• Applied Chemistry for Engineering
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• v.28 no.6
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• pp.714-719
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• 2017

The contaminated engine oil by fuel can intimidate driver safety due to vehicle problems such as engine abrasion, fire and sudden unintended acceleration. In this study, we investigate various functional properties of the engine oil contaminated with fuel. The test results indicated that the engine oil contaminated with fuel had relatively low values of the flash point, pour point, density, kinematic viscosity and cold cranking simulator. Furthermore, a four ball test suggested that the contaminated engine oil increased wear scar due to the poor lubricity. Moreover, SIMDIST (simulated distillation) using ASTM D2887 was applied to analyze fuel characteristics in an engine oil. The SIMDIST analysis result showed a lower carbon number, and the fuel was detected at an earlier retention time than that of using engine oil in chromatogram. Also, it is possible to quantitatively analyze for fuel contents in the engine oil. The SIMDIST method for the diagnosis of oil conditions can be used whether the fuel was involved or not, instead of analyzing other physical properties that require various analytical instruments, large volumes of oil samples, and long analysis time.

• Tribology and Lubricants
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• v.32 no.3
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• pp.95-100
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• 2016

As an alternative fuel, biodiesel has excellent lubricating property. Previously, our research group reported that the properties of biodiesels depended on their composed molecular structure. In this study, we investigate lubricity and the mechanism of lubricity improvement of synthesized biodiesel molecules. We synthesize four types of biodiesel components from fatty acid via fisher esterification and soybean biodiesel from soybean oil via transesterification in high yield (92-96%). We analyze the lubricity of the five 5 types of biodiesel using HFRR (high frequency reciprocating rig). We estimate that the mechanism of lubricity is relevant to the molecular structure and structure conversion of biodiesel. The test results indicate that the longer the length of molecules and the higher the content of olefin, the better the lubricity of the biodiesel molecules. However, the wear scar size of the first test samples’ do not show a regular pattern with the wear scar size of the second test samples’. Moreover, we investigated the structure conversion of the biodiesels by using GC-MS for the recovered biodiesel samples from the HFRR test. However, we do not detect structure conversion. Thus, we conclude that the lubricity of biodiesel depends on how effectively solid adsorption and boundary lubrication occurs based on the size of the molecule and the content of olefin in the molecule. In addition, HFRR test condition in not sufficient for Diels-Alder cyclization of biodiesel components.

• Tribology and Lubricants
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• v.30 no.5
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• pp.256-264
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• 2014

Enhancing the value of fine chemicals based on biomass resources is an important objective for addressing environmental and other concerns such as demand for renewable or green products, as well as from the political perspective to reduce dependence on fossil feedstock associated with the use of petroleum-based products. Based on these considerations, we studied the synthesis of estolide using waste plant-based oil materials and their application as lubricants and pour point depressants. Five estolides were prepared by varying molar ratio of palmitic acid (PA) to oleic acid (OA) using a reaction time of 48 h. The estolides were characterized by size exclusion chromatography (SEC) and nuclear magnetic resonance (NMR). The isolated yields were in the range of 57-78 % and purity was 93-97%, showing iodine values of 18.2-37.8, total acid numbers (TANs) of 75.6-94.2 mg KOH/g and estolide numbers (ENs) of 1.2-1.8. Increasing the ratio of OA to PA in the synthesis decreased the kinematic viscosity and clouding point of the estolides. Four ball wear test of the estolides as a base oil demonstrated that the wear scar diameter (WSD) of the estolides was significantly lower (0.320-0.495 mm) than the WSD of general base oils such as 150N and Yubase (0.735 and 0.810 mm, respectively), indicating better wear resistance of the estolides. However, the lubricant property was found to be independent of the amount of OA in the estolides. These new materials are prospective candidates for application as a lubricant base oil.

• Tribology and Lubricants
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• v.36 no.3
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• pp.168-192
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• 2020

In recently designed diesel engines, the running conditions for piston-pin bearings have become severe because of the higher combustion pressure and increased temperature. Moreover, the metal removal from the bushing material has strongly reduced the ability of the antifriction material to accept asperity contacts. Therefore, it is necessary to find ways of reducing wear scar on the connecting-rod small-end bushing and piston-pin boss bearing related to the higher combustion pressure on the power cell of an engine. In this work, the position and level of material removal from the surfaces of the bushing and bearing under such severe operating conditions - for example, maximum power and torque conditions of a passenger car diesel engine - are estimated for several combinations of surface roughness. First, piston-pin rotating motion is investigated by calculating the friction coefficient at piston-pin bearings, the oil film thickness, and the frictional torques induced by hydrodynamic shear stress. Subsequently, the wear scarring on the surfaces of a connecting-rod small-end bushing and two piston-pin boss bearings related to piston-pin rotational motion is numerically calculated under the maximum power and torque operating conditions. This work is helpful to determine the reasonable surface roughness of the bushing and bearing for reducing wear volume occurring at the interface between a bearing and a shaft.

• Tribology and Lubricants
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• v.20 no.6
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• pp.306-313
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• 2004

Many of the current development in surface modification engineering are focused on multilayered coatings, which have the potential to improve the tribological properties. Four different multilayered coatings were deposited on AISI D2 steel in this study. The prepared samples are designed as $WC-Ti_{0.6}Al_{0.4}N,\;WC-Ti_{0.53}Al_{0.47}N,\;WC-Ti_{0.5}Al_{0.5}N\;and\;WC-Ti_{0.43}Al_{0.57}N$. The multilayered coatings were investigated with respect to coating surface and cross-sectional morphology, roughness, adhesion, hardness, porosity and tribological behaviors. Especially, wear tests of four multilayered coatings were performed by using a ball-on-disc configuration with a linear sliding speed of 0.017 m/sec and a normal load of 5.38 N load. The tests were carried out at room temperature in air by employing AISI 52100 steel ball $(H_R\;=\;66) $ having a diameter of 10 mm. The surface morphology, and topography of the wear scars of samples and balls have been determined by using scanning electron spectroscopy (SEM). Also, wear mechanism was determined by using SEM coupled with energy-dispersive spectroscopy (EDS). Results have showed an improved wear resistance of the $WC-Ti_{1-x}Al_xN$coatings with increasing of Al (aluminum) concentration.

• Tribology and Lubricants
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• v.30 no.6
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• pp.323-329
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• 2014

The friction-reducing properties of lubricants containing ionic liquids based on ammonium dithiocarbamate are studied. The ionic liquids are produced through the following two steps: the synthesis of sodium alkyl dithiocarbamates via the substitution reaction of dialkylamine and carbon disulfide and their subsequent conversion into ammonium dithiocarbamate-based ionic liquids through an ion-exchange reaction with a quaternary alkyl ammonium halide salt. The structures of the ionic liquids are characterized by NMR spectroscopy and Fourier transform infrared spectroscopy. The isolated yields of the ionic liquids, which are viscous and pale yellow, are approximately 92%. The Brookfield viscosities and pour points of the ionic liquids are determined. Further, their wear resistances are measured through the four-ball wear test and the Schwingung Reibung Ver-schleiss (oscillation, friction, wear) test. The wear scar diameter of the lubricants containing 1 wt of the quaternary alkyl ammonium dithiocarbamate-based ionic liquids (0.475-0.631 mm) is significantly lower than that of the base oil (0.825 mm), proving that the ammonium dithiocarbamate-based ionic liquids have good friction-reducing characteristics. However, these friction-reducing characteristics fade significantly after long-term storage, owing to the degradation of the ionic liquids.

• Journal of Advanced Navigation Technology
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• v.28 no.4
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• pp.532-537
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• 2024

In this study, wear characteristics and microstructure changes due to changes in alloy composition of Ni-Cr-Mo-V and Ni-Cr-Mo low-alloy steels used in brake discs for transportation system such as aircraft and high-speed trains. As a result of the hardness test, the hardness of C-Mo-V steel was the highest at 39.4±0.9HRc, and the hardness of Ni-Cr-Mo steel was the lowest at 32.4±0.6HRc. The friction coefficient tended to decrease as the vertical load increased. At a vertical load of 1 N, the friction coefficient of Ni-Cr-Mo steel was the highest at 0.842, and at a vertical load of 5 N, Mn-Cr-V steel was the highest at 0.696. Ni-Cr-Mo showed the largest wear scar width, depth, and wear amount, with a width of 711 ㎛, a depth of 8.24 ㎛, and a wear amount of 11 mg under a vertical load of 1 N, and a width of 1,017 ㎛, a depth of 19.17 ㎛, and a wear amount of 17 mg under a vertical load of 5 N. As a result of wear mechanism analysis, ploughing, delamination, and adhesion in all specimens, with plastic deformation being more prominently observed in Ni-Cr-Mo.

• Tribology and Lubricants
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• v.33 no.4
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• pp.153-167
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• 2017

The aim of this study is to find the change in trend in the eccentricities of two journal bearings supporting the crankshaft of a single cylinder engine and the degree of misalignment of the shaft. We analyze the change in oil film thickness considering the wear scar under mixed-elasto-hydrodynamic lubrication regime at potential wear regions. For this, we first calculate the central eccentricities of the two journal bearings by using the mobility method. Then we calculate the outer end eccentricity by using the geometry of the bearings. Further, the tilting angle and degree of misalignment of the shaft are calculated by using the eccentricities of the two bearings. We show that the eccentricity of bearing #1, on which higher load is applied, increases at the beginning of the start-up cycle and during the coast-down cycle. However, the eccentricity of bearing #2, on which lower load is applied, decreases at the beginning of the start-up cycle and increases during the coast-down cycle. From the results of the analysis of oil film thickness, we show that the mixed-elasto-hydrodynamic lubrication regime for a misaligned shaft is at the initial stages of the start-up cycle for both bearing #1 and #2 and at the final stage of the coast-down cycle for only bearing #1.

• Tribology and Lubricants
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• v.25 no.6
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• pp.432-437
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• 2009

The effect of oxidation in SAE 5W30 engine oils on friction and wear characteristics was investigated using reciprocating bench tester and shell 4-ball tester. Commercial engine oils were collected and oxidized using the KS M 2021 method modifying the oxidation time. Kinematic viscosity, total acid number(TAN), FT-IR spectrum and total base number(TBN) also measured to examine the chemical change of oils with oxidation. The results showed that TAN was slightly changed and Kinematic viscosity was suddenly increased during the oxidation stage. however, TBN results keep a constant slope after TBN linearly decreased with oxidation time. Spectroscopy results showed that spectrums were orderly increased at $1710cm^{-1}$ during the oxidation time. Friction test results showed that oxidation of oils formed unstable friction layers causing higher fluctuating friction. however, the wear resistance was independent of oxidized time due to the different friction characteristics by oxidation. We found several factors in relation to lubrication properties with oxidation time. This factors were Viscosity, TBN, change of FT-IR spectrum, friction coefficient using reciprocating bench tester and wear scar.

• Tribology and Lubricants
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• v.28 no.1
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• pp.33-37
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• 2012

Automotive wheel bearing grease helps to reduce stresses and prevent wear of wheel bearings. But it is easily contaminated by water and other contaminants. Previously, our research group reported the change of grease physical properties such as dropping point, work penetration and oxidation work stability, water washout characteristics, leakage tendency, oil separation, evaporation loss and rust protection by water contamination. In this paper, we analyzed the physical characteristics of grease such as lubricity, viscosity and total acid number to investigate the mechanism of thickener decomposition. In water contaminated grease, the total acid number and wear scar were increased, the viscosity was decreased due to the decomposition of lithium complex thickener.