• Korean Journal of Agricultural and Forest Meteorology
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• v.7 no.1
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• pp.15-27
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• 2005

The water and carbon cycles in terrestrial ecosystems are the essential database for better understanding of the causes and the current processes of climate change and for the prediction of its future change. CarboKorea and HydroKorea are dedicated research efforts to develop technologies to quantitatively interpret and forecast carbon/water cycles in typical landscapes of Korea. For this, stable isotope studies have been launched to genetically partition various components of carbon/water cycles in terrestrial ecosystems. From stable isotope studies, practical deliverables such as evaporation, transpiration and gross primary productivity (GPP) can be provided at scales from tower (footprint) to large watersheds. Such reliable field-based information will form an important database to be used for validation of the results from various eco-hydrological models and satellite image analysis which constitute main components of Carbo/HydroKorea project. Stable isotope studies, together with other relevant researches, will contribute to derive quantitative interpretation of carbon/water cycles in terrestrial ecosystems and support Carbo/HydroKorea to become a leading research infrastructure to answer pending scientific and socio-economic questions in relation to global changes.

• Korean Journal of Agricultural and Forest Meteorology
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• v.7 no.1
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• pp.4-14
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• 2005

CarboKorea and HydroKorea are the domestic projects aiming to improve our understanding of carbon and water cycles in a typical Korean forest located in a complex terrain with a watershed connected to large rivers. The ultimate goal is to provide a nowcasting of these cycles for the whole Peninsula. The basic strategy to achieve such goal is through the inter- and multi-disciplinary studies that synthesize the in-situ field observation, modeling and remote sensing technology. The challenge is the fact that natural ecosystems are nonlinear and heterogeneous with a wide range of spatio-temporal scales causing the variations of mass and energy exchanges from a leaf to landscape scales. Our paradigm now shifts from temporal variation at a point to spatial patterns and from spatial homogeneity to complexity of water and carbon at multiple scales. Yet, a large portion of our knowledge about land-atmosphere interactions has been established based on tower observations, indicating that the development of scaling logics holds the key to the success of CarboKorea and HydroKorea. Here, we review the pioneering work of FIFE (First ISLSCP Field Experiment) on scaling issues in a temperate grassland and discuss the lessons from it for the application to Gwangneung forest site.

• Proceedings of the KSEEG Conference
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• 2002.04a
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• pp.91-91
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• 2002

• Journal of Korean Society on Water Environment
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• v.29 no.3
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• pp.337-342
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• 2013

The particle counter compared with the turbidimeter provides good precision and sensitivity and can get the characteristics of particulates effectively. The purpose of this study is to provide the application of particle counter in sand and activated carbon filters. The particle count by size could be more easily sense when the water quality is changed by the influent of high turbidity or algae. We could decide the optimal backwashing cycles and detect the efficiencies of filters by monitoring the total particle count of effluent in sand and activated carbon filters.

• Proceedings of the Korea Water Resources Association Conference
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• 2021.06a
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• pp.204-204
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• 2021

Terrestrial water storage (TWS) includes all components of water (e.g., surface water, groundwater, snow and ice) over the land. So accurately predicting and estimating TWS is important in water resource management. Although many land surface models are used to predict the TWS, model output has errors and biases in comparison to the observation data due to the model deficiencies in the model structure, atmospheric forcing datasets, and parameters. In this study, Gravity Recovery And Climate Experiment (GRACE) satelite TWS data is assimilated in the Community Land Model version 5 with a biogeochemistry module (CLM5.0-BGC) over East Asia from 2003 to 2010 by employing the Ensemble Adjustment Kalman Filter (EAKF). Results showed that TWS over East Asia continued to decrease during the study period, and the ability to simulate the surface water storage, which is the component of the CLM derived TWS, was greatly improved. We further investigated the impact of assimilated TWS on the vegetated and carbon related variables, including the leaf area index and primary products of ecosystem. We also evaluated the simulated total ecosystem carbon and calculated its correlation with TWS. This study shows that how the better simulated TWS plays a role in capturing not only water but also carbon fluxes and states.

• Journal of Korean Society of Water and Wastewater
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• v.34 no.5
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• pp.323-334
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• 2020

Adsorption by granule activated carbon(GAC) is recognized as an efficient method for the removal of perfluorinated compounds(PFCs) in water, while the poor regeneration and exchange cycles of granule active carbon make it difficult to sustain adsorption capacity for PFCs. In this study, the behavior of PFCs in the effluent of wastewater treatment plant (S), the raw water and the effluents of drinking water treatment plants (M1 and M2) located in Nakdong river waegwan watershed was monitored. Optimal regeneration and exchange cycles was also investigated in drinking water treatment plants and lab-scale adsorption tower for stable PFCs removal. The mean effluent concentration of PFCs was 0.044 0.04 PFHxS g/L, 0.000 0.00 PFOS g/L, 0.037 0.011 PFOA g/L, for S wastewater treatment plant, 0.023 0.073 PFHxS g/L, 0.000 0.00 PFOS g/L, 0.013 0.008 PFOA g/L for M1 drinking water treatment plant and 0.023 0.073 PFHxS g/L, 0.000 0.01 PFOS g/L, 0.011 0.009 PFOA g/L for M2 drinking water treatment plant. The adsorption breakthrough behaviors of PFCs in GAC of drinking water treatment plant and lab-scale adsorption tower indicated that reactivating carbon 3 times per year suggested to achieve and maintain good removal of PFASs. Considering the results of mass balance, the adsorption amount of PFCs was improved by using GAC with high-specific surface area (2,500㎡/g), so that the regeneration cycle might be increased from 4 months to 10 months even if powdered activated carbon(PAC) could be alternatives. This study provides useful insights into the removal of PFCs in drinking water treatment plant.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.448-448
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• 2011

We investigated the fabrication method of superhydrophobic nanocoating prepared by a simple spin-coating and the chemisorption of fatty acid. The resulting coating showed a tremendous water repellency (static water contact angle = $154^{\circ}$) and the water contact angle can be modulated by changing the number of deposition cycles of ZnO and the carbon length of Self-Assembled Monolayers (SAM). Varying the number of deposition cycles of ZnO controlled the surface roughness, and affected to the superhydrophobicity. This simple coating method can be universally applicable to any substrates including flexible surfaces, papers and cotton fabrics, which can effectively be used in various potential applications. We also observed the thermal and dynamic stabilities of SAM on ZnO nanoparticles. The superhydrophobicic surface maintained its superhydrophobic properties below $250^{\circ}C$ and under dynamic conditions.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.08a
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• pp.360-360
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• 2011

We demonstrated the fabrication method of superhydrophobic nanocoating through a facile spin-coating and the chemical modification. The resulting coating showed a tremendous water repellency with a static water contact angle (CA) of 158$^{\circ}$ and a hysteresis of 1$^{\circ}$. The number of ZnO nanoparticle (NP) coating cycles affected on the surface roughness, which is key role for superhydrophobic surface, and thus the CA can be modulated by changing the ZnO NP coating cycles. The CA can be controlled by changing the carbon length of Self-Assembled Monolayers(SAM). This simple ZnO coating is substrate-independent including flexible surfaces, papers and cotton fabrics, which can effectively be used in various potential applications. We also observed the thermal and dynamic stabilities of SAM on ZnO nanoparticles. The superhydrophobicic surface maintained its superhydrophobic properties below 250$^{\circ}C$ and under dynamic conditions.

• Journal of Electrochemical Science and Technology
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• v.14 no.3
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• pp.222-230
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• 2023

Capacitive deionization of saline water is one of the most promising water purification technologies due to its high energy efficiency and cost-effectiveness. This study synthesizes porous carbon composites composed of reduced graphene oxide (rGO) and activated carbon (AC) with various rGO/AC ratios using a facile chemical method. Surface characterization of the rGO/AC composites shows a successful chemical reduction of GO to rGO and incorporation of AC into rGO. The optimized rGO/AC composite electrode exhibits a specific capacitance of ~243 F g^-1 in a 1 M NaCl solution. The galvanostatic charging-discharging test shows excellent reversible cycles, with a slight shortening in the cycle time from the ~260^th to the 530^th cycle. Various monovalent sodium salts (NaF, NaCl, NaBr, and NaI) and chloride salts (LiCl, NaCl, KCl, and CsCl) are deionized with the rGO/AC electrode pairs at a cell voltage of 1.3 V. Among them, NaI shows the highest specific adsorption capacity of ~22.2 mg g^-1. Detailed surface characterization and electrochemical analyses are conducted.

• Korean Journal of Agricultural and Forest Meteorology
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• v.9 no.2
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• pp.149-160
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• 2007

KoFlux Gwangneung Supersite comprises complex topography and diverse vegetation types (and structures), which necessitate complementary multi-disciplinary measurements to understand energy and matter exchange. Here, we report the results of this ongoing research with special focuses on carbon/water budgets in Gwangneung forest, implications of inter-dependency between water and carbon cycles, and the importance of hydrology in carbon cycling under monsoon climate. Comprehensive biometric and chamber measurements indicated the mean annual net ecosystem productivity (NEP) of this forest to be ${\sim}2.6\;t\;C\;ha^{-1}y^{-1}$. In conjunction with the tower flux measurement, the preliminary carbon budget suggests the Gwangneung forest to be an important sink for atmospheric $CO_2$. The catchment scale water budget indicated that $30\sim40%$ of annual precipitation was apportioned to evapotranspiration (ET). The growing season average of the water use efficiency (WUE), determined from leaf carbon isotope ratios of representative tree species, was about $12{\mu}mol\;CO_2/mmol\;H_2O$ with noticeable seasonal variations. Such information on ET and WUE can be used to constrain the catchment scale carbon uptake. Inter-annual variations in tree ring growth and soil respiration rates correlated with the magnitude and the pattern of precipitation during the growing season, which requires further investigation of the effect of a monsoon climate on the catchment carbon cycle. Additionally, we examine whether structural and functional units exist in this catchment by characterizing the spatial heterogeneity of the study site, which will provide the linkage between different spatial and temporal scale measurements.