• Title/Summary/Keyword: Water diffusion coefficient

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Diffusion of Chloride Ions in Limestone Powder Concrete

  • Moon Han-Young;Jung Ho-Seop;Kim Jong-Pil
    • Journal of the Korea Concrete Institute
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    • v.16 no.6 s.84
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    • pp.859-865
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    • 2004
  • In this study, the diffusion of chloride ions in cement concrete made with and without the limestone powder was investigated. In order to study the effect of the limestone powder, all mixtures were prepared at a fixed water-cementitious ratio (0.45). From the experimental results, the setting time of limestone powder concrete is faster than that of control concrete, and compressive strength of all specimens decreased with increasing replacement ratio of limestone powders. The diffusion properties of limestone powder concretes indicated a trend increasing with curing period. LSA10 and LSA20 concretes, the diffusion coefficient was smaller than that of control concrete. The addition of $10-20\%$ limestone powder reduces the diffusion coefficient of chloride ions, irrespective of fineness levels of limestone powder.

Chloride Permeability of High Strength Concrete (고강도 콘크리트의 염화물 침투특성)

  • ;;;Kawano, Hirotaka
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.05a
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    • pp.985-990
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    • 2001
  • Chloride permeability of high strength concrete(HSC) was investigated using saltwater pending test and rapid chloride permeability test by electrical potential(ASTM C 1202). The lower water-cement ratio concrete showed the lower diffusion coefficient of chloride. The relationship between the diffusion coefficient of chloride and charge passed by the rapid chloride permeability test could be obtained. This relationship appears to be an effective method for evaluating chloride permeability of low water-cement HSC.

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Estimation of Probability Valuable for Diffusion Coefficient of Chloride Ion (염소이온 확산계수의 확률변수 평가)

  • Bae Su Ho;Lee Kwang Myong;Kim Jee Sang;Jung Sang Hwa
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.515-518
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    • 2005
  • In recent years, many research works have been carried out in order to obtain a more controlled durability and long-term performance of concrete structures exposed to chloride environments. In particular, the development of new procedures for probability-based durability analysis and design has been proved to be very valuable. To carry out the procedures described above, the statistical properties of design valuables such as diffusion coefficient of chloride ion, surface chloride concentration, and chloride threshold value etc. should be known. For this purpose, this paper presents the statistical properties of the diffusion coefficient of chloride ion such as mean value and standard deviation with water-cement(w/c) ratio and curing conditions, respectively. It was observed from the test that the standard deviation for the diffusion coefficient of chloride ion was found to be small with decrease in the w/c ratio irrespective of curing conditions and that of standard curing was found to be smaller than that of field curing.

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A study on the development of the high efficiency condensing heat exchanger (고효율 응축형 열교환기 개발에 관한 연구)

  • Lee, Geum-Bae;Park, Sang-Il;Park, Jun-Tae
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.5
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    • pp.589-601
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    • 1997
  • A computer simulation program of a high efficiency condensing heat exchanger is developed. The flue gas flows outside bare tube bundles both in strong cross flow and in weak counter flow and the cooling water inside the tubes. Condensing heat exchangers achieve high efficiency by reducing flue-gas temperatures to a level at which most of the water vapor in the flue gas is condensed and the latent heat associated with phase change of the water is recovered. The computer model has been verified by comparison with measured data. To verify the model, heat transfer coefficient was adjusted, along with the mass transfer diffusion coefficient and pressure drop coefficient, to achieve agreement between predicted and measured data. The efficiencies of heat exchanger increase 2.3 ~ 8.1% by condensations of 6.3 ~ 62.6% of the water vapor in the flue gas.

Influence of Water-Cement Ratios and Curing Conditions on the Diffusion Characteristics of Chloride Ion in Concrete (콘크리트의 염소이온 확산특성에 미치는 물-시멘트비 및 양생조건의 영향)

  • Bae, Su-Ho;Lee, Kwang-Myong;Kim, Jee-Sang;Jung, Sang-Hwa
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.4A
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    • pp.753-759
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    • 2006
  • To predict service life of concrete structures exposed to chloride attack, surface chloride concentration, diffusion coefficient of chloride ion, and chloride corrosion threshold value in concrete, are used as important factors. Of these, as the diffusion coefficient of chloride ion for concrete is strongly influenced by concrete quality and environmental conditions of structures and may significantly change the service life of structures, it is considered as the most important factor for service life prediction. The qualitative factors affecting the penetration and diffusion of chloride ion into concrete are water-cement (W/C) ratio, age, curing conditions, chloride ion concentration of given environment, wet and dry conditions, etc. In this paper the influence of W/C ratio and curing conditions on the diffusion characteristics of chloride ion in concrete was investigated through the chloride ion diffusion test. In the test, the voltages passing through the diffusion cell were measured by accelerated test method using potential difference, and then with the consideration of IR drop ratio the diffusion coefficient of chloride ion for concrete with different W/C ratios were estimated by Andrade's model. Furthermore, under different curing conditions formulas for the estimation of the diffusion coefficient of chloride ion have been proposed by the regression analysis considering the effect of W/C ratio and age.

Chloride Diffusion Coefficient at Reference Time for High Performance Concrete for Bridge Pylons in Marine Environment (해상교량 주탑용 고성능 콘크리트의 기준재령 염소이온 확산계수)

  • Yoon, Chul-Soo;Kim, Ki-Hyun;Yang, Woo-Yong;Cha, Soo-Won
    • Journal of the Korea Concrete Institute
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    • v.24 no.4
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    • pp.435-444
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    • 2012
  • High performance concrete mixes are selected and corresponding test specimens are made for the study of chloride diffusion coefficient at reference time. The concrete mixes were same designs as those used in construction of bridges located in a marine environment. Mix design variables included binder type, water-to-binder ratio, mineral admixtures to total binder weight substitution ratio, fine aggregate source, chemical water reducer admixture type for high strength and high flowability, and target slump or slump flow. The test results showed that the diffusion coefficients at reference time varied significantly according to the type of mineral admixtures and their substitution ratios. A model for diffusion coefficient at reference time considering the type of mineral admixture and the substitution ratio was developed. Diffusion coefficients from the developed model were compared with those from literature review, a previous model, and additional test results. All of the comparisons verified that the developed model can reasonably predict diffusion coefficients and the application of the model to the durability design against chloride penetration is appropriate.

Hypoxia Estimation of Coastal Bay through Estimation of Stratification Degree (성층강도 산정을 통한 내만의 Hypoxia 산정)

  • Jung, Woo-Sung;Lee, Won-Chan;Hong, Sok-Jin;Kim, Jin-Lee;Kim, Dong-Myung
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.20 no.5
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    • pp.511-525
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    • 2014
  • Goal of this study is estimating of validity of calculated vertical diffusion coefficient for Masan bay is semi-enclosed bay by using eco-hydrodynamic model that is used to analysis of physical structure of coastal waters and calculates the vertical diffusion coefficient. physical structure of coastal waters is calculated by EFDC model, vertical diffusion coefficient calculated as the density gradient is bigger, the vertical diffusion coefficient as density gradient is increases, the vertical diffusion coefficient is decreased. Validity of vertical diffusion coefficient estimated by reproducibility of concentration of dissolved oxygen that calculated in ecosystem model is constructed by Stella program. The Results of model in 2008~2009 were $R^2$ value of 2008 is 0.529~0.700 and $R^2$ value is 0.542~0.791. This results were similar to observed data and simulated to hypoxia at that time. The 'vertical diffusion coefficient' represents stratification and physical stable of a water body, and will be useful for prediction of Hypoxia outbreak.

Diffusion-weighted Imaging and Apparent Diffusion Coefficient Maps for the Evaluation of Pyogenic Ventriculitis

  • Kim, Hyeong-Seok;Hong, Jae-Taek;Lee, Sang-Won;Son, Byung-Chul;Sung, Jae-Hoon;Kim, Moon-Chan
    • Journal of Korean Neurosurgical Society
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    • v.38 no.1
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    • pp.23-27
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    • 2005
  • Objective : The aim of this study is to assess the significance of an apparent diffusion coefficient[ADC] study for diagnosis of ventriculitis. Methods : Seven patients with ventriculitis were enrolled in this study. Diffusion-weighted[DW] magnetic resonance images[MRI] and ADC maps in the dependent intraventricular collection, periventricular white matter and non-dependent cerebrospinal fluid[CSF] were obtained. The images and ADC data from the different lesions were compared. Results : The DW MRI showed marked hyperintensity in the purulent pus lesion, and the corresponding ADC maps revealed prominent hypointensity and restricted ADC values compared with the non-dependent CSF and normal white matter. Conclusion : The decreased ADC value and increased signal intensity of the dependent intraventricular fluid on the DW MRI show restricted water diffusion in the purulent fluid, which is indicative of a pyogenic ventriculitis diagnosis.