• Title/Summary/Keyword: Water film

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Mechanical Properties of Cellulose/Chitosan and Sericin/Chitosan Blend Films (셀룰로오스/키토산 및 세리신/키토산 복합화필름의 역학특성)

  • Yoon Heung Soo;Lee Eui So;Kim Seung Il;Yoon Ho Gyu;Takahashi Kiyohisa
    • Textile Coloration and Finishing
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    • v.17 no.1
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    • pp.30-37
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    • 2005
  • The tensile properties, acetic acid solubility and degree of swelling in distilled water of cellulose/chitosan and sericin/chitosan film blended by mixing chitosan acetic acid solution with cellulose solution or sericin solution were investigated and the effect of crosslinking agent on solubility and degree of swelling were also considered. From the experimental results, the model of intermolecular bond is proposed. Tensile modulus of 100% cellulose film is high but the tensile strength and elongation are low. The elongation of 100% chitosan film is high but tensile modulus and strength is low. But it is possible to make film having same or higher tensile strength and modulus compared to that of 100% cellulose film by mixing cellulose and chitosan or by mixing sericin and chitosan. Chitosan is solved in 5vol % acetic acid solution but cellulose and sericin are not solved. Degree of swelling of chitosan in distilled water is higher than that of cellulose and sericin. Lower than 40wt% chitosan content, the solubility of cellulose/chitosan film in 5vol % acetic acid solution shows lower expected value but higher in case of sericin/chitosan film.

Experiments on Time Dependent Film Boiling on a Sphere

  • Ounpanich Bancha;Pomprapha Temsiri;Archakositt Urith;Nilsuwankosit Sunchai
    • Proceedings of the KSME Conference
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    • 2002.08a
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    • pp.403-406
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    • 2002
  • A number of the experiments on the phenomenon in which the thermal energy was transferred from a hot sphere to the surrounding water through the film boiling process had been conducted. As the sphere only carried the thermal energy associated with its initially high temperature but did not contain any other thermal source, the film boiling was only driven by the decreasing temperature of the sphere and, thus, was time dependent. The results from the experiments showed that the temperature of the sphere was slowly decreased in the beginning. This corresponded to the period in which the sphere was penetrating the water surface. Later, when the sphere was fully submerged and the transition film boiling was observed over the whole surface, the temperature of the sphere was decreased relatively much faster. In the last stage, the temperature of the sphere was again slowly decreased. This was considered caused by the relatively low temperature of the sphere, which reduced and later ceased the film boiling process. In addition, the estimation of the departure rate of the steam bubbles from the film layer was also correlated for the experiments.

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Electrochemistry and Determination of 1-Naphthylacetic Acid Using an Acetylene Black Film Modified Electrode

  • Huang, Wensheng;Qu, Wanyun;Zhu, Dazhai
    • Bulletin of the Korean Chemical Society
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    • v.29 no.7
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    • pp.1323-1325
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    • 2008
  • The acetylene black (AB) was dispersed into water in the presence of dihexadecyl hydrogen phosphate (DHP) via ultrasonication, resulting in a stable and well-distributed AB/DHP suspension. After evaporation of water, an AB/DHP composite film-modified electrode was prepared. The electrochemical responses of $K_3$[Fe$(CN)_6$] at the unmodified electrode, DHP film-modified electrode and AB/DHP film-modified electrode were investigated. It is found that the AB/DHP film-modified electrode possesses larger surface area and electron transfer rate constant. Furthermore, the electrochemical behaviors of 1-naphthylacetic acid (NAA) were examined. At the AB/DHP film-modified electrode, the oxidation peak current of NAA remarkably increases. Based on this, a sensitive and convenient electrochemical method was proposed for the determination of NAA. The linear range is in the range from $4.0 {\times} 10^{-8}\;to\;5.0 {\times} 10^{-6}$ mol $L^{-1}$, and the detection limit is $1.0 {\times} 10^{-8}$ mol $L^{-1}$. Finally, this new sensing method was employed to determine NAA in several soil samples.

Photolithography Process of Organic Thin Film with A New Water Soluble Photoresist

  • Kim, Kwang-Hyun;Song, Chung-Kun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1038-1039
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    • 2004
  • We developed a new photoresist which was composed of polyaniline, uv-curing agent, N-methyl-2- pyrrolidine (NMP) and N-Butyl alcohol (BuOH) as solution. The photoresist is characterized by the capability of being developed in water. We successfully patterned pentacene thin film, which was vulnerable to organic solvent and thus could not be patterned by the conventional photolithography process, with the water soluble photoresist and the minimum feature size was found to be 2um.

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A Study on the Nitrogen Control in the Treated Leachate water by Bio-film Module System (생물막을 이용한 침출수처리수 중의 질소제어에 관한 연구)

  • 최규철;이규성;정일현
    • Journal of environmental and Sanitary engineering
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    • v.11 no.1
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    • pp.71-76
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    • 1996
  • Bio-film module system was applied to the treated leachate water that priorly had been treated with biological nitrification process. The experiments were performed in the laboratory and treated leachate water treatment facility. Experimental results obtained from laboratory conditions and nitrogen removal efficiencies were averaged 90% for 1 hr.

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Desalting enhancement for blend polyethersulfone/polyacrylonitrile membranes using nano-zeolite A

  • Mansor, Eman S.;Jamil, Tarek S.;Abdallah, Heba;Youssef, H.F.;Shaban, Ahmed M.;Souaya, Eglal R.
    • Membrane and Water Treatment
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    • v.10 no.6
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    • pp.451-460
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    • 2019
  • Thin film composite membranes incorporated with nano-sized hydrophilic zeolite -A were successfully prepared via interfacial polymerization (IP) on porous blend PES/PAN support for water desalination. The thin film nanocomposite membranes were characterized by SEM, contact angle and performance test with 7000 ppm NaCl solution at 7bar. The results showed that the optimum zeolite loading amount was determined to be 0.1wt% with permeate flux 29LMH.NaCl rejection was improved from 69% to 92% compared to the pristine polyamide membrane where the modified PA surface was more selective than that of the pristine PA. In addition, there was no significant change in the permeate flux of the thin film nanocomposite membrane compared with that of the pristine PA in spite of the formation of the dense polyamide layer. The stability of the polyamide layer was investigated for 15 days and the optimized membrane presented the highest durability and stability.

Nanotribological Behavior of Adsorbed Water Layer on Silicon Surface (실리콘 표면에 흡착된 수분층의 나노트라이볼로지 거동)

  • 안효석;김두인;최동훈
    • Tribology and Lubricants
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    • v.19 no.5
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    • pp.245-250
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    • 2003
  • Water is known to playa crucial role on friction of moving parts in nanoscale contact. Little is, however, known about the tribological behavior of a solid surface that is covered with water adsorption layer. The objective of this study is to investigate the nanotribological behavior of the water layer in relation to water affinity of the surface and relative humidity. This paper presents an examination of the frictional behavior of water adsorption layer as 'confined liquid film'. It is shown that the friction is inversely proportional to the hydrophilicity of surface and relative humidity. On the other hand, friction of hydrophobic surface is not influenced by relative humidity. A model is proposed for the water-mediated contact in which it is shown that the water layer between two hydrophilic surfaces with high relative humidity behaves as a lubricant.

Effects of processing conditions on water vapor permeability and solubility of Alaska Pollack meal protein isolate film (가공조건이 명태어분단백질 필름의 수증기 투과도와 용해도에 미치는 영향)

  • YOU Byeong-Jin;SHIM Jae-Man
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.33 no.5
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    • pp.413-417
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    • 2000
  • The effects of film processing conditions on the water vapor permeability (WVP), the solubility of film's protein (SFP) and the soluble film's meterials amount (SFMA) were investigated to establish the conditions for preparing biodegradable and edible Alaska Pollack meal protein isolate (APMPI) film. ms of film were decreased with increasing plasticizer concentration but those were decreased with decrement of APMPI's pH values. SEPs were decreased with increasing APMPI's pH and plasticizer concentration. SFMAS were also strongly affected by plasticizer concentration and APMPI's pH. In the case of adding different plasticizers, WVP was increased in order as follows: glycerol, polyethylene glycol and sorbitol but SFMA showed inverse order.

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Effect of Irrigation Water Salinization on Salt Accumulation of Plastic Film House Soil around Sumjin River Estuary (섬진강 하구 관개용수 염화에 의한 시설재배단지 토양의 염류집적 심화)

  • Lee, Seul-Bi;Hong, Chang-Oh;Oh, Ju-Hwan;Gutierrez, Jessie;Kim, Pil-Joo
    • Korean Journal of Environmental Agriculture
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    • v.27 no.4
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    • pp.349-355
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    • 2008
  • The causes of salt accumulation in soils of plastic film houses nearby Sumjin river estuary in Mokdo-ri($127^{\circ}46'E\;35^{\circ}1'N$), Hadong, Gyeongnam, Korea were investigated in 2006. With chemical properties soils and water analyzed and fertilization status monitored, the study showed that mean salt concentration of soil was much higher at EC $4.3\;dS\;m^{-1}$ than the Korean average (EC $2.9\;dS\;m^{-1}$) in 2000s for plastic film house's soil with exchangeable Na $0.8\;cmol^+\;kg^{-1}$ and water-soluble Cl $232\;mg\;kg^{-1}$, and then might result to salt damage in sensitive crop plants. Salt concentration of ground water used as main irrigation water source contained very high EC with corresponding value of $2.6\;dS\;m^{-1}$. Particularly, increase of EC value was directly proportional with the increased pumping of ground water used as a water-covering system in order to protect the temperature inside plastic film houses from the early winter season. High Na and Cl portion of ions in water might had contributed to the specific ion damage in the crops. Secondly, heavy inputs of chemicals and composts significantly increased the accumulated salts in soil. Conclusively, salt accumulation might had been accelerated by use of salted-groundwater irrigation and heavy fertilization rate. To minimize this problem, ensuring good quality of irrigation water is essential as well as reducing fertilization level.

Approximate Solution of Absorption Process in an Air-Cooled Vertical Plate Absorber (공냉식 수직평판형 흡수기의 흡수과정에 대한 근사해법)

  • Jeong, E.S.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.6 no.4
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    • pp.453-462
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    • 1994
  • An unsteady quasi one-dimensional model of momentum, heat and mass transfer in a falling film of a vertical plate absorber which is cooled by air was developed using the integral method. Energy conservation of the absorber wall is considered in the model. The model can predict absorption rate, film thickness and mean velocity as well as concentration and temperature profiles. Predictions of steady state temperature and concentration profiles for LiBr/water system for constant wall temperature condition are in good agreement with the two-dimensional finite difference method solutions. Effects of operating conditions, such as convective heat transfer coefficient between the cooling air and the absorber wall, cooling air temperature and film thickness at inlet, on absorption rate of water vapor into LiBr/water solution were shown.

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