• Current Optics and Photonics
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• v.1 no.4
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• pp.278-283
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• 2017

We theoretically study the dynamics of water tetramer in intense femtosecond laser pulses with different frequencies. The simulations are carried out by incorporating the molecular dynamics method non-adiabatically into the time-dependent local-density approximation (TDLDA-MD). Three typical scenarios of water tetramer including the normal vibration with enlarged OH bonds, free OH bonds breaking and the pure Coulomb explosion are presented by investigating the electronic and ionic dynamics. The result indicates that the ionization is enhanced and the corresponding fragmentation effect as well as the damping of the dipole moment are found more notably when increasing the laser frequency especially when the frequency falls in the resonant region of the absorption spectra. The study of the level depletion reveals that the ratio of the emission amount from different levels can be controlled by changing the laser frequency referring to the Keldysh parameter.

• Journal of Hydrogen and New Energy
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• v.2 no.1
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• pp.7-13
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• 1990

We are interested in studying the artificial photolysis of water which mimics the natural plant photosynthesis. In the artificial system there should be a proper photosensitizer, electron donor and electron acceptor. Since Mn-tetramer is known to be the essential part for the oxygten-evolving system in the natural photosynthesis, it is important to know or study the reactivity of Mn-porphyrins. As a model for the Mn-tetramer in the natural photosynthesis, we prepared the lipophilic and hydrophilic Mn-porphyrins. For the lipophilic porphyrin with long hydrocarbon chain, the long hydrocarbon chain was inserted in the porphyrin ring formation step. For the hydrophilic porphyrin, the porphyrin was sulfonated with sulfuric acid. These syntheses of lipophilic and hydrophilic Mn-porphyrins are significant, since the behaviors of these compounds will be different in the microemulsions or vesicles. We also found that the Mn-porphyrins were photoreduced in the microemulsion and water in the presence of amines.