• Title/Summary/Keyword: Water absorbance

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Ammonia neutralization and removal using electrolyzed-acidic water (전해산성수를 이용한 암모니아 중화와 제거)

  • Choi, Weon-Kyung
    • Journal of the Korea Convergence Society
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    • v.12 no.5
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    • pp.185-190
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    • 2021
  • An electrolyzed-acidic water treatment was investigated as a methods for removing ammonia, which is a cause of odor in life environment. The prepared electrolyzed-acidic water was found out as stable solvent capable of neutralizing weak alkaline ammonia by measuring changes in pH and ORP. It was found out that ammonia was removed from the mixture solution of electrolyzed-acidic water and ammonia water by the UV-vis absorbance analysis and electrochemical open-circuit potential measurement. The neutralized ammonia by electrolyzed-acidic water and effectively removed odor was measured using ammonia gas detecter. Consequently, we recommend the electrolyzed-acidic water can effectively and safely remove ammonia in eco-friendly.

Study on Colour Development in Silver Containing Glass (은을 이용한 착색유리 제조에 관한 연구)

  • 이종근
    • Journal of the Korean Ceramic Society
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    • v.11 no.2
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    • pp.3-10
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    • 1974
  • For the manufacture of the silver-yellow glass, silver nitrate was used as a colorant in the base glass of $K_2O$-CaO-$SiO_2$ system. The latter in which the optimum condition was revealed showing beautiful yellow color had been selected among others after the preparatory studies to choose base glass. Other base glass systems considered were $Na_2O$-CaO-$SiO_2$, $R_2O$-PbO-$SiO_2$ and $R_2O$-PbO-BaO-$SiO_2$. The color developed on the specimen in various conditions was examined, using spectorphotometer, in term of the changes in absorbance with wavelength in the visible range. Experimental variables were the amount of the colorant and the additives, reheating temperature and time. The additives such as ZnO, BaO, $B_2O_3$ and $As_2O_3$ were added to increase the coloring action. It was observed that as the amount of silver increased in the base glass the absorbance around $410{\mu}m$ showed the increasing tendency, but the width of absorption curve was wider. Hence, the optimum amount of silver appeared to be 0.11~0.12%. It was found that ZnO was effective additive when present about 0.1%, while $As_2O_3$ ineffective rather retarding the coloration. Borax and $BaCO_3$ were proved effective when contained separately, but appeared ineffective when coexisted. Proper reheating temperature and time was ranged 550~$580^{\circ}C$ and 50~60 minutes. The higher the reheating temperature and the longer the reheating time, the absorbance was increased, while the width of absorption curve was wider. The colored glass prepared in the present experimental condition was found to have good water-resistance for the decorative purpose.

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Microplate-Based Oxygen Radical Absorbance Capacity (ORAC) Assay of Hydrophilic and Lipophilic Compartments in Plasma

  • Kwak Ho Kyung;Blumberg Jeffrey B.;Chen Chung Yen;Milbury Paul E.
    • Nutritional Sciences
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    • v.9 no.1
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    • pp.48-54
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    • 2006
  • Methods have been developed to evaluate the total antioxidant capacity of foods and plasma but limitations are associated with their ability to determine precisely the contribution of lipophilic antioxidants in a lipid milieu as well as interactions among them Thus, we modified the Oxygen Radical Absorbance Capacity (ORAC) assay to determine the peroxyradical scavenging ability of both hydrophilic and lipophilic compartments in plasma The hydrophilic ORAC assay was performed in a phosphate buffer system utilizing 2,2'-azobis (2-amidinopropane) dihydrochloride as a peroxyradical generator and fluorescein as the target The lipophilic ORAC assay was carried out in a dimethylsulfoxide :butyronitrile (DMSO/BN, 9:1 v/v) system using 2,2'-azobis (2,4-dimethyl valeronitrile) as a peroxyradical generator and BODIPY C11 581/591 as the target Analyses were conducted in bovine serum supplemented with water - and lipid - soluble antioxidants and in human plasma. Albumin (0.5$\sim$5 g/dL) and uric acid (0.1$\sim$0.5 $\mu$mol/L) increased hydrophilic ORAC values in a dose-dependent fashion ($R^{2}$=0.97 and 0.98, respectively) but had no impact on lipophilic ORAC values. $\alpha$-Tocopherol (15$\sim$200 $\mu$mol/L) increased lipophilic ORAC values in a dose-dependent fashion ($R^{2}$=0.94); neither $\alpha$-tocopherol nor $\beta$-carotene had an impact on hydrophilic ORAC values. However, addition of $\beta$-carotene at physiological concentration (0.23$\sim$1.86 $\mu$mol/L), either alone or in combination with other carotenoids, had no significant impact on lipophilic ORAC values. Thus, while assays of 'total antioxidant capacity' in biological matrices would be a useful research and clinical tool, existing methods are limited by the lack of complete responsiveness to the full range of dietary antioxidants.

Effect of GAC Packing Mass in Hybrid Water Treatment Process of PVdF Nanofibers Spiral Wound Microfiltration and Granular Activated Carbon (PVdF 나노섬유 나권형 정밀여과와 입상 활성탄의 혼성 수처리에서 활성탄 충진량의 영향)

  • Kyung, Kyu Myung;Park, Jin Yong
    • Membrane Journal
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    • v.27 no.1
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    • pp.68-76
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    • 2017
  • Flat membrane with $0.4{\mu}m$ pore size was prepared with PVdF (polyvinylidene fluoride) nanofiber, which has the advantages such as excellent strength, chemical resistance, non-toxicity, and incombustibility. The spiral wound module was manufactured with the flat membrane and a woven paper. Hybrid water treatment process was composed of the PVdF nanofibers spiral wound microfiltration and granular activated carbon (GAC) adsorption column. Effect of GAC packing mass was investigated by comparing the case of recycling or discharging the treated water using the synthetic solution of kaolin and humic acid. After each filtration experiment, water back-washing was performed, and recovery rate and filtration resistances were calculated. Also, effect of GAC adsorption was compared by measuring turbidity and $UV_{254}$ absorbance. As a result, there was no effect of GAC packing mass on turbidity treatment rate; however, the treatment rate of $UV_{254}$ absorbance was 0.7~3.6% for recycling the treated water, and increased to 3.2-5.7% for discharging the treated water. In the case of recycling the treated water, reversible filtration resistance ($R_r$) and irreversible filtration resistance ($R_{ir}$) trended to decrease as increasing GAC packing mass; however, total fitration resistance ($R_t$) was almost constant, and recovery rate of water back-washing trended to increase a little.

Fate and Characteristics of Dissolved Organic Matters in a Water Reclamation Facility, Korea (하수처리수 재이용시설의 공정별 용존유기물질 거동 및 특성)

  • Kwon, Eun-Kwang;Lee, Wontae
    • Journal of Korean Society on Water Environment
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    • v.37 no.5
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    • pp.355-362
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    • 2021
  • This study investigated the fate of dissolved organic matter (DOM) in a water reclamation facility (WRF) in Korea. The WRF consists of coagulation, sedimentation, microfiltration, and reverse osmosis (RO) components. The production capacity of WRF is 90,000 m3/day. The reclaimed water is reused as industrial water. We also characterized DOM in raw, processed, and finished waters based on analysis of dissolved organic carbon (DOC), ultraviolet absorbance at 254 nm (UVA254), fluorescence excitation emission matrix (FEEM), and DOC fractions via liquid chromatography-organic carbon detection (LC-OCD). Based on the results of DOC, UVA254, and FEEM analyses, neither the coagulation/sedimentation nor the microfiltration at the WRF effectively removed DOM. The RO process removed more than 94% of DOM. The raw water (i.e., secondary treated effluent obtained from a wastewater treatment plant) exhibited tryptophan-like peaks, which are a promising marker of wastewater, in the FEEM analysis. Coagulation and microfiltration failed to eliminate the wastewater marker, whereas RO completely removed it. The raw water also carried high levels (89.4%) of hydrophilic and low-molecular weight substances, which are difficult to remove via coagulation-sedimentation or microfiltration. Humic substance was a major component of the hydrophilic fractions. Based on the LC-OCD analysis, RO effectively removed the humic and polymeric materials from DOM.

Solubilization of bromadiolone in humic acid pseudomicellar media

  • Prakash, John
    • Advances in environmental research
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    • v.1 no.3
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    • pp.211-221
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    • 2012
  • Bromadiolone (BRD), a second generation anticoagulant often applied to the living environment to control rodents, is usually considered to have low environmental toxicity due to its poor solubility in water. In this study of the effect of humic acid (HA) on BRD using electronic absorption spectroscopy, it has been observed that BRD is appreciably solubilized even in low concentrations of aqueous HA solutions. The BRD solubilization efficiency of aqueous HA was found to be $2.39{\pm}0.14$ ($4.53{\pm}0.26{\mu}M\;ppm^{-1}$). It was also seen that BRD is reasonably solubilized in aqueous extract of farm soil.

Dyeing of Tencel with Coptis chinensis Franch (황련에 의한 Tencel직물의 염색)

  • 배상경
    • Textile Coloration and Finishing
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    • v.12 no.5
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    • pp.288-294
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    • 2000
  • The dyeing of Tencel fabric with Coptis chinensis Franch was studied. The colorant was extracted with distilled water under various concentrations of dyestuff, times, mordants. UV-VIS spectra were obtained to find the maximum wavelength and absorbance of colorant. Tencel fabric was dyed with different mordants in pre and post-mordanting methods. Maximum wavelength of spectrum was 343 nm, and K/S value of pre-mordant was higher than post-mordant. Aluminium and stannic mordants changed color from yellow to blue-greenish and red-bluish. Colorfastnesses of light, and washing were low grade, but that of perspiration was increased.

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Advanced Water Treatment by Ozonation in a Continuous Flow System (연속식 오존접촉조에서의 정수처리효과에 대한 연구)

  • Lee, Byung-Ho;Jung, Woo-Sung;Kim, Jae-Hoon;Lee, Jun-Hee;Kim, Tae-Gun
    • Journal of Korean Society of Water and Wastewater
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    • v.11 no.2
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    • pp.94-104
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    • 1997
  • Ozone Treatment is getting a common process in a water treatment plant all over the nation. Especially an advanced water treatment using ozone and biofiltration has been a typical method in the regions where using the Nak-Dong River as a drinking water source. The effectiveness of ozone treatment in a continuous flow contact system was investigated with sand filtered water of the Nak-dong River. Pilot tests of the experiments were performed three times of the year like June, August, and October 1995. Most degradable organics of sand filtered water were oxidized in the first and second contact chamber of the system. Ozone treatment was effective for the removal of UV254 absorbance. However, Noticeable removals of $KMnO_4$ demand and TOC(Total Organic Carbon) were occurred when their concentrations exceeded about 5mg/l. The organics causing $KMnO_4$ demand and TOC were degraded into lower molecular matter in an early stage of the ozone contact in the system. Dissolved oxygen concentration was increased after ozone treatment.

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Change of Molecular Weight of Organic Matters through Unit Water Treatment Process and Associated Chlorination Byproducts Formation

  • Sohn, Jin-Sik;Kang, Hyo-Soon;Han, Ji-Hee;Yoon, Yeo-Min
    • Environmental Engineering Research
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    • v.12 no.5
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    • pp.224-230
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    • 2007
  • The objectives of this study were to evaluate the change of molecular weight (MW) profiles in natural organic matter (NOM) through various treatment processes (coagulation, granular activated carbon (GAC), and ozonation) using high performance size exclusion chromatography based on ultraviolet absorbance and dissolved organic detection (HPSEC-UVA-DOC). In addition, relationships between MW profiles and disinfection by-production (DBP) formation were evaluated. Each treatment process results in significant different effects on NOM profiles. Coagulation is effective to remove high molecular weight NOM, while GAC is effective to remove low molecular weight NOM. Ozonation removes only a small portion of NOM, while it induces a significant reduction of UV absorbance due to breakdown of the aromatic groups. All treated waters are chlorinated, and chlorination DBPs such as trihalomethanes (THMs) and haloacetic acids (HAAs) are measured under formation potential conditions. Both THM and HAA formation potentials were significantly reduced through the coagulation process. GAC was more effective to reduce THM formation compared to HAA formation reduction, while ozonation showed significant HAA reduction compared to THM reduction.

Optimal Conditions for Extraction of Anthocyan from Celosia cristata L., Brassica juncea czerniak et coss, Beta vulgaris L. for manufacture of Color Dongchimi (컬러동치미 제조를 위한 홍갓, 맨드라미, 비트에 함유된 안토사이안 색소의 최적 추출 조건)

  • Kim, Mi-Hye
    • Journal of the Korean Society of Food Culture
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    • v.27 no.6
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    • pp.686-694
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    • 2012
  • This study was conducted to develop a method to change the color of traditional Dongchimi using natural dyes to meet changing consumer demands. It was intended to improve the manufacturing process ability for color Dongchimi, and the best optimum extraction solvent and method from the natural dyes were proven to be confirmed and valid. The extraction process was evaluated using different solvents including distilled water, 20% ethyl alcohol, and 1% citric acid, and the quantity of the extracted anthocyanin was then measured based on the absorbance. The greatest absorbance was observed when 1% citric acid was used. Based on these findings, it would be most efficient to allow the traditional Dongchimi to produce citric acid naturally instead of using artificial additives during its production. Celosia cristata L. was extracted in its largest quantity when reacted with 20% ethyl alcohol. Therefore, instead of applying Celosia cristata L. to Dongchimi as the sub-ingredient during the preparatory stage, it will be more efficient to use Celosia cristata L. as the fractional ingredient in order to first extraction.