• Title/Summary/Keyword: Water leaching

Search Result 570, Processing Time 0.024 seconds

Dimensional Stability, Color Change, and Durability of Boron-MMA Treated Red Jabon (Antochephalus macrophyllus) Wood

  • PRIADI, Trisna;ORFIAN, Gema;CAHYONO, Tekat Dwi;ISWANTO, Apri Heri
    • Journal of the Korean Wood Science and Technology
    • /
    • v.48 no.3
    • /
    • pp.315-325
    • /
    • 2020
  • Boron compound had many advantages as wood preservative, but it was prone to leaching. Improving boron preservation was required to extend the service life of fast growing and low durability red jabon (Antochephalus macrophyllus) hardwood. This study aimed to evaluate the dimensional stability, color change and durability of modified red jabon wood by double impregnation with boron and methyl methacrylate (MMA) and heat treatment. Impregnation I used boric acid or borax, and impregnation II used MMA, while heat treatment used temperatures of 90 ℃ or 180 ℃ for 4 hours. The dimensional stability, leachability, water absorption, color change and decay resistance of modified red jabon wood were tested. The results showed that MMA impregnation increased the dimensional stability of red jabon wood, while the leaching and water absorption in the wood significantly reduced. Heating at 180 ℃ caused less water absorption and higher dimensional stability of the wood than that of heating at 90 ℃. Impregnation with boric acid and MMA followed by heating at 90 ℃ resulted in the highest wood ASE, 89.9%. The color change (∆E*) of wood increased significantly after MMA impregnation and heating at 180 ℃. Boric acid impregnation caused more resistant wood than borax impregnation against decay fungi and termites. Impregnation with boric acid and MMA followed with heating at 180 ℃ increased significantly the wood resistance against decay fungi and termites.

Recovery of $ZrO_2$ by Leaching from $LiF-BeF_2-ZrO_2$ Molten Salt in Distilled Water ($LiF-BeF_2-ZrO_2$ 용융염에서 증류수 침출에 의한 $ZrO_2$의 회수 - 증류수에서 $LiF-BeF_2-ZrF_4+ZrO_2$ 용융염의 용해현상 -)

  • Woo, Mun-Sik;Yoo, Jae-Hyung;Park, Hyun-Soo;Kang, Young-Ho;Kwon, Soo-Han
    • Analytical Science and Technology
    • /
    • v.13 no.6
    • /
    • pp.712-721
    • /
    • 2000
  • $LiF-BeF_2-ZrF_4$(63-30-7 mol%) molten salt was dissolved up to 0.02g in 1ml of distilled water at room temperature. $ZrO_2$ oxide made from $ZrF_4$ through pyrohydrolysis was recovered by leaching in distilled water with $LiF-BeF_2-ZrF_4$molten salt including it at room temperature. The crystalline sharpness of recovered $ZrO_2$ oxide was not damaged.

  • PDF

Leaching Characteristics of Foundry Sands When Used as Reactive Media in Permeable Reactive Barriers (반응벽체에 쓰인 주물사의 용출특성에 관한 연구)

  • ;Benson, Craig H
    • Journal of the Korean Geotechnical Society
    • /
    • v.18 no.5
    • /
    • pp.179-193
    • /
    • 2002
  • Waste foundry sands were tested to determine their leaching characteristics when used as reactive media in permeable reactive barriers (PRBs). Water leach tests and column leach tests were performed on twelve foundry sands and three reference materials such as Peerless iron, a local fill material, and torpedo sand. The latter three materials were tested to compare concentrations of heavy metals and anions found in other materials commonly placed below the groundwater table with those from the foundry sands. Results of water leach tests md total elemental analyses showed that all of the laundry sands are Category 2 materials per Section NR 538 of the Wisconsin Administrator Code. However, tests on Peerless iron, torpedo sand, and a typical fill material indicate that these materials, which are commonly placed below the groundwater table, also are Category 2 materials. Thus, using foundry sand as a PR3 medium should pose no greater risk than that imposed using conventional construction materials.

Manufacturing Characteristics of Environmental-friendly Waste Ash Brick with Industrial By-Products (산업부산물을 이용한 친환경 연소재벽돌의 제조특성)

  • Kim, Han-Seok;Jung, Byung-Gil;Kim, Dae-Yong;Kang, Dong-Hyo;Jang, Seong-Ho
    • Journal of Environmental Health Sciences
    • /
    • v.35 no.3
    • /
    • pp.226-234
    • /
    • 2009
  • The main objective of this study was to evaluate the effects on shape and size, compressive strength, water absorption and heavy metals leaching with various weight mixing ratios in waste ash brick products using waste recycling MSWI(Municipal Solid Waste Incinerator) bottom ash, steel slag and waste building material. The manufacturing processes for the waste ash brick consist of screening, mixing, conveyor transmission, compaction.forming, and curing steps of raw materials. The weight mixing ratios of steel slag around bottom ash were adjusted within the ranges of 10% to 30%. The reported results show that the width and thickness of the manufactured waste ash brick could be satisfied with $90{\pm}2mm\;and\;57{\pm}2mm$, respectively which are K.S. standards of products qualities. And in case of length, only 20-Ba50Ss30, 20-Ba60Wb20 and 20-Ba50Wb30 for the mixing ratios could be satisfied with $190{\pm}2mm$ that is K.S. standards of products quality. The compressive strength and water absorption for 20-Ba50Ss30 and 20-Ba70Wb10 were over $8N/mm^2$ and below 15% respectively that are K.S. standards of manufactured waste ash brick. The results of tests for the heavy metals leaching in the all manufactured waste ash bricks are also passed to the wastes management regulations. The cost analysis of 20-Ba50Ss30 is evaluated. The manufacturing cost is evaluated 34.3 won/brick with 8 hours and 20tons of raw material per day. Incinerators with problems in bottom ash disposal can therefore derive significant benefits from the application of waste ash brick production.

Analysis of Organic Matter and Nutrient Leaching Characteristics of Agricultural Land Soils in Reservoir Area (저수구역 경작지 토양의 유기물 및 영양염류 용출특성 분석)

  • Yu, Nayeong;Shin, Minhwan;Lim, Jungha;Kum, Donghyuk;Nam, Changdong;Lim, Kyoungjae;Kim, Jonggun
    • Journal of The Korean Society of Agricultural Engineers
    • /
    • v.63 no.1
    • /
    • pp.89-102
    • /
    • 2021
  • Soils in agricultural lands contain large amount of organic matter and nutrients due to the injected fertilizers and manure. During heavy rain, surface water and base runoff pollutants flows into a nearby stream or lake with eroded soil from agricultural lands. On the other hands, agricultural lands near the lake are inundated due to the increase of the water level in the lake, leading to organic matter and nutrient release from the inundated soil. In this study, releasing rates of nutrient salts and organic substances were analyzed for the soil in the agricultural land, where cultivation activities has been carried out and periodically flooded, to account for the possibility of contamination from the inundated agricultural land in reservoir areas The experiment results have shown that COD was released from the soil in anaerobic conditions, and T-P was released in both anaerobic and aerobic conditions. However, in the case of T-N, it was found that the runoff by soil was not made before the rainfall occurred, and when the soil was impound due to rainfall, the elution occurred under the aerobic conditions. Through the results of this study, it was possible to account for the effect of flooded agricultural lands on the water quality in the lake, and this could be reflected in an efficient agricultural non-point pollution management policy. In order to determine the precise releasing rate for each agricultural land, it is believed that the leaching experiment for paddy fields and grasslands are needed.

Lithium Recovery from NCM Lithium Ion Battery by Hydrogen Reduction Followed by Water Leaching (NCM계 리튬이온 배터리 양극재의 수소환원과 수침출에 의한 리튬 회수)

  • So-Yeong Lee;So-Yeon Lee;Dae-Hyeon Lee;Ho-Sang Sohn
    • Resources Recycling
    • /
    • v.33 no.1
    • /
    • pp.15-21
    • /
    • 2024
  • The demand for electric vehicles powered by lithium-ion batteries is continuously increasing. Recovery of valuable metals from waste lithium-ion batteries will be necessary in the future. This research investigated the effect of reaction temperature on the lithium recovery ratio from hydrogen reduction followed by water leaching from lithium-ion battery NCM-based cathode materials. As the reaction temperature increased, the weight loss ratio observed after initiation increased rapidly owing to hydrogen reduction of NiO and CoO; at the same time, the H2O amount generated increased. Above 602 ℃, the anode materials Ni and Co were reduced and existed in the metallic phases. As the hydrogen reduction temperature was increased, the Li recovery ratio also increased; at 704 ℃ and above, the Li recovery ratio reached a maximum of approximately 92%. Therefore, it is expected that Li can be selectively recovered by hydrogen reduction as a waste lithium-ion battery pretreatment, and the residue can be reprocessed to efficiently separate and recover valuable metals.

Sorption and Leaching Studies of Fenitrothion and Tebuconazole in Granular Activated Carbon and Charcoal (Fenitrothion과 Tebuconazole의 입상 활성탄 및 차콜에 의한 흡착과 용탈에 관한 연구)

  • Lee, Dong-Ik;Chun, So-Ul;Joo, Young-Kyoo
    • Asian Journal of Turfgrass Science
    • /
    • v.20 no.1
    • /
    • pp.47-55
    • /
    • 2006
  • Golf course community has always been concerned about water quality regarding to pesticide and fertilizer managements. This study conducted to investigate sorption and leaching behavior of common pesticides used for golf course in granular activated carbon I (GAC 1), granular activated carbon II(GAC II), and charcoal. We used batch study to investigate the influence of concentrations of Smithion and Folicur and particle sizes of GAC I, GAC II, and charcoal on sorption. Also, column study was used to investigate the leaching effect of Smithion in GAC I and charcoal. We found that sorption of Smithion and Folicur were higher in less $45{\mu}m$ of particle size for GAC I, GAC II, and charcoal compared to $1.7{\sim}2.0mm$ size, and the sorption of Smithion and Folicur in less $45{\mu}m$ of particle size ranged from 90 to 99%. In the column study, there was no difference in leaching effect between GAC I and charcoal. Overall, we found that charcoal might offer a cost effective adsorbent as a pesticides in leachate.

Leaching Behavior of LD Slag

  • Kim, Hyung-Suek;Han, Ki-Hyun;M. S. Oh;Byeon, Tae-Bong
    • Proceedings of the IEEK Conference
    • /
    • 2001.10a
    • /
    • pp.526-531
    • /
    • 2001
  • LD slag, that is, a by-product of steel making process, has been mainly used as land construction materials. Recently, the seashore application of LD slag was tried in Japan and Korea tut the reaction between LD slag and seawater was not studied yet. We tried to clarify the leaching reaction and/or mechanism of LD slag and the reaction between seawater and LD slag. We tried to apply these results to the decarbonization of seawater for seawater magnesia process. At first, LD slag was milled and classified into 5 grades, that is, (ⅰ)45${\mu}{\textrm}{m}$ under, (ⅱ)0.25~0.5mm (ⅲ)0.5~1mm(ⅳ)1~2mm, (ⅴ)2.36~3.35mm. These slags were leached in the distilled water. In case of 45${\mu}{\textrm}{m}$ under, the pH of the leached solution was over 12. The chemical analysis of leached solution showed that the $Ca^{+}$$^2$was main component and the S $i^{+}$$^4$was very low. On the other hand, the content of S $i^{+}$$^4$in leached solution was decreased with the increase of pH of this solution. The nearly pure calcium solution was made and the ultra high purity MgO could be made with this calcium solution. The leaching behavior of LD slag was different between the fine particle and coarse particle. The calcium was leached by bulk dissolution in the coarse particle and by surface controlled reaction in fine particle. The leaching rate was slow in coarse particle and fast in fine particle. Therefore, the high pH solution, that is, over 12, was obtained in fine particle.cle.e.

  • PDF

Experimental Evaluation on Occurrence Possibility of Pollutants from Aggregates (순환골재의 오염물질 발생 가능성에 관한 실험적 평가)

  • Park, Jeong-Ho;Seong, Jin-Uk;Park, Je-Chul
    • Journal of the Korean Recycled Construction Resources Institute
    • /
    • v.1 no.1
    • /
    • pp.1-7
    • /
    • 2013
  • This study was on leaching test(KSLT, TCLP) of the aggregate for the products(RA-1) and for the site(RA-2) to evaluate the characteristics of contaminants and the possibility of contamination arising from the aggregate. On the basis pH, conductivity and heavy metal contents in the aggregate, RA-1 indicated higher than RA-2. As a result of the leaching test, the pollutants were eluted from the aggregate increased as the particle size of the aggregate was smaller. The pH in the aggregate had a strong alkali by a pH value of 9.0~12.3, the conductivity was higher in less than 10mm RA-1 due to the leaching of dissolved inorganic ions. The heavy metals satisfied the leaching standards of KSLT and less 10% was eluted from the aggregate. As a result of evaluating water pollution possibility of the aggregate, the pH displayed in items with a very high possibility of contamination, conductivity and turbidity did in item with a low possibility of contamination and on the other hand the heavy metals did in item with a very low possibility of contamination.