In this paper, strength and leaching characteristics of water sludge-added lightweight soils(WALS) considering reinforcing materials(waste fishing net, glue treated waste fishing net and geogrid) and layer(1 or 2 layer) were investigated using unconfined compression test and leaching test. Several specimens of water sludge-added lightweight soil consisted of water sludge, cement, and bottom ash were prepared according to flowability. Reinforcing material added into these specimens were waste fishing net and geogrid. A glue treated waste fishing net was also added in order to increase interlocking between soil mixture and waste fishing net. Strength increased in the order of WALS reinforced by waste fishing net, glue treated waste fishing net, and geogrid. Strength of specimen with double layer-reinforcing material was greater than that of specimen with single layer reinforcing material. Leaching result of WALS was also satisfied with standard of ministry of environment.
Electro-thermal production of white phosphorus(WP, P4) generates substantial amount of highly toxic phossy water and sludges. Because of their high phosphorus contents and lack of reliable processing technology, large tonnages of these hazardous wastes have accumulated from current and past operations in the United States. In this study, two different methods for treatment of phosphorus sludge were investigated. These were bulk removal of WP by physical separation(froth flotation) and transformation of WP to oxyphosphorus compounds by air oxidation in the sludge medium. Kerosene, among other collectors, resulted in selective flotation of WP from the associated mineral gangue. Solvent action of kerosene occurring on the WP surface(by rendering WP particles hydrophobic) might produce the high selectivity of WP. The WP recovery in the froth was 79.3% from a sludge assaying 34.2% of WP. In the oxidation study, air gas was dispersed in the sludge medium by the rapid rotation of the impeller blades. The high level of sludge agitation intensity caused a fast completion of the oxidation reactions and it resulted in the high percentage conversion of WP to PO4-3 with PO3-3 making up almost all portion of oxyphosphorus compounds. The WP analysis on the treated sludge showed that supernatant solution and solid residue contained an average of 4.2 μg/L and 143 ppm respectively from the sludge containing about 26 g of WP. Further investigation will be required on operational factors to better understand the processes and achieve an optimum condition.
For a high-rate fermentation and recovery of organic acid, we have developed a new organic acid fermentation reactor with membrane filter, which is the most important part in the new advanced wastewater treatment system. The recovered organic acid is to be reused as an organic carbon source at denitrification process. Some experiments were conducted to compare the performance of acid fermentation at different SRTs, such as 5, 10, and 20 days. The total organic acid concentration produced during the runs was in the range of 2,100-2,900 (mgC/L). The conversion efficiency from substrate to organic acid reached to from 43% to 59%. The recovery rate of organic acid from substrate based on TOC was from 26% to 53%. Regardless of operational conditions, it has been able to maintain the membrane flux constantly, in the range of 0.4-0.46 ($m^3/m^2/day$). The transmembrane pressure drop was 0.2-0.3 (kg/cm) for 100 day's operation. The result of simulation is as follows. Organic removal efficiency of the new advanced treatment system is 95%. 73% of Nitrogen is removed. The removal efficiency of Phosphorus is 93%. By coqulation, soluble phosphorus is able to remove from the water treatment lines, which is impossible at conventional activated sludge system. The unit construction cost is 65000 (yen/m3) and it was 1.4 times than that of the standard activated sludge system. The unit operation cast is 7.7 ($yen/m^3/day$) and it was 1.3 times than that of the standard activated sludge system.
To reduce extensive energy costs of the internal recycling for the purpose of denitrification in the advanced wastewater treatment, a post-treatment process using an electro-coagulation to treat nitrate in the secondary effluents is evaluated in this study. Removals of phosphorus and organics in the secondary effluents by the electro-coagulation were also evaluated to propose an alternative advanced wastewatert treatment process. A series of experiments of the electro-coagulation were carried out with the following 4 different samples: synthetic solution containing nitrate only, synthetic solution containing nitrate as well as phosphorus, secondary effluents from activated sludge cultivated in laboratory, and secondary effluents from real wastewater treatment plants. Removals of nitrate and phosphorus in the synthetic solution were 30 and 97 % respectively, which verified the feasibility of the process. Removals of nitrate, phosphorus and COD in the secondary effluents from the cultivated sludge in laboratory were 49, 90 and 19 % respectively. Removal efficiency of the total nitrogen, nitrrate, phosphorus and COD in the secondary effluent from real wastewater treatment plant were 50, 61, 98 and 80 % respectively. The removal of the total nitrogen was less than the nitrate as expected, which is due to the formation of ammonia nitrogen in the cathode. But the proposed scheme could be an energy saving and alternative process for the advanced wastewater treatment if further studies for the process optimization are carried out.
The treatment performance and operational parameters of a tertiary wastewater treatment process a biological filtration system were investigated. The biological filtration system consisted of a nitrification filter (Fiter 1) and a polishing filter with anoxic and aerobic parts (Filter 2). SS, T-C-BOD, and T-N in effluent were kept stable at less than 3, 5 mg/L, and 5 mgN/L, respectively, under a HRT in Filter (filter-bed) of 0.37~2.3 h. T-N at the outlet of Filter 2 were about 1~5 mgN/L under the condition of LV of 50~202 m/d. In Filter 2, denitrification was accomplished under LV of 50~168 m/d in a 1 m filter-bed. However, the denitrification capacity reached the maximum when the linear velocity was increased to 202 m/d. Relationship between increase in microorganism and headloss was clearer in Filter 2. As a result, the denitrification rate increased from 1.0~2.3 kgN/($m^3-filter-bed{\cdot}d$) as the headloss increased. The COD removal rate was 6.0~9.6 kgCOD/($m^3-filter-bed{\cdot}d$) when operated with Filters 1 and 2. These results mean that captured bacteria contributed a part of COD consumption and denitrification. The maximum nitrification and denitrification rate was 0.5 and 4 kgN/($m^3-filter-bed{\cdot}d$) in Filter 1 and 2.The ratio of backwashing water to the treated water was about 5~10 %. In Filter 1, wasted sludge in backwashing was only 0.7~5.3 gSS/($m^3$-treated water). In Filter 2, added methanol was converted into sludge and its value was 8.0~24 gSS/($m^3$-treated water). These results proved that this process is both convenient to install as tertiary treatment and cost effective to build and operate.
Journal of the Korea Organic Resources Recycling Association
/
v.6
no.2
/
pp.45-57
/
1998
The object of this experiment was to determine the optimum mixing ratio of paper mill sludge and sewage sludge with woodchips as a bulking agent. The bulking agent was mixed with the mixture of paper mill sludge and sewage sludge(2:1 by dried weight) at the rates of 0(W-0), 20(W-20), 33(W-33), and 50(W-50)% on volume basis, and then the mixtures were composted by forced aerated static pile. The changes of physicochemical properties of the mixtures were measured during the composting in order to evaluate the maturity of composts. The temperatures of W-30 and W-50 treatments increased rapidly as soon as the composting started, and reached $60^{\circ}C$ in the fifth day of composting. Reduction of hot water soluble C/N ratio of W-33 and W-50 treatments showed faster than that of W-0 and W-20 treatments at early stage of the composting. The contents of hot water soluble $NO_3{^-}-N$ showed little change in the early stage of the composting in all treatments, but increased rapidly after 20 days of the composting, and the contents of W-0 among all treatments were lower than the others. The G.I. values of W-50 treatment were over 80 before 20 days after starting the composting, those of W-0 treatment were over 80 after 30 days. As a result of evaluation of compost, W-33 and W-50 treatments were found very reasonable at the mixing ratio of a bulking agent. But it is very difficult to aerate compost pile for W-50 treatment than W-33 treatment due to intensified fluctuation of temperature. Considering cost, availability of a bulking agent, and productivity of compost, W-33 treatments more efficient than W-50 treatment.
Journal of the Korean Applied Science and Technology
/
v.31
no.4
/
pp.669-678
/
2014
The amount of waste water generated from the domestic sources is consistently increasing in proportion to economic growth, and the conventional activated sludge process is widely being used for general waste water treatment. But the ministry of environment becomes stringthent treatment standards of N and P (less than 20mg/L of N, 2mg/L of P) to prevent the eutrophication of lake water, and therefore highly advanced treatment technology is required not only in the existing treatment plants where the activated sludge process is being used, but also in newly constructed treatment plants for the treatment of N and P. This study is aimed at highly operating the engineering technology method was developed by domestic to eliminate N and P at the same time. Experiments were conducted in the treatment plant located in Yong In city. The bioreactor was started from the principal equipment for the elimination of N and P and the elimination of organic compounds. It consists of an internal recycle piping from the end of the aerobic tank to the anoxic tank and external recycle piping from the final settling basin to the denitrification tank. By experiment of 4 types separate inflow of waste water to the denitrification tank and the anaerobic tank, and changes in staying time at the anoxic tank and the aerobic tank, the elimination of organic compounds in each type and the relationship in the efficiency between the elimination of N and P were researched.
Generally, ready-mixed concrete(RMC) gets hardened by time, so the remaining concrete in the drum should be cleaned. But if the RMC waste water generated from this is discharged to soil without any treatment, the strong alkaline elements and heavy metals affect water and ecosystem pollution. Although about 10 to 15% of water used for cleaning in the RMC factory is discharged to soil or river, the concrete report of this affecting soil pollution has not been sufficient. Hence, in this study it was analyzed the extraction of cleaning water from RMC factories all over the country and heavy metal and pH components remaining in soil when this is penetrated to various soils having water permeability. The specimens used for the experiment are weathering soil and soils having different particle size, and it is made to be penetrated to those for 24 hours while fixed thickness of the layer is maintained. Cleaning water is divided into that before deposition treatment(sludge water) and that after deposition treatment(upper water) to be penetrated into soil, and according to the result of penetrating sludge water to soil, Cu and Mn, Fe, and Zn were found to be remained over 23 to 90%. However, it is analyzed that in upper water having deposition treatment, Cu and Mn remain as 60% or more only in weathering soil.
Phosphorus (P) is a limited, essential, and irreplaceable nutrient for the biological activity of all the living organisms. Sewage sludge ash (SSA) is one of the most important secondary P resources due to its high P content. The SSA has been intensively investigated to recover P by wet chemicals (acid or alkali). Even though $H_2SO_4$ was mainly used to extract P because of its low cost and accessibility, the formation of $CaSO_4$ (gypsum) hinders its use. Heavy metals in the SSA also cause a significant problem in P recovery since fertilizer needs to meet government standards for human health. Therefore, P recovery process with selective heavy metal removal needs to be developed. In this paper some of the most advanced P recovery processes have been introduced and discussed their technical characteristics. The results showed that further research is needed to identify the chemical mechanisms of P transformation in the recovery process and to increase P recovery efficiency and the yields.
Journal of Korean Society of Environmental Engineers
/
v.33
no.2
/
pp.113-119
/
2011
The study purpose was to examine an effect of zero emission of excess sludge on biological reactor and treated water quality within the biological reactor in the process of biological treatment combined with excess sludge reduction system with ozone. Under an ozone injection rate 0.03 g $O_3/g$ SS, Sludge Disintegration Number (SDN) 3 and less than pH 4 as pre-treatment process, it was possible to maintain a stable biological treatment process without sludge disintegration. In the test of $OUR_{max}$, of sludge, its value was hardly under the condition of ozone injection rate 0.03 g $O_3/g$ SS. There were almost no changes of MLVSS/MLSS within biological reactor followed by a solubilization of excess sludge. Accumulation of microorganism within biological reactor was also not observed. After solubilization of excess sludge, an increase for organic matter and SS concentrations of an effluent was not observed and T-N concentration was reduced by increasing nitrification and denitrification rate within biological reactor. Most of T-P was not removed by zero emission of excess sludge and was leaked by being included in effluents.
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