• Bulletin of the Korean Chemical Society
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• 제25권6호
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• pp.937-940
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• 2004

• 마이크로전자및패키징학회지
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• 제10권4호
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• pp.53-60
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• 2003

CCD(Charge-Coupled Device) wafer와 같이 표면이 polymer 성분의 micro lens로 구성되어있는 경우 passivation 막을 도포하지 않는 것이 보통인데, 이때 particle이 lens 표면에 쉽게 달라붙는 현상이 나타나게 된다. 특히 sawing 하면서 발생하는 particle은 치명적인 불량을 유발한다. 본 연구에서는 sawing에서 발생한 particle을 효과적으로 flushing하기위한 방안으로 측면노즐과 중심노즐의 분사위치, 분사각도, 퍼짐각도를 최적화 하고, 아울러 flushing 노즐을 추가한 새로운 형태의 wafer saw를 도입하였다. 개선된 saw를 적용하여 실험한 결과 particle로 인한 CCD chip의 불량률이 9.l%로부터 0.63%로 현격하게 개선되었음을 확인할 수 있었다.

• 대한기계학회논문집B
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• 제26권11호
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• pp.1630-1637
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• 2002

A slab-wick heat pipe was fabricated and tested for applications where the condenser temperature is in a range of 80 to 12$0^{\circ}C$. The pipe material was 9.53 mm O.D. copper tube and the working fluids were ethanol and water. The total length of the heat pipe was 1.6 m, in which evaporator section was 1.4 m and the condenser was 0.10 m. The slab was a composite wick structure fabricated with STS316 wire screens. Thermal load was varied for a specified fill charge ratio and inclined angle. The optimum fill charge ratio was identified to be 110% based on a theoretical calculation of the pore space in the slab wick of the heat pipe. The maximum thermal load was 120W for ethanol and the same was 200W for water with the condenser temperature of 8$0^{\circ}C$. The thermal performance of the slab wick heat pipe is analysed in terms of temperature characteristics and thermal resistance against thermal load, tilt angle and fill charge ratio.

• EDISON SW 활용 경진대회 논문집
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• 제3회(2014년)
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• pp.103-113
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• 2014

Hydrophobicity is the key concept to understand the role of water in protein folding, protein self-assembly, and protein-ligand interaction. Conventionally, hydrophobicity of amino acids in a protein has been argued based on hydrophobicity scales determined for individual free amino acids, assuming that those scales are unaltered when amino acids are embedded in a protein. Here, we investigate how the hydrophobicity of constituent amino acids depends on the protein context, in particular, on the total charge and secondary structures of a protein. To this end, we compute and analyze the hydration free energy - free energy change upon hydration quantifying the hydrophobicity - of three short proteins based on the integral-equation theory of liquids. We find that the hydration free energy of charged amino acids is significantly affected by the protein total charge and exhibits contrasting behavior depending on the protein net charge being positive or negative. We also observe that amino acids in the central ${\beta}$-strand sandwiched by ${\beta}$-sheets display more enhanced hydrophobicity than free amino acids, whereas those in the ${\alpha}$-helix do not clearly show such a tendency. Our results provide novel insights into the hydrophobicity of amino acids, and will be valuable for rationalizing and predicting the strength of water-mediated interaction involved in the biological activity of proteins.

• EDISON SW 활용 경진대회 논문집
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• 제5회(2016년)
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• pp.163-166
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• 2016

Hydrophobicity is the key concept to understand the water plays in protein folding, protein aggregation, and protein-protein interaction. Traditionally, the hydrophobicity of protein is defined based on the scales of the hydrophobicity of residue, assuming that the hydrophobicity of free amino acids is maintained. Here, we explore how the hydrophobicity of constituting amino acids in protein rely on the protein context, in particular, on the total charge and secondary structures of a protein. To this end, we calculate and investigate the hydration free energy of three short proteins based on the integral-equation theory of liquids. We find that the hydration free energy of charged amino acids is significantly affected by the protein total charge and exhibits contrasting behavior depending on the protein total charge being positive or negative. We also observe that amino acids in the ${\beta}-sheets$ display more enhanced the hydrophobicity than amino acids in the loop, whereas those in the ${\alpha}-helix$ do not clearly show such a tendency. And the salt-bridge forming amino acids also exhibit increase of the hydrophobicity than that with no salt bridge. Our results provide novel insights into the hydrophobicity of amino acids, and will be valuable for rationalizing and predicting the strength of water-mediated interaction involved in the biological activity of proteins.

• 설비공학논문집
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• 제21권6호
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• pp.367-372
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• 2009

The performance of a $CO_2$ heat pump water heater was measured with a variation of operating conditions such as refrigerant charge amount, outdoor temperature, compressor frequency, EEV opening, and water mass flow rate. The optimum refrigerant charge amount of the $CO_2$ system was 1800 g. At water mass flow rates of 75, 85, and 95 kg/h, the water heating temperatures were 74, 67, and $62^{\circ}C$ and COPs were 2.6, 2.8, and 3.0, respectively. Besides, the compressor frequency and water mass flow rate were adjusted to maintain the water heating temperature at $60^{\circ}C$ with the decrease of outdoor temperature. As the outdoor temperature decreased by $5^{\circ}C$, the compressor frequency increased beyond 60 Hz and the water mass flow rate decreased by 16.7%.

• 대한설비공학회:학술대회논문집
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• 대한설비공학회 2008년도 동계학술발표대회 논문집
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• pp.310-315
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• 2008

In this study, experimental study on the heating performance of a $CO_2$ heat pump water heater with a variation of operating conditions such as refrigerant charge amount, outdoor temperature, compressor frequency, EEV opening and water mass flow rate. Based on the test results, the optimum charge amount was 1800 g. At the water mass flow rates of 75, 85, 95 kg/hr, the water heating temperature was 62, 67, $74^{\circ}C$ and COP was 2.6, 2.8, 3.0, respectively. Besides, the water mass flow rate and compressor frequency were varied to maintain above the water heating temperature of $60^{\circ}C$ with the decrease of outdoor temperature. So, The compressor frequency increased beyond 65 Hz and the water mass flow rate was 45 kg/hr at the outdoor temperature of $-13^{\circ}C$, 65 kg/hr at $-8^{\circ}C$, 75 kg/hr at $-3^{\circ}C$ and 85 kg/hr at 2, $7^{\circ}C$. As the outdoor temperature decreased, the heating COP decreased by 2.5-39.8%.

• 센서학회지
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• 제8권3호
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• pp.211-218
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• 1999

This paper describes the application of a coupled finite element-boundary element method (FE-BEM) to obtain the steady-state response of a piezoelectric transducer. The particular structure considered is a PZT4 disc-typed projector. The projector is three-dimensionally simulated to transduce applied electric charge on axial surfaces of the piezoelectric disc to acoustic pressure in air or in water. The directivity pattern of the acoustic field formed from the projected sound pressure is also simulated. And the displacement of the disc caused by the externally applied electric charge is shown in temporal motion. The coupled FE-BE method is described in detail.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2017년도 춘계학술대회 논문집
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• pp.126-126
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• 2017

Using first principles calculations we unveil fundamental mechanism of hydrolysis reactions of two hazardous chemicals $PCl_3$ and $POCl_3$ with molecular water clusters nearby. It is found that the water molecules play a key role as a catalyst significantly lowing the activation barriers by transferring its protons to the reaction intermediates. Interestingly, torsional angles of molecular complexes at transition states are identified as a vital descriptor on the reaction rate. Analysis of charge distribution over the complexes further reinforces the finding with atomic level correlation between the torsional angle and variation of the orbital hybridization state of P in the complex. Electronic charge separation (or polarization) enhances thermodynamic stability of the activated complex at transition state and reduces the activation energy through hydrogen bonding network with water molecules nearby. Calculated potential energy surfaces (PES) for the hydrolysis reactions of $PCl_3$ and $POCl_3$ depict their two contrastingly different profiles of double- and triple-deep wells, respectively. It is ascribed to the unique double-bonding O=P in the $POCl_3$. Our results on the activation free energy show well agreements with previous experimental data within $7kcalmol^{-1}$ deviation.

• 한국표면공학회지
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• 제52권5호
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• pp.258-264
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• 2019

Assembling heterostructures by combining dissimilar oxide semiconductors is a promising approach to enhance charge separation and transfer in photoelectrochemical (PEC) water splitting. In this work, the CuO nanorods array/$Cu_2O$ thin film bilayered heterostructure was successfully fabricated by a facile method that involved a direct electrodeposition of the $Cu_2O$ thin film onto the vertically oriented CuO nanorods array to serve as the photoelectrode for the PEC water oxidation. The resulting copper-oxide-based heterostructure photoelectrode exhibited an enhanced PEC performance compared to common copper-oxide-based photoelectrodes, indicating good charge separation and transfer efficiency due to the band structure realignment at the interface. The photocurrent density and the optimal photocurrent conversion efficiency obtained on the CuO nanorods/$Cu_2O$ thin film heterostructure were $0.59mA/cm^2$ and 1.10% at 1.06 V vs. RHE, respectively. These results provide a promising route to fabricating earth-abundant copper-oxide-based photoelectrode for visible-light-driven hydrogen generation using a facile, low-cost, and scalable approach of combining electrodeposition and hydrothermal synthesis.