• Bulletin of the Korean Chemical Society
• /
• v.30 no.8
• /
• pp.1771-1777
• /
• 2009

The homogeneous B$F_3$ containing chiral Co(III) salen complexes were anchored non-covalently on the surfaces of mesoporous SBA-16 silica containing aluminum species. The Brönsted and Lewis acidic sites are attributed to the immobilization of fluorine functionalized chiral salen complexes on the supports. The FT-IR, UV, ESCA, and NMR analyses were performed to determine the structure of synthesized chiral salen catalysts. These heterogeneous catalysts could be applied in asymmetric ring opening of terminal epoxides by water and phenol derivatives. They showed very high enantioselectivity and yield more than 98% in the catalytic synthesis of optically active products.

• YAKHAK HOEJI
• /
• v.44 no.4
• /
• pp.325-333
• /
• 2000

The 1,3-dipolar cycloaddition reaction of the quinoxaline 4-oxides 2 with 2-chloroacrylonitrile gave the 2,3-dihydro-1H-1,2-diazepino[3,4-b]quinoxalines 3, which were converted into the 2,3,4,6-tetrahydro-1H-1,2-diazepino[3,4-b]quinoxalines 5-7. The reaction of compounds 3 with selenium dioxide in acetic acid/water resulted in ring transformation to give the 1,4-dihydro-4-oxopyridazino[3,4-b]quinoxalines 8.

• Journal of Integrative Natural Science
• /
• v.11 no.1
• /
• pp.39-43
• /
• 2018

Poly(hydroxyethyl methacrylate)-based hydrogels were surface-functionalized with spiropyran (SP) derivatives to obtain photochromic contact lenses. The contact lens reversibly changes from colorless to purple as response to UV light since colorless ring-closed SP state converts to purple ring-opened merocyanine (MC) state under UV light irradiation. The purple contact lens emits red light at 640 nm. Importantly, the presence of SP segments did not significantly affect the equilibrium water content (EWC) of the lens. SP-functionalized hydrogel lenses may find potential applications in developing light-adaptive ophthalmic materials.

• Mycobiology
• /
• v.32 no.4
• /
• pp.197-198
• /
• 2004

A new technique for single spore isolation was developed for predacious fungi forming constricting rings directly on the spores using Dactylaria brochopaga and Arthrobotrys dactyloides. Constricting rings were induced directly on the spores by transferring the spores in 25 ppm solution of DL-Valine in sterile distilled water. Freshly hatched and thoroughly washed second stage juveniles of Meloidogyne incognita were transferred into cavity blocks containing induced rings for trapping and killing of nematodes. The killed nematodes were surface sterilized with streptomycin and inoculated into petri dishes containing maize meal agar media with 100 ppm streptomycin. The petri dishes were incubated at $29{\pm}1^{\circ}C$ for few days which yielded axenic culture of these fungi.

• Archives of Pharmacal Research
• /
• v.12 no.1
• /
• pp.52-57
• /
• 1989

The structure of cinmetacin was determined by single crystal X-ray diffraction analysis. The compound was recrystallized from a mixture of acetone and water in orthorhombic, space group $P2_12_12_1$, with Z=4, a=35.681(8), b=9.482(2), c:5.071(1) ${\AA}$, $D_x=1.352 g/cm^3$, and $D_m=1.35g/cm^3$. The structure was solved by direct method and refined by least-squares procedure to the final R value of 0.036 for 1441 observed reflections ($F{\geq}3{\sigma}(F)$). The carboxyl group of the molecule is nearly perpendicular to the indole ring. The dihedral angle between indole ring and phenyl group is $64.5^{\circ}$. The molecules are linked together via O(1)-H ----O(3) hydrogen bonds, and arranged along 2-fold screw axis in the crystal. The intermolecular contacts are the normal van der Waals' forces.

• The Korean Journal of Malacology
• /
• v.21 no.1
• /
• pp.57-64
• /
• 2005

Samples of Corbicula japonica Prime of Jujin estuary in Gochang were collected from July 2000 to September 2001. Age of C. japonica was determined from the rings on the shell. The relationship between shell length and ring radius in each ring group was expressed as a regression line. Therefore, there is a correspondence in each ring formation. Based on the monthly variation of the marginal index (MI') of the shell, it is assumed that the ring of this species was formed once a year during the period of February and March. The relationship between shell length (SL; mm) and total weight (TW; g) was expressed by the following equation: TW = 1.0942 ${\times}10^{-4}SL^{3.3217}$ ($r^2$ = 0.9905). Shell length (SL) and shell height (SH; mm) was highly correlated with shell height as the following equation: SH = 0.9174 SL - 0.9935 ($r^2$ = 0.9885). The shell length (SL) - shell width (SW) relation was also expressed by the following equation; SW = 0.5925 SL - 1.1706 ($r^2$ = 0.9726). Growth curves for shell length and total weight fitted to the von Bertalanffy's growth curve were expressed as: $$SL_t = 46.4861[1-e^{-0.3383(t+0.0958)}]$$, $$TW_t = 34.54[1-e^{-0.3383(t+0.0958)}]^3.3217$$.

• Steel and Composite Structures
• /
• v.3 no.5
• /
• pp.321-331
• /
• 2003

The paper presents the results of an experimental investigation conducted on welded tubular joints, that are employed in offshore platforms, to study the behaviour and strength of these joints under axial brace compression loading. The geometrical configuration of the joints tested were T and Y. The nominal diameter of the chord and brace members of the joint were 324 and 219 mm respectively. The chord thickness was 12 mm and the brace 8 mm. The tested joints are approximately quarter size when compared to the largest joints in the platforms built in a shallow water depth of 80 m in the Bombay High field. Some of the joints were actually fabricated by a leading offshore agency which firm is directly involved in the fabrication of prototype structures. Strength of the internally ring-stiffened joints was found to be almost twice that of the unstiffened joints of the same configuration and dimensions. Bending of the chord as a whole was observed to be the predominant mode of deformation of the internally ring-stiffened joints in contrast to ovaling and punching shear of the unstiffened joints. It was observed in this investigation that unstiffened joint was stiffer in ovaling mode than in bending and that midspan deflection of unstiffened joint was insignificant when compared to that of the internally ring stiffened joint. The measured midspan deflection of the unstiffened joint in this investigation and its relation with the applied axial load compares very well with that predicted for the brace axial displacement by energy method published in the literature. A comparison of the measured deflection and ovaling of the unstiffened joint was made with that published by the author elsewhere in which numerical prediction of both quantities have been made using ANSYS software package. The agreement was found to be quite good.

• Journal of Ginseng Research
• /
• v.30 no.3
• /
• pp.153-157
• /
• 2006

This study was carried out to identify the age of red ginseng using the stem vestige counting methods and annual ring staining method. The samples were soaked, humidified, and restored before identifying the age. Root tissue was removed from rhizome after soaking treatment in $50^{\circ}C$ water for three days. It was found to be useful for precise identification of age. Safranine staining for counting the annual ring in sliced ginseng was not useful due to the poor staining. However, annual ring was clearly revealed whenr humidified sliced ginseng or soaked sliced ginseng were dried mechanically. These two method was useful to identify the age of red ginseng.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.35 no.10
• /
• pp.1083-1088
• /
• 2011

The effects of an impeller and floating ring seals on the performance of centrifugal pumps are investigated on the basis of their test results using water. The pumps are single-staged centrifugal pumps developed for 30-ton- and 75-ton-class liquid rocket engines, and are components of a turbopump that supplies propellants (liquid oxidizer and kerosene) to the combustion chamber. The exit width of the impellers and the numbers and exit angles of the impeller blades are found to have influences on the pump heads. In addition, the pumps have different efficiencies according to the gaps between the floating ring seals and the impellers, whereas the pump size seems to have less effect on the efficiency.

• Journal of the Architectural Institute of Korea Structure & Construction
• /
• v.35 no.12
• /
• pp.165-172
• /
• 2019

The aim of the research is to evaluate the influence of various replacing ratios of supplementary cementitious materials(SCMs) such as fly ash(FA), blast furnace slag(BS), and both FA and BS on general properties including segregation resistance as a powder based high fluidity concrete of normal strength grade with water-to-cement ratio 0.40. Specifically, by replacing the SCMs with low density powders, it was assessed that the decreased segregation resistance due to the decreased viscosity by J-ring test. As a result of the experiment, from the general test, the mixtures with SCMs showed increased segregation resistance by increased viscosity as the references, while some segregation was shown from J-ring test due to the decreased density of fresh state mixture related with the capacity of delivering coarse aggregate.