$), and were conditioned to about 10~11% moisture content before impregnation in materials humidity control room. Methyl methacrylate (MMA) as monomer and benzoyl peroxide (BPO) as initiator are used. The monomer containing BPO was impregnated into wood pieces in the vacuum system. After impregnation, the treated samples were polymerized with heat-catalyst methods. The immersed weights of monomer in woods are directly proportionated to the impregnation times. Monomer impregnation properties of Cheungcheung-Namoo, Mulpurae-Namoo and Seo-Namoo are relatively good, but in Karae-Namoo, it is very difficult to impregnate the monomer MMA. Fig. 3 shows the linear relation between polymer retentions in wood and polymerization times; that is, the polymer loadings are increasing with polymerization times. Furthermore species, moisture content, specific gravity and anatomical or conductible structure of wood, bulking solvents and monomers etc have effects on both of impregnation of monomer and polymer retention. Physical properties of treated materials are shown in table 3. Increasing rates of specific gravity are ranged 3 to 24% and volume swelling 3 to 10%. ASE is 20 to 46%, AE 14 to 50% and RWA 18 to 40%. Especially, the ASE in relation to absorption of liquid water increases approximately with increase of polymer content, although the bulking effect of the polymerization of monomer may also be influential. WPCs from Mulpurae-Namoo and Cheungcheung-Namoo have high dimensional stability, while its of Karae-Namoo and Seo-Namoo are-very low. Table 4 shows the mechanical properties of WPCs from 6 species. With its specific gravity and polymer loading increase, all mechanical properties are on the increase. Increasing rate of bending strength is 10 to 40%, compression strength 25 to 70%, ;impact bending absorbed energy 4 to 74% and tensile strength 18 to 56%. Mulpurae-Namoo and Cheungcheung-Namoo with high polymer content have considerable high increasing rate of strengths. But incase of Karae-Namoo with inferior monomer impregnation it is very low. Polymer retention in cell wall is 0.32 to 0.70%. Most of the polymer is accumulated in cell lumen. Effective. of polymer retention is 58.59% for Mulpurae-Namoo, 26.27% for Seo-Namoo, 47.98% for Cheungcheung-Namoo, 25.64% for Korosae-Namoo, 9.96% for Karae-Namoo and 25.84% for Sanbud-Namoo.

• Journal of the Korean Wood Science and Technology
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• 제45권5호
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• pp.622-628
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• 2017

본 연구에서는 국산 참나무류의 고부가가치재 이용기술 개발을 위해 굴참나무와 신갈나무를 대상으로 입목으로부터 마루판재까지의 가공수율을 조사하였다. 또한 참나무류 건조시간 단축을 위한 건조스케줄의 개선 및 물성평가를 수행하였다. 건조시간은 총 173시간이 소요되었으며, 최종함수율은 굴참나무 5.39%, 신갈나무 4.17%로 측정되었다. 건조에 따른 굴참나무와 신갈나무의 재색변화는 ${\Delta}E$ 값이 7~11으로 현저한 변화를 보였다. 건조에 따른 수축률은 굴참나무의 경우, 접선방향 8.1%, 방사방향 5.0%이었으며, 신갈나무의 경우, 접선방향 8.5%, 방사방향 6.2%로 평가되었다. 제재수율은 30~40%, 최종제품수율은 8~15%로 평가되었다. 본 연구에서 조사된 참나무류의 가공특성은 아직까지 저이용되고 있는 국산 활엽수의 효율적인 생산계획을 수립하는데 기여할 수 있을 것으로 기대된다.

• 한국산업보건학회지
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• 제16권1호
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• pp.68-80
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• 2006

This study aimed to prepare the fundamental data and assess the status and trend of exposure level for 5 chemical substances such as sulfuric acid, hydrogen chloride, ammonia, formaldehyde and phenol in manufacturing industry by type of industry, working process, and size of factory, chronological change. Subjects related to this study consist of 146 factories, 12 industries and 17 working processes located in Busan area from Jan. 1997 to Dec. 2001. 1. All 5 kinds of chemical substances by type of industry, working process were generated in chemical manufacturing industry. There were founded in 8 types of industries and 13 types of working processes for ammonia, which is the highest number of in all 5 chemical substances. 2. In terms of the exposure level for 5 chemical substances by type of industry, working process, geometric mean concentration for sulfuric acid was $0.40mg/m^3$ in manufacture of chemicals and chemical products, $0.30mg/m^3$ in compounding process, for hydrogen chloride was 0.57 ppm in manufacture of basic metal, 0.48 ppm in dyeing process, for ammonia was 1.11 ppm in manufacture of rubber and plastic products, 0.94 ppm in buffing process, for formaldehyde was 0.49 ppm in manufacture of wood and of products of wood and cork, except furniture; manufacture of articles straw and plating materials, 0.53 ppm in mixing process, and for phenol were 0.53 ppm in manufacture of chemical and chemical products, 0.55 ppm in compounding process, respectively. Results for 5 chemical substances by type of industry and working process were significantly higher than those of the others(p<0.05). 3. The exposure level for hydrogen chloride, formaldehyde were significantly increased by size of industry (p<0.01). ammonia was significantly decreased by size of industry (p<0.01). 4. In trend of the concentration difference of five chemical substances by chronology, geometric mean concentration for sulfuric acid was significantly increased (p<0.01), hydrogen chloride and ammonia were significantly decreased by year (p<0.05) and for formaldehyde and phenol were decreased in chronological change. According to the above results 5 chemical substances were founded together in a way mixed in the same places one another and concentrations of chemical substances by industry, working process, size of industry and year appeared markedly. The authors recommend more systemic and effective work environmental management should be conducted in workplaces generating five chemical substances.

• 임산에너지
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• 24권2호
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• pp.1-9
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• 2005

친환경적으로 돈분뇨를 처리하기 위하여 목질칩을 이용한 정화조에서 장기 처리한 목질칩과 돈분뇨 성분의 변화 양상을 관찰하였다. 자체 제작한 정화조에 히터를 가동하면서 3일 후 발효 적정온도인 $55{\sim}60^{\circ}C$에 도달하였고, $180{\iota}$/일 돈분뇨 분해능을 보기는 정화조에서 사용하는 목질칩의 성분은 돈분뇨의 처리시기가 경과함에 따라 회분의 양이 증가하여 돈분뇨 자체에 포함되어 있는 여러 무기물 함량이 더해진 것으로 보였다. 알칼리와 유기용매추출물 및 Klason 리그닌함량은 거의 변화가 없었고, 무처리칩에 비해 흘로셀룰로오스의 양은 약 10% 감소하여 발효 중 목질칩이 부탄소원으로 이용되었을 가능성이 있다고 판단되었다. 장기 처리된 돈분뇨의 성분 중 무기물 함량($Ca^{2+},\;Mg^{2+},\;K^+,\;Na^+$ 등)은 무처리칩에 비해 처리기간에 파라 증가하는 경향을 보였고, 중금속(Cd, As, Cu 등)은 거의 검출되지 않았다. 돈분뇨 원액에 비해 전질소 함량은 감소하나 무처리칩보다는 높은 수치를 보여 나중에 돈분뇨를 발효, 분해한 목질칩을 산지의 퇴비화에 사용해도 환경적 문제가 없을 것이라고 판단되었다. 장기 처리에 따른 미생물 변이는 반응기 내의 온도가 급격히 상승하면서 생균수가 증가하였다.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2011년도 추계학술대회 초록집
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• pp.108.1-108.1
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• 2011

This paper proposes the method to develop the fuel of suljigemi pellets using agricultural by-products the occurred during the manufacturing of alcohol. This paper is the goal to make sulgigemi pellet fuel for develops pellet of high calorie. The methods of sulgigemi pellet manufacturing well mix as the dough with the water and the sulgigemi. And then we have dried in the after compression and molding using well mixed the sulgigemi. The moisture of pellets has dried it removed until about 85%. Suljigemi pellet has the effect of zero emission as the soil conditioner using ash after burning. The merits for the sulgigemi pellet are the convenience of storage and custody. Also sulgigemi pellet has the reduction effect of carriage fee, fuel economy and low-cost high-efficiency effects, environmentally clean fuel as CO2 emissions savings. In experiment, we confirmed to calories of the wood pellet and the sulgigemi pellet. The calorie of the suljigemi pellets has high 233 kilo calories than the wood pellets. So the technologies of the sulgigemi fuel pellets are developing low carbon, green growth renewable energy fuel through futuristic energy system will be.

• 펄프종이기술
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• 제41권4호
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• pp.8-14
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• 2009

Characteristics of biodegradable polymers for mulching mat for seedling were investigated. The solvent solubility of polymers is highest in methylene chloride and chloroform. Tensile strength and breaking elongation of polymer dipped paper were increased to the 0.43-1.46 kN/m and the 0.03-0.26%, respectively. PLAs had showed lower glass transition temperature and melting point than those of polyester. As a result, PLA should be most suitable polymer for mulching mat manufacturing. After biodegradation of polymers by lipase, surface of polymers was change to more flat due to enzymatic degradation.

• 한국화재소방학회논문지
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• 제30권2호
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• pp.7-18
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• 2016

본 연구는 주택이나 창고 등의 내부 마감재로 사용하는 합성 목재의 연소 독성평가에 관한 것으로 SEM, 콘 칼로리미터, FTIR를 활용해 집성판, MDF, 미송합판, 코어합판, 나왕 방부목 5종의 재료별 연소가스 독성을 실험 및 분석하였다. 각 재료별 독성특성 중 나왕 방부목에서 이산화탄소($CO_2$)의 치사농도인 100,000 ppm을 2.5배 초과하는 256,965 ppm, 이산화황($SO_2$)의 치사농도인 400 ppm의 3.6배를 초과하는 1,475 ppm이 검출되었다. 집성판은 이산화질소($NO_2$)가 1,569 ppm으로 치사농도인 250 ppm의 6배가 측정되었고, 암모니아($NH_3$)는 MDF에서 치사농도 값인 750 ppm 대비 795 ppm이 측정되었다. 따라서 대부분의 건축 재료에서 인체에 치명적인 가스가 발생되는 것을 확인하였고, 향후 건축 재료의 위해성을 평가하기 위한 기초데이터로 활용하고자 한다.

• Journal of the Korean Wood Science and Technology
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• 제41권6호
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• pp.490-496
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• 2013

폐목재의 재활용으로 인한 보드의 물리 기계적 특성이 하락하는 경향이 있다. 그 원인으로는 가공되어 있던 재료를 재활용함에 있어 그 형상이 불균질하고 기존의 접착제 성분과 이물질로 인한 보드 품질의 불균일과 저하를 초래한다. 또한 접착제에 포함되어 있는 포름알데히드로 인해 높은 방산량을 가지게 된다. 이러한 제품의 질적 하락이 수입되는 파티클보드와의 가격 및 품질 경쟁력 약화로 이어져 국내 보드 산업의 문제점으로 대두되고 있다. 따라서 본 연구에서는 최근 파티클보드의 원재료로 사용되고 있는 합판 정재단 부산물을 이용한 보드를 제조하고 각각의 제조 조건별 물리 기계적 특성을 평가하였다. 그 평가결과로 베니어 적층 복합보드를 EMDI 수지를 이용하여 4~16 mesh의 일반적인 chip 크기로 중층을 제작했을 때 휨강도가 57.7 $N/mm^2$로 OSB 측정결과 26.8 $N/mm^2$에 비해 215% 높은 휨강도를 나타냈으며 7.1~17.3%의 두께팽창률은 내수성을 지닌 보드로서 적합함을 보였다. 또한 0.7 ppm의 포름알데히드 방산량은 E1등급의 평균값 1.5 ppm과 E0 등급 최대값 0.7 ppm의 조건에 충족하며 이러한 결과는 바닥 깔개용 OSB를 대체 가능할 것으로 사료된다.

• 한국가구학회지
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• 제24권2호
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• pp.140-147
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• 2013

In the latest furniture design field, we can find mass production with concept of heterogeneity that is made by harmonizing existing object with other object, which has new value. In order to follow the trend in the reality, various design process method that applied concept of Hybrid is attempted by flexibly combining or changing heterogeneous materials, formations or functions such as combination of new material and wood or IT. However, not like other design fields, its research range in furniture design is limited. This study is conducted in order to overcome and supplement problems that are made when these different materials are combined, such as faults or cracks made due to difference of expansion and contraction coefficient, lack of intensity and change of formation due to external temperature and humidity. Panels that are combined for this study were verified materials that have passed environmental adaptation test throughout the period of 1 year and 2 months, which will be made into a table. By doing this, this study will be an empirical study that establish concept of furniture made with acrylic and provides manufacturing method of combining wood and acrylic. Finally it proposed a new furniture design method that follows the trend by researching new materials with the new concept.

• Journal of the Korean Wood Science and Technology
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• 제39권1호
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• pp.60-67
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• 2011

본 연구에서는 고밀도 우드세라믹을 제조하기 위한 기초 연구로서 수지함침율 및 탄화온도에 따라 제조된 1차 탄화 우드세라믹을 수지 재 함침 후 2차 탄화하여 우드세라믹을 제조하고 밀도경사를 조사하였다. 2차 탄화 후 최소, 평균 및 최고밀도가 1차 탄화 우드세라믹보다 증가하였고, 밀도경사 비율도 증가하였다. 따라서 고밀도와 밀도경사 비율이 작은 균질한 우드세라믹을 제조하기 위해서는 2차 함침과 2차 탄화에 의한 우드세라믹 제조방법도 효과가 있는 것으로 나타났다.