• Title/Summary/Keyword: Water content ratio

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Characteristics of Anti-reflective Coating Film Prepared from Hybrid Solution of TEOS/Base and MTMS/Acid (TEOS/염기 및 MTMS/산 혼성 용액으로 제조한 반사방지 코팅막의 특성)

  • Park, Hyun-Kyu;Kim, Hyo-Sub;Park, Chu-Sik;Kim, Young-Ho
    • Applied Chemistry for Engineering
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    • v.30 no.3
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    • pp.358-364
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    • 2019
  • To improve the optical characteristics and antifouling of anti-reflective coating (AR) films, various AR coating films were prepared by varying the mixing ratio of tetraethylorthosilicate (TEOS)/base and methyltrimethoxysilane (MTMS)/acid hybrid solution. Prepared AR coating films were characterized by UV-Vis spectroscopy, contact angle analyzer, atomic force microscope (AFM), FT-IR and pencil scratch hardness test. In an AR coating film that prepared from the hybrid solution with a 10 wt% MTMS/acid solution, the glass substrate showed an excellent optical property (97.2% transmittance), good antifouling ($121^{\circ}$ water contact angle and $90^{\circ}\;CH_2I_2$ contact angle) and moderate mechanical strength (pencil hardness of 4 H). In particular, it is considered that the good antifouling was due to the well dispersion of the methyl group ($-CH_3$), derived from a small amount of MTMS/acid solution in the hybrid solution, on the substrate surface. From results of the pencil hardness test, the mechanical strength of AR coating film was improved as the content of MTMS/acid solution increased.

Effect of fattening period on growth performance, carcass characteristics, and economic traits of Holstein steers

  • Kim, Sung Il;Park, Sungkwon;Myung, Jeong Hwan;Jo, Young Min;Choi, Chang Bon;Jung, Keun Ki
    • Journal of Animal Science and Technology
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    • v.63 no.5
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    • pp.1008-1017
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    • 2021
  • This study was conducted to investigate the effect of different fattening periods on the growth performance, carcass characteristics, and economic traits of Holstein steers. Sixty Holstein steers (8.0 ± 0.28 months old) with an average body weight (BW) of 231.88 ± 2.61 kg, were randomly allocated to five different fattening period treatments: 20, 21, 22, 23, and 24 months (n = 12 in each treatment group). Final BW and average daily gain (ADG) did not differ among the treatment groups during the early fattening period. At the late stage of the fattening period, the final BW of steers in the 24-month treatment group (812.84 kg) was greater (p < 0.05) than that of steers in the 20-month treatment group (750.39 kg). During the same period, steers in the 20- and 21-month treatment groups had a significantly higher (p < 0.05) ADG than those in the 22-month treatment group. The highest ADG (1.36 kg/day) was found in the 20-month treatment group (1.36), followed by the 21- (1.33 kg/day), 22- (1.22 kg/day), 23- (1.21 kg/day), and 24- (1.14 kg/day) month treatment groups. The feed conversion ratio (FCR) increased as the fattening period increased, and the FCR was 12.88% lower in the 20-month treatment group than in the 24-month treatment group. However, no significant differences were detected in back-fat thickness, loin area, marbling score, and chemical characteristics (water, crude protein, and crude fat content) among the treatment groups. The composition of fatty acids including C18:0, C18:1, saturated fatty acids, unsaturated fatty acids, and poly-unsaturated fatty acids did not differ among the experimental groups. As the fattening period increased, production costs increased, resulting in a decrease in gross income. The gross income for steers in the 24-month treatment group was 35.8% and 23.5% lower than that for steers in the 20- and 21-month treatment groups, respectively. Taken together, the best performance, including the ADG, FCR, and gross income, was obtained when the fattening program of the Holstein steers lasted 20 months.

Response of broilers to supplementation of branched-chain amino acids blends with different valine contents in the starter period under summer conditions

  • Kop-Bozbay, Canan;Akdag, Ahmet;Atan, Helin;Ocak, Nuh
    • Animal Bioscience
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    • v.34 no.2
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    • pp.295-305
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    • 2021
  • Objective: The objectives of this study were to compare the effects of normal and low protein content (PC) of starter diet supplemented or not with blends of branched-chain amino acids (BCAAs) on growth performance of broilers under summer conditions and to investigate whether these effects altered some quality traits and the characteristics of gastrointestinal tract. Methods: A total of 768 mixed-sex broiler chicks (Ross 308, one-d-old) with an average initial body weight (BW) of 47.6±1.03 g were allocated into six treatments with four replications in 2×3 factorial arrangement. Factors were: PC, normal (N, 22% to d 15); and low (L, 20% to d 15); and added BCAA blends, L-leucine, L-isoleucine, and L-valine at zero (0L:0I:0V); 1.0, 0.25, and 0.25 (4L:1I:1V); or 1.0, 0.25, 0.75 (4L:1I:3V) g/kg of diet. Hence, six dietary treatments were named as N0L:0I:0V, N4L:1I:1V, N4L:1I:3V, L0L:0I:0V, L4L:1I:1V, and L4L:1I:3V. Average indoor temperature and humidity were 32.8℃±1.7℃ and 61.1%±4.12%, respectively. Results: BW, feed conversion ratio (FCR) and carcass weight were not affected by PC, BCCA and their interaction (p>0.05). The L diets decreased the water holding capacity of the breast (p = 0.002) and thigh (p = 0.050) meats and dressing percentage (p = 0.005) compared to the N diets. The 4L:1I:1V diet decreased breast yield compared to the 0L:0I:0V diets (p = 0.041). The effect of PC on feed intake, mortality and gastrointestinal trait weight were depended on the L:I:V ratios under summer conditions due to interactions between factors (p<0.05). The FI and mortality of L4L:1I:1V broilers were lower than those of N4L:1I:1V birds (p<0.05). Conclusion: It was concluded that the blends of BCAAs used failed to improve performance and to promote breast yields, because diets with normal or with reduced protein supplemented or not with BCAAs up to d 15 produced a similar BW and FCR in broilers raised in hot-climate conditions.

Flow and Strength Characteristics of the Lightweight Foamed CLSM(Controlled Low-Strength Materials) with Coal Ash (석탄회를 활용한 경량기포유동화재의 플로우 및 강도 특성)

  • Lee, Seungjun;Lee, Jonghwi;Chae, Hwiyoung;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.12 no.10
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    • pp.73-82
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    • 2011
  • Coal ash of industial by-products was not recycled about 30% in total emissions. Moreover, it caused environmental pollution as well as wasted unnecessary expenses and time. Currently, fly ash(FA) is recycled as construction material however ponded ash(PA) is mostly buried. Lightweight foamed Controlled Low-Strength Materials(CLSM) evaluated in this study reduces unit weight by mixing foam in the traditional Controlled Low-Strength Material and has lightweight and flowability to be available for backfill materials in construction. Flow test, unconfined compressive strength test, and foamed-slurry unit weight test were performed in this study and the applicability of lightweight foamed CLSM for construction materials was evaluated. The results indicate that the mixture ratio(PA:FA) ranging from 70:30 to 50:50, cement of 7%, foam of 2~3%, and water content of 26.5~29.5% were required to satisfy the following standards such as flow value(i.e., 20cm), unconfined compressive strength(i.e., 0.8~1.2MPa), and foamed-slurry unit weight(i.e., $12{\sim}15kN/m^3$).

Relationship between Corrosion in Reinforcement and Influencing Factors Using Half Cell Potential Under Saturated Condition (습윤 상태에서의 반전위를 이용한 철근 부식과 영향 인자 간의 상관성 분석)

  • Jeong, Gi-Chan;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.2
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    • pp.191-199
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    • 2021
  • In this study, the correlation between the influencing factors on corrosion and Half Cell Potential(HCP) measurement was analyzed considering the three levels of W/C ratio, cover depth, and chloride concentration. The HCP increased with enlarged cover depth, so it was confirmed that the increment of cover depth was effective for control of corrosion. Based on the criteria, the case of 60mm cover depth showed excellent corrosion control with under -200mV, indicating increase of cover depth is an effective method for reducing intrusion of external deterioration factors. When fresh water was injected to the upper part of specimens, very low level of HCP was monitored, but in the case that concentrations of chloride were 3.5% and 7.0%, HCP dropped under -200mV. In addition, the case with high volume of unit binder showed lower HCP measurement like increasing cover depth. Multiple regression analysis was performed to evaluate the correlation between the corrosive influence factors and HCP results, showing high coefficient of determination of 0.97. However, there were limitations such as limited number of samples and measuring period. Through the additional corrosion monitoring and chloride content evaluation after dismantling the specimen, more reasonable prediction can be achieved for correlation analysis with relevant data.

High-purity Lithium Carbonate Manufacturing Technology from the Secondary Battery Recycling Waste using D2EHPA + TBP Solvent (이차전지 폐액으로부터 D2EHPA + TBP solvent를 활용한 탄산리튬 제조기술)

  • Dipak Sen;Hee-Yul Yang;Se-Chul Hong
    • Resources Recycling
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    • v.32 no.1
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    • pp.21-32
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    • 2023
  • Because the application of lithium has gradually increased for the production of lithium ion batteries (LIBs), more research studies about recycling using solvent extraction (SX) should focus on Li+ recovery from the waste solution obtained after the removal of the valuable metals nickel, cobalt and manganese (NCM). The raffinate obtained after the removal of NCM metal contains lithium ions and other impurities such as Na ions. In this study, we optimized a selective SX system using di-(2-ethylhexyl) phosphoric acid (D2EHPA) as the extractant and tri-n-butyl phosphate (TBP) as a modifier in kerosene for the recovery of lithium from a waste solution containing lithium and a high concentration of sodium (Li+ = 0.5 ~ 1 wt%, Na+ = 3 ~6.5 wt%). The extraction of lithium was tested in different solvent compositions and the most effective extraction occurred in the solution composed of 20% D2EHPA + 20% TBP + and 60% kerosene. In this SX system with added NaOH for saponification, more than 95% lithium was selectively extracted in four extraction steps using an organic to aqueous ratio of 5:1 and an equilibrium pH of 4 ~ 4.5. Additionally, most of the Na+ (92% by weight) remained in the raffinate. The extracted lithium is stripped using 8 wt% HCl to yield pure lithium chloride with negligible Na content. The lithium chloride is subsequently treated with high purity ammonium bicarbonate to afford lithium carbonate powder. Finally the lithium carbonate is washed with an adequate amount of water to remove trace amounts of sodium resulting in highly pure lithium carbonate powder (purity > 99.2%).

Analysis of Efficiency of Suction Board Drain Method by Step Vacuum Pressure (단계석션압 조건에 따른 석션보드드레인 공법의 효율 분석)

  • Kim, Ki-Nyun;Han, Sang-Jae;Kim, Soo-Sam
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.6C
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    • pp.321-329
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    • 2008
  • In this study, a series of column test as a way in order to make up for the weakness point of the conventional acceleration method were conducted to both propose the suction board drain method and grapes the specific improvement character of this method as a result of a sort of plastic drain board and a phase of vacuum pressure conditions. On this occasion, the study focused on computing the effective factors of the fittest Suction board drain method affected by each condition through confirming the settlement generated during the test, the water content reduction and stress increase effect occurred arising from the test, and the ratio of consolidation related to the improvement period. In accordance with the shape of core and that whether the core is attached to the filter(pocket or adhesion), the castle type of adhesion and the column type of pocket are more efficient than the others as a consequence of the test to find out the improvement effect depending on each drainage such as a castle type, coil type, harmonica type, column type of pocket and a castle of the adhesion. In case of the step suction pressure, the shorter the period of $-0.8\;kg/cm^2$ as a final step of the suction pressure is, the better the improvement is. In addition, the correlation between degree of consolidation per each suction pressure level and duration of application was drawn as a curve and the point of inflection on this curve was provided to determine the duration period to maximize the consolidation.

Chloride Threshold Value for Steel Corrosion considering Chemical Properties of Concrete (콘크리트의 화학적 특성을 고려한 철근 부식 임계 염소이온 농도)

  • Song, Ha-Won;Jung, Min-Sun;Ann, Ki Yong;Lee, Chang-Hong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.1A
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    • pp.75-84
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    • 2009
  • The present study assesses the chloride threshold level for corrosion of steel in concrete by examining the properties of four different binders used for blended concrete in terms of chloride binding, buffering of cement matrix to a pH fall and the corrosion behaviour. As binders, ordinary Portland cement (OPC), 30% pulverised fuel ash (PFA), 60% ground granulated blast furnace slag (GGBS) and 10% silica fume (SF) were used in a concrete mix. Testing for chloride binding was carried out using the water extraction method, the buffering of cement matrix was assessed by measuring the resistance to an artificial acidification of nitric acid, and the corrosion rate of steel in mortar with chlorides in cast was measured at 28 days using an anodic polarisation technique. Results show that the chloride binding capacity was much affected by $C_{3}A$ content and physical adsorption, and its order was 60% GGBS>30% PFA>OPC>10% SF. The buffering of cement matrix to a pH fall was varied with binder type and given values of the pH. From the result of corrosion test, it was found that the chloride threshold ranged 1.03, 0.65, 0.45 and 0.98% by weight of cement for OPC, 30% PFA, 60% GGBS and 10% SF respectively, assuming that corrosion starts at the corrosion rate of $0.1-0.2{\mu}A/cm^{2}$. The mole ratio of [$Cl^{-}$]:[$H^{+}$], as a new presentation of the chloride threshold, indicated the value of 0.008-0.009, irrespective of binder, which would be indicative of the inhibitive characteristic of binder.

Parameters on Physiological Responses of Soybean (Glycine max Merr.) to Salinity (염분에 대한 콩의 생리학적 반응지표 연구)

  • Chon, Sang-Uk;Park, Jong-Hwan
    • Korean Journal of Environmental Agriculture
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    • v.22 no.3
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    • pp.185-191
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    • 2003
  • The mechanism imparting salt tolerance to crop plants remains still unsolved, although soybean has been classified as a susceptible plant to NaCl. To determine optimum parameters on physiological responses for improving sensitivity of salinity in breeding program, soybean (Glycine max Merr., cv. "Gwan-gan") plants were grown in a greenhouse, treated 20 days after emergence for 7 days with NaCl at 0, 30, 60, and 90mM, corresponding to electric conductivity of 1.2, 4.4, 7.3, and 10.4 dS/m, respectively, and assessed 30 days after treatment. Chlorophyll contents were significantly decreased by NaCl ($0.4{\sim}1.0\;mg/g$) compared to control (1.2 mg/g). Photosynthesis rate by NaCl treatment at $0{\sim}90\;mM$ at flowering stage was ranged from 5.0 (control) to $9.6\;{\mu}mol/m^2/s$. Oxygen for respiration was consumed from 5.4 to $9.7\;{\mu}mol/m^2/s$ so that the ratio of $O_2$ (evolution:consumption) was increased with the increase of NaCl, indicating that $O_2$ consumption seems to go beyond $O_2$ evolution. Water potential of leaf at vegetative stage II was ranged from -0.6 to -1.8 MPa and the highest level was observed at mid-day. Water potential by salt stress was decreased with range of $-2.1{\sim}-2.7MPa$ compared to control. Transpiration was decreased from 17% to 20% by NaCl stress. Water vapor diffusing resistance of intercellular air space was affected significantly, increasing up to $16{\sim}24%$ compared to control by NaCl treatment. Salt-treated soybean tended to accumulate $Na^+$, specially in root, with reduced absorption of N, P, $K^+$, $Ca^{2+}$, and $Mg^{2+}$ contents. Free proline content of soybean leaf as affected by different NaCl concentrations was increased 4.2 times ($184{\sim}434\;{\mu}g/g$) more than control. NaCl also increased activities of nitrate reductase and peroxidase by $28{\sim}161%$ and $3{\sim}22%$, respectively. The results show that physiological characteristics of soybean plants during assay were useful as the best parameters of salt stress or salt tolerance test to improve sensitivity in screening and breeding program among cultivars or germplasms.

Quality Characteristics of Cookies with Hot Water Extract of Seamustad (Undaria pinnatifida) Sporophylls and Treated with Gamma Irradiation (감마선 조사된 미역귀(Undaria pinnatifida Sporophyll) 열수추출물을 첨가한 쿠키의 품질 특성)

  • Kim, Da-Mi;Kim, Kyoung-Hee;Yun, Young-Sik;Kim, Jae-Hun;Lee, Ju-Woon;Yook, Hong-Sun
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.40 no.11
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    • pp.1604-1611
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    • 2011
  • In this study we assessed the effects of gamma irradiation (50 kGy) on cookies to which was added various concentrations (1%, 3%, 5%, 7%) of hot water extract from seamustad (Undaria pinnatifida) sporophylls (WEUS) for future industry use. The pH of the dough went down significantly with the addition of WEUS. However, density was not related to that. The spread ratio of the cookies increased significantly as more WEUS was added to the cookie recipe, and cookies containing gamma-irradiated extract were taller than non-irradiated cookies with the same concentration. The loss rate of cookies was the same between control and experiment groups. On the other hand, the leavening rate significantly increased upon the addition of WEUS, and gamma-irradiated cookies were higher than non-irradiated cookies in the same concentration. The L value of cookies was much reduced with higher WEUS content, but the b value showed no significant differences between the control and experiment groups. The a value showed no significant difference for non-irradiated groups, but did for gamma-irradiated groups. Upon the addition of WEUS, hardness was shown to be higher than the control. The antioxidant activity, DPPH radical scavenging, was significantly higher with the control cookies, and upon the addition of WEUS, the gamma-irradiated cookies had higher antioxidant effects than non-irradiated cookies. The sensory evaluation showed that cookies made with WEUS have a positive impact in color, smell, taste, texture, and overall acceptability, but the sensory evaluation worsened with a lot of WEUS. The results of acceptability were higher in cookies with 3% the non-irradiated group and 1% the gamma-irradiated group. These results suggest that the 1% gamma-irradiated group was in the best condition to use in the industry since just a little of it makes exceptional quality, sensory properties, and functionality.