• Journal of the Korean Wood Science and Technology
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• 제34권1호
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• pp.15-22
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• 2006

국내에서 문화재로 지정되어 관리되고 있는 많은 목조 고건축물들의 효과적인 보존 및 관리를 위해서는 목재의 내부 상태를 정확하게 평가할 수 있든 비파괴 검사법이 요구된다. 따라서 본 연구에서는 현장에서 적용 가능한 X선 CT 시스템을 개발하기 위한 연구의 일환으로, 먼저 휴대형 soft-X선 촬영 장치를 사용한 목재의 밀도측정 방법을 확립하고 그 적용 가능성을 확인하고자 하였다. 먼서 측정방법을 확립하기 위하여 X선 강도와 필름명도 사이의 상관관계를 분석하였으며, 또한 관전류와 관전압의 변화에 따른 X선 초기강도의 변화를 확인하여 정량화 하였다. 다음으로 목재의 밀도와 연륜각, 두께가 질량감쇠계수에 미치는 영향을 확인하고, 목재의 침량감쇠계수를 결정하여 Beer의 법칙에 적용함으로써 X선 측정결과로부터 목재의 밀도를 계산할 수 있는 식을 제시하였다. 마지막으로 X선 촬영법을 통해 측정한 밀도를 기존의 치수법에 의한 측정결과와 비교함으로써 앞에서 결정된 밀도측정 방법의 작용 가능성을 확인할 수 있었다. 이상의 결과는 앞으로 개발하고자 하는 X선 CT 시스템에서 입력값으로 요구되는 밀도를 측정하는 방법을 확립하는데 있어서 효과적으로 활용될 수 있을 것으로 기대된다.

• Journal of the Korean Wood Science and Technology
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• 제45권6호
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• pp.836-845
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• 2017

Gravimetric method is usually used to evaluate air-dry density, which is governing physical or mechanical properties of wood. Although it had high evaluation accuracy, the method is time consuming process. Thus, this study was conducted to estimate air-dry density of wood with high accuracy by using polychromatic X-ray and digital detector as alternative of gravimetric method. To quantify polychromatic X-ray projection for evaluating air-dry density, Lambert-Beer's law with the integral value of probability function was used. The integral value was used as weighting factor in the law, and it was determined by conducting simple test at various penetration depths and tube voltage. Mass attenuation coefficient (MAC) of wood also calculated by investigating polychromatic X-ray projection according to species, penetration depth and tube voltage. The species had not an effect on change of MAC. Finally, an air-dry density of wood was estimated by applying the integral value, MAC and Lambert-Beer's law to polychromatic X-ray projection. As an example, the relation of the integral value (${\alpha}$) according to penetration depth (t, cm) at tube voltage of 35 kV was ${\alpha}=-0.00091t{\times}0.0184$ while the regression of the MAC (${\mu}$, $cm^2/g$) was ${\mu}=0.5414{\exp}(-0.0734t)$. When calculation of root mean squared error (RMSE) was performed to check the estimation accuracy, RMSE at 35, 45 and 55 kV was 0.010, 0.013 and $0.009g/cm^3$, respectively. However, partial RMSE in relation to air-dry density was varied according to tube voltage. The partial RMSE below air-dry density of $0.41g/cm^3$ was $0.008g/cm^3$ when tube voltage of 35 kV was used. Meanwhile, the partial RMSE above air-dry density of $0.41g/cm^3$ decreased as tube voltage increased. It was conclude that the accuracy of estimation with polychromatic X-ray and digital detector was quite high if the integral value and MAC of wood were determined precisely or a condition of examination was chosen properly. It was seemed that the estimation of air-dry density by using polychromatic X-ray system can supplant the gravimetric method.

• Journal of the Korean Wood Science and Technology
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• 제26권4호
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• pp.20-25
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• 1998

Radial variation of crystalline state in a stem of Chamaecyparis obtusa E. was examined by x-ray diffraction analyses. Relative crystallinity and degree of crystallite orientation showed significant differences between juvenile and adult wood. That is, Relative crystallinity increased with increasing the age from pith to about 20th annual ring, after which it reached a more or less constant value. On the other hand, degree of crystallite orientation decreased outward from pith to about 10 years and presented almost a constant value thereafter. Crystal width by Scherrer's equation did not show any significant differences between juvenile and adult wood. Therefore, it was considered that crystallinity index and degree of crystallite orientation by x-ray diffraction method could be used for evaluating wood quality.

• Journal of the Korean Wood Science and Technology
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• 제21권1호
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• pp.15-20
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• 1993

X-ray diffractograms of the vessel elements and the wood fibers of Quercus variabilis BLUME were recorded and resolved into characteristic reflections of cellulose I. Some differences were observed in the ratio of integrated intensity and crystallinity index between vessel elements and wood fibers. Present results suggest that cellulose crystal structure in the hardwood species was varied with the elements of wood.

• Journal of the Korean Wood Science and Technology
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• 제22권3호
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• pp.26-31
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• 1994

To provide further information for reutilization of the waste wood obtained after cultivating oak mushroom in Kangwon-do, the crystal structures of the waste wood were investigated and compared to those of normal woods by a series of x-ray diffraction analysis. The results obtained are as follows: 1. An x-ray diffraction diagram of cultivated wood for 5 years was same as that of typical cellulose with some orientation of cellulose crystallites, but that of cultivated wood for 8 years a random. 2. Crystallinity indices in normal and cultivated woods for 5 years ranged from 57% to 60%. In the cultivated wood for 8 years, however, the value showed about 40%. 3. Crystallite widths of cultivated woods for 5 years and for 8 years were 3 nm and 2.5 nm, respectively. 4. Intensity ratios of equatorial and meridional layers did not show any significant differences. From the above results, it is clear that the waste wood obtained after cultivating oak mush room for 5 years showed basically same crystal structures with normal wood. Therefore, we think that the waste wood may be used available for cellulosic material instead of normal wood.

• Journal of the Korean Wood Science and Technology
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• 제20권3호
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• pp.55-60
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• 1992

Japanese red pine (Pinus densiflora S. et. Z.) decayed by brown-rot fungi Tyromyces palustris and Gloeophyllum trabeum were subjected to X-ray diffraction analysis and infrared spectral examinations. Pine woods decayed by T. palustris showed the increase of relative crystallinity in the initial stage of degradation. When the weight loss was above 30%, then the crystallinity went down slowly. In contrast, the wood samples degraded by G. trabeum showed the decrease of crystallinity from the beginning stage of decay. The changes of crystallinity in brown-rotted woods suggested that the degradation rate of crystalline cellulose was varied with the brown rot fungal species. X-ray diffraction analyses also indicated that crystalline cellulose was much more slowly broken down than the amorphous one. The most notable difference in the IR spectra of the brown-rotted wood samples was that the adsorption band centered at 1,730$cm^{-1}$ was significantly diminished in the decayed wood. indicating the degradation of hemicellulose by brown-rot fungi. However, no marked changes of intensities at 1,000, 1,060 and 1,040$cm^{-1}$ were observed in the brown rotted wood samples, suggesting that crystal line cellulose was resistant against the attack by brown rot fungi.

• Journal of the Korean Wood Science and Technology
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• 제21권4호
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• pp.73-78
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• 1993

Crystal structure of tension, opposite and lateral wood of Platanus orientalis L. were analysed in some aspects of crystallinity index, crystallite size, d-spacing of (200) and (004), and integrated intensity ratios with X-ray diffraction method. Crystallinity index and crystallite width in tension wood appeared somewhat larger than opposite or lateral wood. However, d-spacing and integrated intensity ratios were nearly identical irrespective of tension, opposite, and lateral wood.

• Journal of the Korean Wood Science and Technology
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• 제31권6호
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• pp.1-7
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• 2003

The phase transformation from cellulose I into cellulose II in woods by way of Na-cellulose I was examined by x-ray diffraction analysis.The formation of Na-cellulose I in woods increased with the increase of treating time in alkali solution. When compression wood was treated with 20% NaOH solution at room temperature for 1 day, the x-ray diagram showed only Na-cellulose I. On the other hand, the x-ray diagram of tension wood showed a mixture of cellulose I and Na-cellulose I. Cellulose I of tension wood could not be transformed completely into Na-cellulose I even after 10-day treatment, but was transformed into Na-cellulose I after 30-day treatment. Na-cellulose I of compression and tension woods was converted to the cellulose I pattern and the mixture of cellulose I and cellulose II, respectively, after washing with water and drying at 20℃. Cellulose I regenerated from Na-cellulose I in wood could not be converted to cellulose II by delignification. Thus, it revealed that the delignification of the alkali-treated wood did not affect their cellulose structures. From the results, therefore, it can be concluded that lignin in woods prevents the formation of the stable Na-cellulose I and the conversion from cellulose I to cellulose II. This means that the conversion of chain polarity of wood cellulose hardly occurs during mercerization because cellulose microfibrils are fixed by lignin which not to be intermingled.

• Journal of the Korean Wood Science and Technology
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• 제34권1호
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• pp.23-31
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• 2006

X선은 강한 투과성과 직진성으로 인하여 비파괴 검사법으로써 다양한 분야에서 활용되고 있다. 본 연구에서는 고건축물과 같은 목조 건축물에 사용되고 있는 구조부재의 열화를 현장에서 탐지할 수 있는 비파괴 검사법을 개발할 목적으로 X선 CT시스템의 적용가능성을 검토하였다. 먼저 이전 연구의 결과를 바탕으로 CT영상을 구성하는 체계를 확립하고, 얻어진 CT영상을 실제 부재의 단면 형태와 비교함으로써 개발된 시스템의 적용가능성을 확인하였다. 개발된 X선 CT시스템의 적용을 통해 결함의 형태와 크기, 위치뿐만 아니라 결함에서의 밀도 또한 비교적 정확하게 탐지할 수 있음이 확인되었다. 이러한 결과는 건축물에서 사용되고 있는 목재 부재에 열화가 발생하였을 경우에, 열화 발생의 원인을 파악하고 그에 따른 효과적인 대처방안을 수립하는데 있어서 유용하게 활용될 수 있을 것으로 기대된다. 그러나 현재의 시스템은 개발 초기단계로 측정에 따른 소요시간이나 측정회수, 측정 정밀도에 있어서 여러 제약을 받는다. 따라서 이러한 제약을 극복하기 위한 추가적인 연구가 요구된다.

• Journal of the Korean Wood Science and Technology
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• 제48권3호
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• pp.283-290
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• 2020

For visual inspection-based wood identification, optical microscopy techniques typically require a relatively large sample size, and a scanning electron microscope requires a clean surface. These novel techniques experience limitations for objects with highly limited sampling capabilities such as important and registered wooden cultural properties. Synchrotron X-ray microtomography (SR-µCT) has been suggested as an effective alternative to avoid such limitations and various other imaging issues. In this study, four pieces of wood fragments from wooden members used in the Manseru pavilion of Bongjeongsa temple in Andong, Korea, wereused for identification. Three-dimensional microstructural images were reconstructed from these small wood samples using SR-µCT at SPring-8. From the analysis of the reconstructed images, the samples were identified as Zelkova serrata, Quercus sect. Cerris, and Pinus koraiensis. The images displayed sufficient spatial resolution to clearly observe the anatomical features of each species. In addition, the three-dimensional imaging allowed unlimited image processing.