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A Novel Acid-Base Catalyzed Sol-Gel Synthesis of Highly Active Mesoporous TiO2 Photocatalysts

  • Khan, Romana;Kim, Sun-Woo;Kim, Tae-Jeong;Lee, Hyo-Sun
    • Bulletin of the Korean Chemical Society
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    • v.28 no.11
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    • pp.1951-1957
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    • 2007
  • A new synthetic strategy based on the acid-base catalyzed sol-gel method was developed for the preparation of a series of mesoporous TiO2 nanoparticles. A key feature of the method involves a gradual change in pH (0.8- 9) during the sol-gel transition, which guarantees easy introduction of mesoporosity without relying on the well-established sonochemical or template approach. In addition, this method leads to the exclusive formation of the anatase phase stable enough to the calcination temperature up to 600 oC. The physicochemical properties of the particles in the series were characterized by various spectroscopic and analytical techniques such as wide-angle XRD, SAXRD, BET surface area, FE-SEM, TEM, FT-IR, TGA, and XPS. The photocatalytic efficiency of these materials was investigated for the oxidation of toluene under UV-irradiation. All but T-ad in the series exhibited high photocatalytic activity pushing the reaction into completion within 3 h. The reaction followed the first order kinetics, and the rate reaches as high as 3.9 × 10?2/min which exceeds the one with the commercially available Degussa P-25 by a factor of 3.2. When comparison is made among the catalysts, the reactivity increases with increase in the calcination temperature which in turn increases the crystallinity of the anatase phase, thus revealing the following rate orders: T-3 < T-4 < T-5 < T-6.

Development of New Hybrid Cultivar 'Senock' in Zoysiagrass (한국잔디 신품종 '세녹(Senock)' 개발)

  • Choi Soon Soo;Yang Geun Mo
    • Asian Journal of Turfgrass Science
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    • v.18 no.4
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    • pp.201-209
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    • 2004
  • This study was carried out to develope new zoysiagrass cultivar 'Senock' (Patent registration: 10-2003-0072018). Artificial crossing between collected lines of Z. sinica and Z. matrella (collected in South Korea) was conducted to develope F1 plant (CSM) which was cultivated at field for open self-pollination. Among the open pollinated progenies, CSM8 (Senock) showed superior performance in color and density rating. 'Senock' showed genetically dark green color, with medium leaf width ($3.1\pm0.17mm$), low plant height ($14\pm5.67cm$), and wide leaf angle ($67.3\pm11.1degree$). Height to the lowest leaf blade of this cultivar was $2.0\pm0.14cm$, which may allow low mowing height. Specific bands with primer number OPB7 by RAPD analysis can be used for cultivar identification.

Synthesis and Characterization of Transparent Copolyimide Films (II) (투명한 공중합체 폴리이미드 필름의 합성 및 특성 연구(II))

  • Park, Jong-Su;Chang, Jin-Hae
    • Polymer(Korea)
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    • v.33 no.4
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    • pp.313-318
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    • 2009
  • Copolyimides were synthesized from bis (3-aminophenyl) sulfone (APS) and 4,4'-(hexafluoroisopropylidene)diphthalic anhydride (6FDA) containing a fluorine substituent ($-CF_3$) with different mole ratios of 3,3',4,4'-diphenylsulfonetetracarboxylic dianhydride (DSDA) containing a sulfone group (-$SO_2$-). The PI films were obtained from poly (amic acid) (PAA) by solution casting through thermal imidization on a glass plate. Wide-angle X-ray diffraction (XRD), scanning electron microscopy (FE-SEM), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), universal tensile machine (UTM) measurements, and UV-Vis spectrometry were used to assess thermo-mechanical properties, morphology, and optical transparency. Thermal properties and optical transparency decreased with increasing DSDA mole fraction. In contrast, mechanical properties increased with increasing DSDA mole fraction. As compared to conventional PI films, however, the PI copolymer films in this work were found to exhibit better optical transparency.

A Study on the transducer development and multi-point signal and its directivity detection of FBG(Fiber Bragg Grating) hydrophone (FBG(Fiber Bragg Grating) 하이드로폰의 트랜스듀서 개발과 다중점 신호 검출 및 지향성에 관한 연구)

  • 김경복
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.25 no.9B
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    • pp.1551-1562
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    • 2000
  • In the using of FBG developed in home land, we designed and manufactured three types of FBG sound transducers the first in Korea. On FBG transducers manufactured we made an demonstrated on respective frequency response peculiarties in the water and analyzed the special characters. As the experimental result on frequency response peculiarities, we made t possible underwater acoustic detection on C type to maximum 18kHz, And for the purpose of realization on multi-point signal detection on wide scope in the water, in the using of WDM(Wavelength Division Multiplexing) method and passive band-pass filter system, established arrays system and succeeded in multi-point underwater acoustic signal detection to the frequency 1.3KHz out of the two B type FBG transducers. Additionally, it would be possible directivity detection for the objects of its source as the intensity of detection signal varies with the sound source's direction and angle. From now on we prepared a new moment on the practical used study on FBG hydrophone.

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K-Band Radar Development for the Ground Moving Vehicle (지상 이동 차량용 K-대역 레이다 개발)

  • Lee, Jong-Min;Cho, Byung-Lae;Sun, Sun-Gu;Lee, Jung-Soo;Park, Sang-Soon
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.22 no.3
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    • pp.362-370
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    • 2011
  • This paper presents a K-band radar system installed on the ground moving vehicle to detect and track a high-speed target. The presented radar is separated into three search regions to satisfy a wide area detection and a limitation of the installing space of the radar, and each region performs detecting the target independently and tracking the detected target automatically. The presented radar radiating K-band FMCW waveform acquires range and velocity information of the target at the every dwell and receiving antenna of the radar is applied the multiple baseline interferometer to extract the precise angle information of the target. 3-dimensional tracking accuracy of the radar is 0.25 m RMSE measured actually through a fire experiment of an imitation target.

Development of 100[W] LED Flood Lighting with Tunable Colors and Color Temperatures (광색가변 및 색온도 제어용 100[W]급 투광기 개발)

  • Youn, Jin-Sik;Kim, Gi-Hoon;Song, Sang-Bin;Lim, Young-Cheol
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.22 no.12
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    • pp.1-9
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    • 2008
  • This paper is about l00[W] discrete LED floodlight lighting system, light color and color temperature to be controlled using the 3[W] RGBA LED, is developed the product with optical, heat dissipation, circuit, luminaire and system design. The result, color temperature is changed corresponding to black body locus from 2,000[K] to 10,000[K] and The Color Rendering Index(C.R.I) is achieved from 71 to 91 by high C.RI. Driving voltage is $90{\sim}250[Vac]$, circuit efficiency is 87[%], P.F is more than 93. moreover the LED lens is designed to achieve narrow, middle, wide beam angle, heat dissipation design is executed to minimize variation of luminous output by the surroundings temperature and to ensure reliability.

Analysis of Generation Characteristics of a Bifacial BIPV System According to Installation Methods (양면형 BIPV 시스템의 설치환경에 따른 발전특성 분석)

  • Kang, Jun Gu;Kim, Jin Hee;Kim, Jun Tae
    • Current Photovoltaic Research
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    • v.3 no.4
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    • pp.121-125
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    • 2015
  • BIPV system is one of the best ways to harness PV module. The BIPV system not only produces electricity, but also acts as a building envelope. Thus, it has the strong point of increasing the economical efficiency by applying the PV modules to the buildings. Bifacial solar cells can convert solar energy to electrical energy from both sides of the module. In addition, it is designed as 3 busbar layout which is the same with ordinary mono-facial soalr cells. Therefore, many of the module manufacturers can easily produce the bifacial solar cells without changing their manufacturing equipment. Moreover, bifacial BIPV system has much potential in building application by utilizing glass to glass structure. However, the performance of bifacial solar cells depends on a variety of factors, ranging from the back surface to surrounding conditions. Therefore, in order to apply bifacial solar cells to buildings, an analysis of bifacial PV module performance should be carried out that includes a consideration of various design elements, and reflects a wide range of installation conditions. As a result it found that the white insulation reflector type can improve the performance of the bifacial BIPV system by 16%, compared to the black insulation reflector type. The performance of the bifacial BIPV was also shown to be influenced by inclination angle, due to changes in both the amount of radiation captured on the front face and the radiation transmitted to the rear face through the transparent space. In this study is limited design condition and installation condition. Accordingly follow-up researches in this part need to be conducted.

Moving Object Preserving Seamline Estimation (이동 객체를 보존하는 시접선 추정 기술)

  • Gwak, Moonsung;Lee, Chanhyuk;Lee, HeeKyung;Cheong, Won-Sik;Yang, Seungjoon
    • Journal of Broadcast Engineering
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    • v.24 no.6
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    • pp.992-1001
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    • 2019
  • In many applications, images acquired from multiple cameras are stitched to form an image with a wide viewing angle. We propose a method of estimating a seam line using motion information to stitch multiple images without distortion of the moving object. Existing seam estimation techniques usually utilize an energy function based on image gradient information and parallax. In this paper, we propose a seam estimation technique that prevents distortion of moving object by adding temporal motion information, which is calculated from the gradient information of each frame. We also propose a measure to quantify the distortion level of stitched images and to verify the performance differences between the existing and proposed methods.

The Influence of Fluorescent Dye Doping on Efficiency of Organic Light-Emitting Diodes (형광염료 도핑이 유기발광소자의 효율에 미치는 영향)

  • Lee, jeong-gu
    • Proceedings of the Korea Contents Association Conference
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    • 2008.05a
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    • pp.301-305
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    • 2008
  • An organic light-emitting diode(OLED) has advantages of low power driving, self light-emitting, wide viewing angle, excellent high resolution, full color, high reproduction, fast response speed, simple manufacturing process, or the like. However, there are still a number of challenges to get over in order to put it to practical use as a high performance display. First of all, the most important thing is to improve the efficiency of the OLED element in order to commercialize it. To this end, its efficiency can be improved by lowering the driving voltage through the improvement of structure of the OLED element and the application of new organic substance. Therefore, in this study, we have manufactured a red OLED element by applying fluorescent dyes to the emitting layer of the element having the structure of ITO/TPD/Znq2+DCJTB/Znq2/Al and the structure of ITO/CuPc/NPB/Alq3+DCJTB/Alq3/Al, in order to light-emitting various colors or improve the brightness and the efficiency, and then we have evaluated its electrical and optical characteristics.

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Background Treatment Technique of Various Time-Lapse Images (다양한 미속촬영 영상의 배경처리 기법)

  • Kim, Jong-Seong;Kim, Jong-Chan;Seo, Young-Sang;Song, Seung-Heon;Kim, Eung-Kon
    • Proceedings of the Korea Contents Association Conference
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    • 2008.05a
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    • pp.639-643
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    • 2008
  • Since seasonal changes, blooming of a flower, etc., which take place in accordance with passage of time, transpire over an extended duration of time, one performs the Time-Lapse so that one can watch them quickly by compressing time. Because such a Time-Lapse records a wide range of conditions including the place, angle of view, and time found in a natural state in accordance with a precise interval of time and in the samestate, it is also referred to as Interval recording. The Time-Lapse technique is used widely in various fields such as education, science, documentary, and the media. In terms of acquiring a Time-Lapse image, by making it possible for one to treat an image by deleting and adjusting unnecessary backgrounds excluding the main subject for photography such as the flower unlike existing methods and by making it possible for one to apply extensively the real-life recorded image as a library or image data in 2D or 3D, the present study seeks to propose a technique for the background treatment of Time-Lapse image that allows for everyone to bestow creativity to image production easily and conveniently.

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