• Title/Summary/Keyword: Water vapor permeability

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Water vapor barrier properties of polymer-like amorphous carbon deposited polyethylene naphthalate film

  • Kim, Jeong-Yong;Park, Gyu-Dae;Song, Ye-Seul;Lee, Hui-Jin;Vu, Minh Canh;Kim, Seong-Ryong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.303.1-303.1
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    • 2016
  • Polymer-like amorphous carbon films were deposited on polyethylene naphthalate (PEN) substrate by plasma-enhanced chemical vapor deposition (PECVD) and their water vapor transmission rates (WVTR) were tested. propane was used as precursors. To make a polymer-like amorphous carbon film the deposition rate, surface roughness, light transmittance, and WVTR of the films were characterized as a function of the precursor feed ratio and plasma power. The water vapor transmission rates of bare PEN film and single layer PAC on PEN substrate were 6.95 g/m2/day and 0.3 g/m2/day, respectively. The superior property the water vapor permeability of thin layers of PAC was attributed to uniform coverage and good adhesion between PAC film and PEN substrate.

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Study on Performance of Water Vapor-Permeation Through Hydrophilic Polymer Membranes (친수성 고분자 막을 이용한 수증기 투과 성능에 관한 연구)

  • Rhim Ji-Won;Yun Tae-Il;Seo Moo-Young;Cho Hyun-Il;Ha Seong-Yong
    • Membrane Journal
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    • v.16 no.2
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    • pp.115-122
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    • 2006
  • In this study the membrane preparation and water vapor permeation of the hydrophilic polymer materials, polyaminosiloxane and polyhydroxylsiloxane, used as the coating materials for the preparation of asymmetric flat and hollow fiber membranes were investigated. And the water vapor permeation towards air permeation and their permselectivity were intensively studied for the resulting Resin A/Resin C (coupling agent) and Resin B/Resin C membranes. The water vapor permeability for 3 wt% Resin C introduced into Resin A (Resin A/Resin C) membrane was higher than for 1 and 5 wt% membranes and also water vapor permeability increased with increasing operating temperatures. In addition, at this content of 3 wt% Resin C, the absorption capability became maximum through dynamic equilibrium absorption experiment. Water vapor permeability, 43578 Barrer (1 Barrer = $10^{-10}cm^3(STP){\cdot}cm/cm^2{\cdot}s{\cdot}cmHg$) and 53000 Barrer, and the selectivity of $P(H_2O)P(Air)$, 101.3 and 102.6 were shown at 25 and $35^{\circ}C$, respectively.

Property Evaluation of Breathable Blend Fabric of MPCE Copolymer and Wet Coagulated Polyurethane (MPCE copolymer와 습식 폴리우레탄의 블렌드에 의한 투습방수 나일론 직물의 제반 물성변화에 관한 연구)

  • Yi, Jong-Woo;Chae, Ei-Jung;Bae, Jin-Seok
    • Textile Coloration and Finishing
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    • v.26 no.4
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    • pp.322-330
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    • 2014
  • The phospholipid-based MPCE(2-Methacryloxyethyl Phosphoryl Chlorine) copolymer was mixed with wet polyurethane for coating of nylon fabrics. The substitution rate of water in coagulation bath with DMF was changed under control of the size of formed hydrophilic microporous cell enable to manufacture excellent breathable, anti-bacterial and moisture control fabrics. Biocompatible property, vapor permeability, hydrostatic pressure, moisture management and anti-bacterial property were investigated for treated nylon fabrics. In result, increased moisture transmission rates, decreased water resistance and outstanding moisture control property could be confirmed by enhanced hydrophilicity of wet-coated nylon fabric with MPCE copolymer.

Water and oxygen permeation through transparent ethylene vinyl alcohol/(graphene oxide) membranes

  • Kim, Hye Min;Lee, Heon Sang
    • Carbon letters
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    • v.15 no.1
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    • pp.50-56
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    • 2014
  • We prepared ethylene vinyl alcohol (EVOH)/graphene oxide (GO) membranes by solution casting method. X-ray diffraction analysis showed that GOs were fully exfoliated in the EVOH/GO membrane. The glass transition temperatures of EVOH were increased by adding GOs into EVOH. The melting temperatures of EVOH/GO composites were decreased by adding GOs into EVOH, indicating that GOs may inhibit the crystallization of EVOH during non-isothermal crystallization. However, the equilibrium melting temperatures of EVOH were not changed by adding GOs into EVOH. The oxygen permeability of the EVOH/GO (0.3 wt%) film was reduced to 63% of that of pure EVOH film, with 84% light transmittance at 550 nm. The EVOH/GO membranes exhibited 100 times better (water vapor)/(oxygen) selectivity performance than pure EVOH membrane.

Development of Retort Packaging Material Using Cellulose Nano Fiber (셀룰로오스 나노 파이버를 적용한 레토르트 포장재 개발)

  • Lee, Jinhee;Choi, Jeongrak;Koo, Kang
    • Textile Coloration and Finishing
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    • v.33 no.1
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    • pp.40-47
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    • 2021
  • As modern society develops, it becomes very complex and diverse, and interests in the convenience of life and the natural environment are gradually increasing. Products used in our daily life are also changing according to the needs of consumers, and food packaging is one of them. In particular, retort packaging materials have been used for the purpose of long-term preservation of contents, but the appearance of products suitable for recent environmental issues has been somewhat delayed. Therefore, in order to develop eco-friendly and human-friendly products by replacing the metals used in the existing retort packaging materials, the possibility of substitution was examined using cellulose nanofibers, a natural material. As a result, it can be seen that all functions can be replaced according to the existing long-term storage characteristics for retort packaging films. In particular, not only oxygen permeability and water vapor permeability, which are one of the most important factors, but also heat resistance, which is heating durability, is evaluated as applicable to commercialization compared to products using metals currently in use.

Moisture and Heat Transfer Characteristics of Waterproof and Water Vapor Permeable Coated Fabrics (기능성 투습방수 코팅포의 수분 및 열전달 특성)

  • Cho, Ji-Hyun;Ryu, Duck-Hwan
    • Korean Journal of Human Ecology
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    • v.8 no.1
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    • pp.151-163
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    • 1999
  • The purpose of this study was to investigate the thermal resistance and the liquid/vapor water transfer characteristics of four waterproof and water vapor permeable coated fabrics with the ground fabric called nylon taffeta. In order to establish the experimental environment, outdoor temperature and humidity in Taegu during the last three years were examined and the experiment was performed at (1) $15^{\circ}C$, 50% R.H., (2) $20^{\circ}C$, 60% R.H., (3) $25^{\circ}C$, 65% R.H., which were the average standards in spring and fall. The test results were as follows ; 1. Among physical parameters, the thinner the thickness was, the higher the water vapor permeability was. But the porosity in thickness was not proportional to water vapor permeability linearly. 2. The thicker the thickness of specimens was and the smaller the bulk density and porosity were, the higher the thermal resistance. And the results also shown that the larger the temperature difference between the environmental temperature and the hot plate was, the more the difference of CLO values was apparent. 3. Since the contact angle of all specimens are above $90^{\circ}$, the all specimens have a good performance in waterproof. The more the specimens surface were rough, the higher the thermal resistance was. 4. According to the result of performing moisture transfer test using the simulating body skin-clothing-environment system, the humidity sensor placed in between the fabric and the environment detected the full saturation in 10 minutes after the experiment had began at $15^{\circ}C$, 50% R.H. and in 15 minutes after the experiment both at $20^{\circ}C$, 60% R.H. and at $25^{\circ}C$, 65% R.H. 5. ${\Delta}$ values of the humidity sensors placed in between the human body and the fabric and in between the fabric and the environment fluctuated repeatedly within the range of $20{\sim}40%$ at $20^{\circ}C$, 60% R.H., and $15{\sim}30%$ at $25^{\circ}C$, 65% R.H.

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Permeability of (SiO2)1-x(ZnO)x Inorganic Composite Thin Films Deposited as a Passivation Layer of Ca Cell (Ca Cell의 보호막으로 증착된 (SiO2)1-x(ZnO)x 무기 혼합 박막들의 투습 특성)

  • Kim, Hwa-Min;Ryu, Sung-Won;Sohn, Sun-Young
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.3
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    • pp.262-268
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    • 2009
  • We investigated the properties of inorganic diatomic films like silicon oxide ($SiO_2$) and zinc oxide (ZnO) and their composite films are packed as a passivation layer around Ca cells on glass substrates by using an electron-beam evaporation technique and rf-magnetron sputtering method. When these Ca cells are exposed to an ambient atmosphere, the water vapor penetrating through the passivation layers is adsorbed in the Ca cells, resulting in a gradual progress of transparency in the Ca cells, which can be represented by changes of the optical transmittance in the visible range. Compared with the saturation times for the Ca cells to become completely transparent in the atmosphere, the protection effects against permeation of water vapor are estimated for various passivation films. The thin composite films consist of$SiO_2$ and ZnO are found to show a superior protection effect from water vapor permeation compared with diatomic inorganic films like $SiO_2$ and ZnO. Also, this inorganic thin composite films are also found that their protection effect against permeation of water vapor can be significantly enhanced by choosing their suitable composition ratio and deposition method, in addition, the main factors affecting the permeation of water vapor through the oxide films are found to be the polarizability and the packing density.

The Effect of Geometrical Structure on the Moisture Transport Properties of Nonwoven Batting Materials (부직포 충전재의 구조적 특성이 수분전달 특성에 미치는 영향-단층구조와 이층구조 부직포의 비교-)

  • 김희숙;나미희
    • Journal of the Korean Society of Clothing and Textiles
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    • v.24 no.6
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    • pp.810-818
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    • 2000
  • The purpose of this study was to analyze the effect of geometrical structure on the moisture transport properties of nonwoven batting materials. Two types of nonwovens were used such as single and double layered nonwovens. Steady and dynamic state water vapor transport properties were measured by absorption, evaporation and cobaltous chloride method respectively. The results of this study were as follows: 1) Geometrical structure affected water vapor evaporation, but there were no differences between single and double layered nonwovens in moisture absorption. Thickness and air permeability were influencing factor on water vapor transport rate. 2) Directionality of double layered nonwoven was observed both in steady and dynamic state moisture transport. There were differences between upper and lower layer of double layered nonwoven both in moisture absorption rate and color change by cobaltous chloride method. 3) In dynamic state of water vapor transport rate, single layered nonwoven reached more rapidly at the established relative humidity. It was confirmed that geometrical structure affected water vapor evaporation and hydrophilicity of fiber affected moisture absorption because there were much more water vapor transport rate by evaporation than absorption within the same period of time.

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A study on Physical Properties of Synthetic Leather added Collagen protein (Part I) (Collagen단백질을 첨가한 합성피혁의 물성에 관한 연구(제1보))

  • 백천의
    • Journal of the Korean Society of Clothing and Textiles
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    • v.21 no.6
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    • pp.970-976
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    • 1997
  • Synthetic leather added collagen protein was coagulated in DMF solution. With increasing collagen concentration, thickness of synthetic leather increased. In addition, water vapor permeability and water vapor absoption increased with increasing collagen protein concentration. But MIU and SMD value of surface properties decreased with increasing collagen protein concentration. As a result, synthetic leather added collagen protein showed comfort and dry touch.

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