• Mass Spectrometry Letters
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• v.11 no.4
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• pp.90-94
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• 2020

Interest in aspects of industrialization relating to human health has increased. Accordingly, the use of labels such as 'natural foods' and 'organic ingredients' has become more widespread, and greater emphasis is being placed on improving quality of life. Water is an essential element for human life, and water quality has a significant impact on human health. However, technology that can precisely determine the substances present in water is still lacking. This study was conducted to establish a complete mass spectrometry process, from pretreatment to analysis, to measure and characterize natural organic matter (NOM) in Korean spring water samples. Salts and other matrices were removed from the samples using solid-phase extraction (SPE) with two different columns (PPL and C18). After establishing an accurate analysis method, the experimental results were evaluated based on Van Krevelen diagrams and analysis of molar O/C and H/C ratios. The method for characterizing NOM introduced herein should facilitate evaluation of water quality.

• Journal of Ocean Engineering and Technology
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• v.27 no.1
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• pp.80-84
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• 2013

This study is to develop the simplified formulae for added mass coefficient of a 2-D floating body with a semi-circle section in a finite water depth. The semi-circle floating body may represent a simplified midship section transformed by Lewis form, which can be used for the ship motion analysis by strip theory. Since the added mass coefficient varies with motion frequencies and sea bottom effect, the correction factor representing the effect of water depth and frequencies is developed for accurate prediction of added mass. Using a two-dimensional numerical wave tank (NWT) technique based on the boundary element method (BEM) including sea bottom boundary the reference values of added mass are calculated to develop the correction factor. For verification and effectiveness of the formulae, the predicted added mass coefficients for various frequencies and water depth ratios are compared with the calculated values from NWT technique.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.10 no.4
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• pp.456-465
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• 1998

Effect of a non-absorbable gas on the absorption process in a vertical tube absorber was investigated numerically. The water vapor mined with air as the non-absorbable gas is absorbed into LiBr/water solution film. The flow is assumed to be laminar and fully developed in both liquid and gas phases. The diffusion and energy equations were solved in both phases to give the temperature and concentrations, from which heat and mass fluxes were determined. It was shown that the local absorption rate decreases as the mass fraction of air in water vapor increases. The vapor pressure of water at the liquid-vapor interface reduces significantly since the non-absorbable gas is accumulated near the interface. The effect of non-absorbable gases on absorption rate becomes larger as the mass flow rate of the vapor decreases. For small amount of non-absorbable gases the total absorption rate of water vapor increases as the mass flow rate of the vapor decreases. Total absorption rate increases as the mass flow rate of the vapor increases for large concentration of non-absorbables at the inlet of an absorber.

• International Journal of Air-Conditioning and Refrigeration
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• v.7
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• pp.69-78
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• 1999

Effects of a non-absorbable gas on the absorption process in a vertical tube absorber has been investigated numerically. The water vapor mixed with air is absorbed into LiBr/water solution film. The flow is assumed to be laminar and fully developed in both liquid and gas phases. The diffusion and energy equations were solved in both phases to give the temperature and concentrations, from which heat and mass fluxes were determined. The local absorption rate has been shown to decrease as the mass fraction of air in the water vapor increases. The vapor pressure of water at the liquid-vapor is interface reduced significantly since the non-absorbable gas accumulates near the interface. The effects of non-absorbable gases on absorption rate become larger as the mass flow rate of the vapor decreases. For a small amount of non-absorbable gases, the total absorption rate of water vapor increases as the mass flow rate of the vapor decreases. The total absorption rate increases as the mass flow rate of the vapor increases for large concentrations of non-absorbable gases at the inlet of an absorber.

• Korean Journal of Environmental Biology
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• v.30 no.4
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• pp.328-338
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• 2012

We investigated seasonal changes in the marine environments and phytoplankton communities in the western part of south coastal waters of Korea during May 2009 and February 2010. In multidimensional scaling analysis of in situ data obtained by shipboard observations, the coastal waters comprised four different water masses: Yellow Sea water mass (YW) of low temperature and salinity, and high suspended solids and nutrient concentrations; south-western coastal water mass (SW) of high salinity and nutrient concentrations; Tsushima Current water mass (TW) of low nutrient concentrations, and high temperature and salinity; and closed bay water mass (CW). The spatial extent of these water masses varied according to seasonal environmental characteristics. In particular, at most study sites, TW expanded during autumn toward coastal waters. Phytoplankton abundances peaked during autumn in CW and spring in YW, which coincided with periods of high nutrient concentrations. In particular, diatoms predominated, and attained an abundance of more than 90% in most water masses. However, dinoflagellates in TW comprised a proportion of approximately 20% abundance.

• Ocean and Polar Research
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• v.34 no.2
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• pp.219-228
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• 2012

Tintinnid species distribution has been monitored in the northern East China Sea (ECS) in the summer of 2006 through 2011. This is used to understand the water mass movements in the northern ECS. The warm oceanic tintinnid species had largely spread in 2007 in the area, indicating that there was greater warm water extension into the northern ECS. However the extension of neritic water within the Changjiang diluted water mass has strengthened in 2008 and 2010 because the neritic species distribution had relatively grown in both years. These annual results based on the biological indicators of tintinnid species are well matched with the salinity change in the area. The warm oceanic species, Dadayiella ganymedes had frequently occurred over the study years and had shown a significant relationship with the salinity change. This is valuable as a key stone species for monitoring the intrusion of the Kuroshio within the northern ECS. Information from tintinnid biological indicators can support physical oceanography data to confirm ambiguous water mass properties.

• Mass Spectrometry Letters
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• v.5 no.1
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• pp.12-15
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• 2014

Thermal ionization mass spectrometry (TIMS) was used to determine the concentration and isotope ratio of uranium contained in samples of soil and groundwater collected from Korea. Quantification of uranium in ground water samples was performed by isotope dilution mass spectrometry. A series of chemical treatment processes, including chemical separation using extraction chromatography, was applied to the soil samples to extract the uranium. No treatments other than filtration were applied to the groundwater samples. Isotopic analyses by TIMS showed that the isotope ratios of uranium in both the soil and water samples were indistinguishable from those of naturally abundant uranium. The concentration of uranium in the groundwater samples was within the U.S. acceptable standards for drinking water. These results demonstrate the utility of TIMS for monitoring uranium in environmental samples with high analytical reliability.

• The Korean Journal of Malacology
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• v.29 no.3
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• pp.245-250
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• 2013

We investigated the factors of mass-mortality in terms of water temperature and prey, in order to prevent the mass-mortality of cultured oysters at Gamak Bay in Yeosu City in 2007. The real-time water temperature was recorded as high, 28 to 31C, during late August. Nutrients, Dissolved Inorganic Nitrogen (DIN) and Dissolved Inorganic Phosphate (DIP) were downed in September. The analyzed results of chlorophyll a content were 0.78-1.50 ${\mu}gL^{-1}$ and phytoplankton for food resources was 81 cells $mL^{-1}$, both were low. The finding here indicate that Gamak Bay is in an oligotrophic state. The mass-mortality of cultured oysters occurred 43.6% in Gamak Bay. The mortality rate of oyster were above 67.0%, at Wanpo, however, it was showed 18.3% at Gumchun. Therefore, we believe the mass-mortality of cultured oysters at Gamak Bay comes from the destruction of bio-rhythms due to high water temperature and quantitatively and qualitatively decreasing food resources due to the limitation of nutrients.

• Nuclear Engineering and Technology
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• v.55 no.2
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• pp.780-791
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• 2023

To study oscillation characteristic of steam and non-condensable gas direct contact condensation through multi-hole sparger at low mass flux, a series of experiments of pure steam and mixture gas condensation have been carried out under the conditions of steam mass flux of 20-120kg/m²s, water temperature of 20-95 ℃ and mass fraction of non-condensable gas of 0-5%. The regime map of pure steam condensation through multi-hole sparger is divided into steam chugging, separated bubble, aggregated bubble and escaping aggregated bubble. The bubbles behavior of synchronization in the same hole columns and desynchronized excitation between different hole columns can be found. The coalescence effect of mixture bubbles increases with water temperature and non-condensable gas content increasing. Pressure oscillation intensity of pure steam condensation first increases and then decreases with water temperature increasing, and increases with steam mass flux increasing. Pressure oscillation intensity of mixture gas condensation decreases with water temperature and non-condensable gas content increasing, which is significantly weaker than that of pure steam condensation. The oscillation dominant frequency decreases with the rise of water temperature and non-condensable gas content. The correlations for oscillation intensity and dominant frequency respectively are developed in pure steam and mixture gas condensation at low mass flux.

• Mass Spectrometry Letters
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• v.14 no.4
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• pp.147-152
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• 2023

The increasing demand for two-dimensional imaging analysis using optical or electronic microscopic techniques has led to an increase in the use of simple one-dimensional and two-dimensional mass spectrometry imaging. Among these imaging methods, secondary-ion mass spectrometry (SIMS) has the best spatial resolution using a primary ion beam with a relatively insignificant beam diameter. Until recently, SIMS, which uses high-energy primary ion beams, has not been used to analyze molecules. However, owing to the development of cluster ion beams, it has been actively used to analyze various organic molecules from the surface. Researchers and commercial SIMS companies are developing cluster ion beams to analyze biological samples, including amino acids, peptides, and proteins. In this study, a water droplet ion beam for surface analysis was realized. Water droplets ions were generated via electrospraying in a vacuum without desolvation. The generated ions were accelerated at an energy of 10 keV and collided with the target sample, and secondary ion mass spectra were obtained for the generated ions using ToF-SIMS. Thus, the proposed water droplet ion-beam device showed potential applicability as a primary ion beam in SIMS.