This research is to determine the stormwater effects on sewer concentrations by measuring and comparing the flow and pollutant concentrations during dry and rainy periods in the existing BOX type combined sewer pipes. The monitoring was carried out in two sites, which are the Daesachen outfall having PE separation wall in BOX type combined sewer pipes and the Yongunchen outfall not having seperatioin wall. The average flow-weighted BOD concentraion in Yongunchen outfall is 2-fold lower than in Daesachen outfall because of the dilution effect from ravine water. However, the pollutant mass loading is 16 fold higher in Yongunchen outfall than in Daesachen outfall because of more flows. According to the research, the separation wall controls 52% pollutant mass during a storm period (11.5 mm/hr rainfall intensity). Therefore, the Yongunchen combined sewer system (CSS) need separation wall to control and to prevent more pollutant input in stream. In Daesachen area, the maximum sewer flow rate during a storm period measured about 10 fold bigger than average sewer flow during dry periods. Also the concentrations between rainy and dry periods increase approximately 33 fold for BOD and 120 fold for SS. In Yongunchen area, it increases about 9 fold for the maximum flow rate, 18 fold for BOD and 22 fold for SS during a storm. Therefore, the research is concluded that the separation wall between stromwater (or ravine water) and sewage can decrease the dilution effect in CSS and control the pollutant loading.
Based on fallen leaves of major Korean conifer species 'Pinus densiflora' and major Korean broadleaved species 'Quercus variabilis', this study sought to identify combustion emission gas types and measure their concentration by means of FTIR (Fourier Transform Infrared) spectrometer. As a result, it was found that there were total 13 types of combustion gas detected from fallen leaves of Pinus densiflora and Quercus variabilis, such as carbon monoxide, carbon dioxide, acetic acid, butyl acetate, ethylene, methane, methanol, nitrogen dioxide, ammonia, hydrogen fluoride, sulfur dioxide and hydrogen bromide. Notably, nitrogen monoxide was additionally detected from fallen leaves of Quercus variabilis. It was found that the overall concentration of combustion gas emitted from the fallen leaves of Pinus densiflora was 4.5 times higher than that from fallen leaves of Quercus variabilis. Particularly, it was found that emission concentration of some combustion emission gas types like carbon monoxide, carbon dioxide and butyl acetate exceeded the upper limit of their time-weighted average (TWA, ppm), while the emission concentration of carbon monoxide and carbon dioxide exceeded their short-term exposure limit (STEL, ppm) for both species. Thus, it was found that carbon monoxide and carbon dioxide have higher hazard to health than other gas types, because these two gas types account for higher than 99% of overall gas emission due to combustion of surface fire starting from litter layer in forest.
Journal of The Korean Society of Agricultural Engineers
/
v.49
no.6
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pp.3-9
/
2007
Stream flow and water quality were measured and analyzed with respect to flow-weighted mean concentrations (FWMCs) of 21 rainfall events from a forested watershed (Forest Research Watershed: FRW) and two mixed watersheds of agriculture and forest (YuPo-Ri Watershed: YPW and WolGog-ri Watershed: WGW) located in the middle of the North Han River basin. The monitoring of each watershed was one year and conducted between 2004 and 2006. YPW showed more intensive agricultural practices than WGW where traditional practices were common. The average of the 21 FWMCs were in the order of YPF>WGW>FRW and were significantly different from each other at the level of 0.05. It was shown that the land use with intensive agricultural practices produced and discharged more NPS pollutants than that with traditional practices and forest. Specially, SS concentrations from the mixed watersheds were significantly higher than those from FRW. Influencing factors on runoff were analyzed rainfall and watershed area. And rainfall intensity was greater impact on runoff than daily rainfall. Measured water quality indices were shown positive correlations among them in general. However, no significant correlation was shown between COD and nutrients(T-N and T-P).
Journal of The Korean Society of Agricultural Engineers
/
v.55
no.4
/
pp.73-82
/
2013
The main objective of this study was to evaluate Representative Concentration Pathways (RCP) scenarios-based flood risk at a Si-Gun level. A bias correction using a quantile mapping method with the Generalized Extreme Value (GEV) distribution was performed to correct future precipitation data provided by the Korea Meteorological Administration (KMA). A series of proxy variables including CN80 (Number of days over 80 mm) and CX3h (Maximum precipitation during 3-hr) etc. were used to carry out flood risk assessment. Indicators were normalized by a Z-score method and weighted by factors estimated by principal component analysis (PCA). Flood risk evaluation was conducted for the four different time periods, i.e. 1990s, 2025s, 2055s, and 2085s, which correspond to 1976~2005, 2011~2040, 2041~2070, and 2071~2100. The average flood risk indices based on RCP4.5 scenario were 0.08, 0.16, 0.22, and 0.13 for the corresponding periods in the order of time, which increased steadily up to 2055s period and decreased. The average indices based on RCP8.5 scenario were 0.08, 0.23, 0.11, and 0.21, which decreased in the 2055s period and then increased again. Considering the average index during entire period of the future, RCP8.5 scenario resulted in greater risk than RCP4.5 scenario.
Precipitation samples were collected by the wet-only event sampling method at Seoul from September 1991 to April 1995. Concentrations of samples for the ion components($NO_3^-, NO_2^-, SO_4^{2-}, Cl^-, F^-, Na^+, K^+, Ca^{2+}, Mg^{2+}$ and $NH_4^+$) were measured in addition to pH and electric conductivity. During the sampling period, 182 samples were collected, but only 163 samples were identified as valid. The pH, calculated from the volume-weighted $H^+$ concentration, was found to be 4.7, indicating a relatively intensive acidity compared with data from other regions of the world, where acid deposition was known to be a problem. Above all, the concentration of non-seasalt sulfate was $84 \mu eq/L$, which was the highest compared to that measured in other regions of the world. The major acidifying ions in the precipitation at Seoul were identified as sulfate and nitrate except for chloride, because the Cl/Na ratio in the precipitation was close to the ratio in seawater. If all of the non-seasalt sulfate and nitrate existed in the form of sulfuric and nitric acids, respectively, the average pH in the precipitation was calculated as 3.7, lower than the measured value. Consequently, the difference between the calculated and measured pH suggest that the acidity of precipitation was neutralized by alkaline species, not due to the low contribution of an anthropogenic air pollutants to the precipitation. The equivalent concentration ratio of sulfate to nitrate was 3.5, which indicated that the contributions of sulfuric and nitric acids to the precipitation acidity were 78% and 22%, respectively.
Real-time analysis of metallic mineral grade and slurry concentration is significant for improving flotation efficiency and product quality. This study proposes an online detection method of ore slurry combining the Prompt Gamma Neutron Activation Analysis (PGNAA) technology and artificial neural network (ANN), which can provide mineral information rapidly and accurately. Firstly, a PGNAA analyzer based on a D-T neutron generator and a BGO detector was used to obtain a gamma-ray spectrum dataset of ore slurry samples, which was used to construct and optimize the ANN model for adaptive analysis. The evaluation metrics calculated by leave-one-out cross-validation indicated that, compared with the weighted library least squares (WLLS) approach, ANN obtained more precise and stable results, with mean absolute percentage errors of 4.66% and 2.80% for Fe grade and slurry concentration, respectively, and the highest average standard deviation of only 0.0119. Meanwhile, the analytical errors of the samples most affected by matrix effects was reduced to 0.61 times and 0.56 times of the WLLS method, respectively.
In order to investigate the complaint rates of subjective fatigue symptoms and study the relationship between them and body type, health awareness in middle school students, we carried out a survey of 1,209 students (654 boy students and 555 girl students) at a middle school in Taejon City by a self-recorded questionnaire. The survey was conducted in June, 1997. The results obtained were as follows: 1. Among complaints of fatigue, "feel like lying down" was the highest, followed by "feel anxious about things", "feel drowsy", "yawning a lot", "eye strain" and "whole body feels tired" in descending order. 2. In the average weighted score of fatigue complaint, dullness and sleepiness (I) was the highest, followed by a difficulty in concentration (II) and bodily projection of fatigue (III) in descending order. Fatigue seems to create mental stress rather than physical burdens. 3. In the classification of body type based on the $R\ddot{o}hrer$ index, the obesity type (145 and above) was 11.0%, standard type (110~144) was 64.7% and leptosomic type (l09 and below) was 24.3%. Comparison between both sexes revealed that the rate of obesity and leptosomic types were significantly higher in boy students than in girl students. 4. In terms body type awareness, the statistics are the following: those who consider themselves to be standard type, 44.3%, slightly obese 24.5%, leptosomic, 23.5% and obese 7.8%. However, the level of obesity awareness was significantly higher in girl students than in boy students. 5. As for health awareness, 36.5% considered themselves healthy, 5.4% generally healthy and 10.1% a little unhealthy, but the level of unhealthy awareness was higher in girl students than in boy students. 6. In the relationship between body type and health awareness, most students thought that they were obese in spite of their standard body type. Also, many students who were obese and leptosomic tended to consider themselves to be a little unhealthy. 7. The more the students were obese or felt unhealthy, the more the average weighted score of fatigue complaints was high.
Lee, Kwon Seob;Jo, Ji hoon;Choi, Bo Kyung;Lee, Hye Lim;Byeon, Sang Hoon
Journal of Korean Society of Occupational and Environmental Hygiene
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v.28
no.1
/
pp.80-90
/
2018
Objectives: This study was performed to propose a domestic occupational exposure limit(OEL) following a health hazard assessment, calculation of a non-carcinogenicity reference concentration worker($RfC_{worker}$) value, and examination of international agencies' exposure limits. It also recommends legal management within the Occupational Safety and Health Act for HCFC-123, which caused an acute hepatotoxicity incident. Methods: An acute hepatotoxicity incident due to the fire extinguishing agent HCFC-123 was investigated. Toxicological hazard and health hazard classifications were examined and a non-carcinogenicity $RfC_{worker}$ value was calculated for HCFC-123. An OEL and the necessity of legal management were recommended as well. Results and Conclusions: An OEL for HCFC-123 of 10 ppm($62.5mg/m^3$), which considered the $RfC_{worker}$ value, 5.56 ppm, produced in dose-response assessment and the exposure level of 19.1-20.9 ppm measured as an eight-hour TWA(time-weighted average) in the incident place, is recommended. HCFC-123 is urged to be included as a chemical requiring legal management in the Occupational Safety and Health Regulations. In addition, it is recommended that a peak exposure of ACGIH be adopted in the Notice of the Ministry of Employment and Labor.
Journal of Korean Society of Occupational and Environmental Hygiene
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v.9
no.1
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pp.87-98
/
1999
The objectives of this study were to evaluate exposures to airborne methylene chloride and postshift carboxyhemoglobin (COHb) in blood of workers engaged in processes using blowing or cleaning agents, and to investigate correlation between methylene chloride concentrations and the blood COHb levels of workers. The geometric mean (GM) of workers' exposures (8 hour-time weighted averages, TWA) to airborne methylene chloride during cleaning molds using rags wetted with the solvent in the manufacture of flexible polyurethane foam (GM = 61.4 ppm), during operating the dip tank for cleaning molds in the manufacture of lens (GM = 61.0 ppm), and during cleaning the blowing nozzles by spraying the solvent in the manufacture of shoes (GM = 117.2 ppm) were exceeded the American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Value ($TLV^{(R)}$)-Time Weighted Average (TWA) (50 ppm). The COHb levels were significantly different among groups (p<0.05). The average COHh levels in blood of non-smoking workers were 2.0% in. low-level (<50 ppm) exposure group, and 3.9 % in high-level (>50ppm) exposure group. The average COHb levels in smoking workers were 3.1% in low-level exposure group, and 4.8% in high-level exposure group. The blood COHb levels of no-exposed workers to methylene chloride were 1.8% in non-smoking group, and 2.8% in smoking group. It was found that the COHb level dependeds on the methylene chloride concentration and smoking habit, and was highly correlated with methylene chloride concentration in air. The correlation coefficient was 0.81 among non-smoking workers. The estimated COHb level (3.6%) and 95% upper confidence limit (4.0%) corresponding to TLV-TWA of methylene chloride exceeded the current ACGIH Biological Exposure Index (COHb 3.5%) for carbon monoxide. The estimated COHb level (5.4%) at 100 ppm exceeded the standard (5%) recommended by National Institute for Occupational Safety and Health (NIOSH) for preventing adverse cardiovascular effect. The estimated COHb value and 95% upper confidence limit at 25 ppm of the Occupational Safety and Health. Adminstration (OSHA) Permissible Exposure Limit-TWA (PEL-TWA) were 2.6% and 3.0%, respectively. It is suggested that COHb in blood be kept below 3.0% to comply with OSHA PEL-TWA.
Mandelic acid is the major metabolite and phenylglyoxylic acid is the minor metabolite of styrene in human. This study was conducted to investigate the correlation between exposure concentrations of styrene and concentration of the metabolites in urine The concentrations of metabolites in urine and exposure concentrations were measured in 60 workers who were occupationally exposed to styrene in FRP industry as well as paint industry and musical instrument manufacturing industry and the concentrations of metabolites in urine ware measured in 90 workers not occupationally exposed to styrene for review the background level in the unexposed population. The results obtained were as follows; 1. The mean exposure concentration is 16.6 $\pm $12.2 ppm (range 0.4-49.9ppm) in the styrene exposed workers. 2. The concentration of mandelic acid in urine collected at the end of shift from worker exposed 8 hours to 50ppm of styrene, based on extrapolation from correlation equations was 578.5 mg/g creatinine and 176.8 mg/g creatinine for next morning urine, the concentration of phenylglyoxylic acid in urine collected at the end of shift was 291.1 mg/g creatinine, 177.9 mg/g creatinine in next morning urine. In the sum of mandelic acid and phenylglyoxylic acid in the urine 870.2 mg/g creatinine in urine sampled at the end of shift corresponds to an exposure of 50ppm of styrene and 366.0 mg/g creatinine for next morning sample corresponds to 50ppm. 3. The correlation of the degree of exposed with sum concentration of mandeliacid and phenylglyoxylic acid in the urine was better(r=0.079 for end of shift, r=0.78 for next morning) than the correlation with single determinant measurement in urine(r=0.75 for mandelic acid at end of shift, r=0.73 for mandelic acid at next morning, r=0.69 for phenylglyoxylic acid at end of shift, r=0.62 for phenylglyoxylic acid at next morning). The monitoring of sum concentration of mandelic acid and phenylglyoxylic acid in urine is a valuable indicator of time weighted average daily exposure ti styrene. And the exposure standard of urinary metabolites produced by styrene should be set, in distinction urine at the end of shift from urine at next morning.
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