• Mass Spectrometry Letters
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• 제11권4호
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• pp.90-94
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• 2020

Interest in aspects of industrialization relating to human health has increased. Accordingly, the use of labels such as 'natural foods' and 'organic ingredients' has become more widespread, and greater emphasis is being placed on improving quality of life. Water is an essential element for human life, and water quality has a significant impact on human health. However, technology that can precisely determine the substances present in water is still lacking. This study was conducted to establish a complete mass spectrometry process, from pretreatment to analysis, to measure and characterize natural organic matter (NOM) in Korean spring water samples. Salts and other matrices were removed from the samples using solid-phase extraction (SPE) with two different columns (PPL and C18). After establishing an accurate analysis method, the experimental results were evaluated based on Van Krevelen diagrams and analysis of molar O/C and H/C ratios. The method for characterizing NOM introduced herein should facilitate evaluation of water quality.

• 한국해양공학회지
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• 제27권1호
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• pp.80-84
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• 2013

This study is to develop the simplified formulae for added mass coefficient of a 2-D floating body with a semi-circle section in a finite water depth. The semi-circle floating body may represent a simplified midship section transformed by Lewis form, which can be used for the ship motion analysis by strip theory. Since the added mass coefficient varies with motion frequencies and sea bottom effect, the correction factor representing the effect of water depth and frequencies is developed for accurate prediction of added mass. Using a two-dimensional numerical wave tank (NWT) technique based on the boundary element method (BEM) including sea bottom boundary the reference values of added mass are calculated to develop the correction factor. For verification and effectiveness of the formulae, the predicted added mass coefficients for various frequencies and water depth ratios are compared with the calculated values from NWT technique.

• 설비공학논문집
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• 제10권4호
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• pp.456-465
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• 1998

Effect of a non-absorbable gas on the absorption process in a vertical tube absorber was investigated numerically. The water vapor mined with air as the non-absorbable gas is absorbed into LiBr/water solution film. The flow is assumed to be laminar and fully developed in both liquid and gas phases. The diffusion and energy equations were solved in both phases to give the temperature and concentrations, from which heat and mass fluxes were determined. It was shown that the local absorption rate decreases as the mass fraction of air in water vapor increases. The vapor pressure of water at the liquid-vapor interface reduces significantly since the non-absorbable gas is accumulated near the interface. The effect of non-absorbable gases on absorption rate becomes larger as the mass flow rate of the vapor decreases. For small amount of non-absorbable gases the total absorption rate of water vapor increases as the mass flow rate of the vapor decreases. Total absorption rate increases as the mass flow rate of the vapor increases for large concentration of non-absorbables at the inlet of an absorber.

• International Journal of Air-Conditioning and Refrigeration
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• 제7권
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• pp.69-78
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• 1999

Effects of a non-absorbable gas on the absorption process in a vertical tube absorber has been investigated numerically. The water vapor mixed with air is absorbed into LiBr/water solution film. The flow is assumed to be laminar and fully developed in both liquid and gas phases. The diffusion and energy equations were solved in both phases to give the temperature and concentrations, from which heat and mass fluxes were determined. The local absorption rate has been shown to decrease as the mass fraction of air in the water vapor increases. The vapor pressure of water at the liquid-vapor is interface reduced significantly since the non-absorbable gas accumulates near the interface. The effects of non-absorbable gases on absorption rate become larger as the mass flow rate of the vapor decreases. For a small amount of non-absorbable gases, the total absorption rate of water vapor increases as the mass flow rate of the vapor decreases. The total absorption rate increases as the mass flow rate of the vapor increases for large concentrations of non-absorbable gases at the inlet of an absorber.

• 환경생물
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• 제30권4호
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• pp.328-338
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• 2012

남해 서부 연안역의 식물플랑크톤 군집 및 환경요인의 계절별 변화를 관찰하고자 2009년 4월부터 2010년 2월까지 계절별 조사를 수행하였다. 환경요인의 변화는 multidimensional scaling (MDS)에 따라 수괴의 변화를 분석하였을 때, 남해 연안역 수괴 (SW; South-western coastal Water mass) 및 남쪽에서 유입되는 고염의 외양 수괴(TW; Tsushima current Water mass), 서쪽 제주해협을 통해 유입되는 저염의 서해 연안수괴 (YW; Yellow sea Water mass), 그리고 해안의 하천으로부터 계절적으로 유입되는 담수(CW; Closed bay Water mass)가 영향을 미치고 있었다. 이들 수괴는 해양 환경의 시 (계절) 공간적 특성에 따라 발달과 확장 및 축소되고 있었다. 즉, 연안에서 외해역 또는 외해역에서 연안 방향(남-북 방향) 그리고 서쪽(진도 주변 해역)에서 동쪽 방향 (동서 방향)의 농도 경사를 보인다. 이러한 남-북 방향의 공간 변동은 연안에서 하천과 지하수로 유입되는 연안 담수(낮은 염분과 높은 영양염 농도)와 대마 해류(고염분과 저영양염) 사이의 혼합에 의한 것이며, 동-서방향의 공간 변동은 제주해협을 통해 남해 연안으로 유입되는 서해의 연안수(저염분과 고영양염)와 대마 해류 사이의 혼합에 의해 조절되고 있는 것으로 해석된다. 식물플랑크톤은 고영양염을 보인 서해 연안수 및 여자만, 득량만에서 높은 개체수를 보였다. 식물플랑크톤 군집별 특성은 규조류가 90% 이상 높은 비율을 차지하였으나 대마 해류 수괴에서 와편모조류가 상대적으로 높아 수괴 특성에 따른 분류군의 차이를 보여 수괴가 갖는 기원적 특성 (original characteristics)의 차이를 보였다.

• Ocean and Polar Research
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• 제34권2호
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• pp.219-228
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• 2012

Tintinnid species distribution has been monitored in the northern East China Sea (ECS) in the summer of 2006 through 2011. This is used to understand the water mass movements in the northern ECS. The warm oceanic tintinnid species had largely spread in 2007 in the area, indicating that there was greater warm water extension into the northern ECS. However the extension of neritic water within the Changjiang diluted water mass has strengthened in 2008 and 2010 because the neritic species distribution had relatively grown in both years. These annual results based on the biological indicators of tintinnid species are well matched with the salinity change in the area. The warm oceanic species, Dadayiella ganymedes had frequently occurred over the study years and had shown a significant relationship with the salinity change. This is valuable as a key stone species for monitoring the intrusion of the Kuroshio within the northern ECS. Information from tintinnid biological indicators can support physical oceanography data to confirm ambiguous water mass properties.

• Mass Spectrometry Letters
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• 제5권1호
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• pp.12-15
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• 2014

Thermal ionization mass spectrometry (TIMS) was used to determine the concentration and isotope ratio of uranium contained in samples of soil and groundwater collected from Korea. Quantification of uranium in ground water samples was performed by isotope dilution mass spectrometry. A series of chemical treatment processes, including chemical separation using extraction chromatography, was applied to the soil samples to extract the uranium. No treatments other than filtration were applied to the groundwater samples. Isotopic analyses by TIMS showed that the isotope ratios of uranium in both the soil and water samples were indistinguishable from those of naturally abundant uranium. The concentration of uranium in the groundwater samples was within the U.S. acceptable standards for drinking water. These results demonstrate the utility of TIMS for monitoring uranium in environmental samples with high analytical reliability.

• 한국패류학회지
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• 제29권3호
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• pp.245-250
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• 2013

We investigated the factors of mass-mortality in terms of water temperature and prey, in order to prevent the mass-mortality of cultured oysters at Gamak Bay in Yeosu City in 2007. The real-time water temperature was recorded as high, 28 to 31C, during late August. Nutrients, Dissolved Inorganic Nitrogen (DIN) and Dissolved Inorganic Phosphate (DIP) were downed in September. The analyzed results of chlorophyll a content were 0.78-1.50 ${\mu}gL^{-1}$ and phytoplankton for food resources was 81 cells $mL^{-1}$, both were low. The finding here indicate that Gamak Bay is in an oligotrophic state. The mass-mortality of cultured oysters occurred 43.6% in Gamak Bay. The mortality rate of oyster were above 67.0%, at Wanpo, however, it was showed 18.3% at Gumchun. Therefore, we believe the mass-mortality of cultured oysters at Gamak Bay comes from the destruction of bio-rhythms due to high water temperature and quantitatively and qualitatively decreasing food resources due to the limitation of nutrients.

• Nuclear Engineering and Technology
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• 제55권2호
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• pp.780-791
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• 2023

To study oscillation characteristic of steam and non-condensable gas direct contact condensation through multi-hole sparger at low mass flux, a series of experiments of pure steam and mixture gas condensation have been carried out under the conditions of steam mass flux of 20-120kg/m²s, water temperature of 20-95 ℃ and mass fraction of non-condensable gas of 0-5%. The regime map of pure steam condensation through multi-hole sparger is divided into steam chugging, separated bubble, aggregated bubble and escaping aggregated bubble. The bubbles behavior of synchronization in the same hole columns and desynchronized excitation between different hole columns can be found. The coalescence effect of mixture bubbles increases with water temperature and non-condensable gas content increasing. Pressure oscillation intensity of pure steam condensation first increases and then decreases with water temperature increasing, and increases with steam mass flux increasing. Pressure oscillation intensity of mixture gas condensation decreases with water temperature and non-condensable gas content increasing, which is significantly weaker than that of pure steam condensation. The oscillation dominant frequency decreases with the rise of water temperature and non-condensable gas content. The correlations for oscillation intensity and dominant frequency respectively are developed in pure steam and mixture gas condensation at low mass flux.

• Mass Spectrometry Letters
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• 제14권4호
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• pp.147-152
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• 2023

The increasing demand for two-dimensional imaging analysis using optical or electronic microscopic techniques has led to an increase in the use of simple one-dimensional and two-dimensional mass spectrometry imaging. Among these imaging methods, secondary-ion mass spectrometry (SIMS) has the best spatial resolution using a primary ion beam with a relatively insignificant beam diameter. Until recently, SIMS, which uses high-energy primary ion beams, has not been used to analyze molecules. However, owing to the development of cluster ion beams, it has been actively used to analyze various organic molecules from the surface. Researchers and commercial SIMS companies are developing cluster ion beams to analyze biological samples, including amino acids, peptides, and proteins. In this study, a water droplet ion beam for surface analysis was realized. Water droplets ions were generated via electrospraying in a vacuum without desolvation. The generated ions were accelerated at an energy of 10 keV and collided with the target sample, and secondary ion mass spectra were obtained for the generated ions using ToF-SIMS. Thus, the proposed water droplet ion-beam device showed potential applicability as a primary ion beam in SIMS.