• 한국염색가공학회지
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• 제22권1호
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• pp.21-27
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• 2010

The purpose of this research was to investigate the color characteristic and the dyeing properties of Glycyrrhizae Radix extract on cotton fabrics. The highest absorbance of Glycyrrhizae Radix extract was obtained in 75 v/v% of ethyl alcohol in water. Pre-mordanted cotton fabrics dyed at $30^{\circ}C$ and pH 3 for 80 minutes showed the highest K/S value. According to the dyeing conditions, the colors of the fabrics varied from yellow(Y) and yellowish red(YR) to greenish yellow(GY). The color fastness of the fabrics in dry-cleaning and water was 4~5 rating. The deodorization capacity and UV-cut effect of the dyed fabrics were higher than those of undyed ones.

• Bulletin of the Korean Chemical Society
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• 제6권1호
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• pp.37-40
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• 1985

The electrical conductance and UV absorbance of 4,N-dimethyl Pridinium Iodide (NDMPI) were measured in the ethanol volume percentage, 95, 90, 80 and 60 of an ethanol-water mixture at 15, 25, 35 and $45^{\circ}C$. Ionic association constants(K) of NDMPI were evaluated in accordance with a combined method of conductance UV absorbance. The ion size parameter (${\gamma}_{\pm}$) and dipole momemt (${\mu}_{A+D-}$) of NDMPI were obtained from the values of K and dielectric constant. The ${\mu}_{A+D-}$- values were in good agreement with the values of transition moment(${\mu}_{mn}$) which is calculated form the UV peak values. The large negative values of the electrical enthalpy (${\Delta}H_{el}^{\circ}$) and entropy (${\Delta}H_{el}^{\circ}$ ) have proved that NDMPI had a positive hydration. The positive values of entropy (${\Delta}S^{\circ}$) means the formation of NDMPI ion goes with dehydration.

• 한국환경보건학회지
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• 제24권2호
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• pp.38-46
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• 1998

The purpose of this study is to evaluate and compare the effective coagulation of commercial humic acid which is well known as major precursor of trihalomethane, with LAS and PAC and to quantify the residual aluminum in the treated water. Then the optimum pH, the dosage of coagulant were determined. 1. Humic acid concentrati6n, UV absorbance and color were well correlated and UV absorbance(254 nm) and color seem to be used in quntificative analysis of humic acid of same kind. 2. Optimal dosage of LAS and PAC increase as humic acid concentration increases. And optimal pH range for coagulation using LAS is pH 5.5-7.0 and pH 3.5-6.5 for PAC. Within these ranges the removal efficiency is 90-99%. 3. The results of quantification of residual aluminum in treated water shows that minimal aluminum remains on the optimal coagulation condition. But the residual aluminum increses as the dosage of coagulant is beyond the optimal range. Thus the dosage of coagulant should be chosen with the condition on which humic acid removal is maximum and the residual aluminum concentration is minimum. 4. In the water treatment process the raw water pH range is 6.5-8.0, and it seems to be possible to remove humic acid by charge neutralization not by sweep floc. But it should be considered that different commercial humic acids have different physical and chemical characteristics.

• 대한화학회지
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• 제30권5호
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• pp.423-432
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• 1986

폐수 중의 6가크롬을 음이온 교환체인 aliquat-336(tri-caprylmethyl ammonium chloride)으로 이온쌍을 형성시켜 유기용매인 p-xylene으로 추출하여 원자흡수분광도법으로 정량하는 방법에 대하여 조사 검토하였다. Toluene을 용매로 사용하여 유기물을 제거한 폐수 100ml를 취하여 염산으로 pH 0.5 되게 산성화시킨 다음 aliquat-336을 0.01M되게 녹인 p-xylene 20ml로 6가크롬을 추출하였다. 표준물첨가법에 의해 air-acetylene 불꽃에서 용매중에 추출된 6가크롬을 정량하였다. Al(III), Fe(III), Cr(III)이온들은 6가크롬의 추출 및 흡광도 측정에 방해 하지 않았으며, Fe(III)이온이 6가크롬을 3가크롬으로 환원시키기 때문이다. 또한 유기물이 존재하면 6가크롬의 흡광도를 감소시키므로 이런 방해유기물을 toluene으로 추출 제거하였다. 최적 조건으로 분석한 결과는 96%이상의 회수율을 보여 주었고 이는 미량 분석에서 정확한 방법이라 할 수 있고, 상대평균편차가 3.95%로서 재현성도 비교적 좋았다.

• 한국농업기계학회:학술대회논문집
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• 한국농업기계학회 2017년도 춘계공동학술대회
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• pp.101-101
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• 2017

Beta-glucan is a polymerized polysaccharide on beta-1,3 chemical bonds. It has the main pharmacological action of various anticancer mushrooms and is colorless and odorless. In addition, it enhances phagocytosis of macrophages against mycobacterium tuberculosism and increases resistance of host against food poisoning bacteria. Owing to these advantages, beta-glucan was used in various health supplement foods such as immune boosters, hypotensive agent and hypoglycemic agent. Our study was aimed to investigate the effective components of beta-glucan, which was optimized via the contents of Sarcodon aspratus and rice bran. First, the mixture ratio condition of Sarcodon aspratus and rice bran were respectively 10:0, 7:3, 5:5, 3:7, and 0:10. The raw materials were fabricated using hot water extraction method. Distilled water of 100 mL was added to the raw material and extracted. After the extraction processed, the content of effective components was analyzed. The absorbance of beta-glucan was measured using a beta-glucan kit (Megazyme, (1-3) (1-4) BETA-D-GLUCAN ASSAY KIT). The absorbance analysis was repeated three times for accurate analysis. After the extracts were lyophilized, the yields of extracted raw materials according to the mixture ratio conditions of Sarcodon aspratus and rice bran (10:0, 7:3, 5:5, 3:7, and 0:10) were respectively 33.1%, 34.5%, 35.3%, 30.7%, and 24.3%. The absorbance was 1.52, 1.47, 1.50, 1.79, and 1.56, respectively. As a result, the optimum ratio of beta-glucan is 3:7 at Sarcodon aspratus and rice bran. This study suggested that the optimal amount of beta-glucan could be used as a health supplement foods and food additive such as immune boosters, hypotensive agent and hypoglycemic agent. However, the new condition (temperature, time) of hot water extraction to maximize the content of beta-glucan could be considered, could be necessary to compare with the existing extracts.

• 한국환경과학회지
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• 제22권7호
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• pp.915-923
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• 2013

Decomposition of non-biodegradable contaminants such as phenol contained in water was investigated using a dielectric barrier discharge (DBD) plasma reactor in the aqueous solutions with continuous oxygen bubbling. Effects of various parameters on the removal of phenol in aqueous solution with high-voltage streamer discharge plasma are studied. In order to choose plasma gas, gas of three types (argon, air, oxygen) were investigated. After the selection of gas, effects of 1st voltage (80 ~ 220 V), oxygen flow rate (2 ~ 7 L/min), pH (3 ~ 11), and initial phenol concentration (12.5 ~ 100.0 mg/L) on phenol degradation and change of $UV_{254}$ absorbance were investigated. Absorbance of $UV_{254}$ can be used as an indirect indicator of phenol degradation and the generation and disappearance of the non-biodegradable organic compounds. Removal of phenol and COD were found to follow pseudo first-order kinetics. The removal rate constants for phenol and COD of phenol were $5.204{\times}10^{-1}min^{-1}$ and $3.26{\times}10^{-2}min^{-1}$, respectively.

• 한국물환경학회지
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• 제21권2호
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• pp.125-131
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• 2005

Natural organic matter(NOM) is defined as the complex matrix of organic material and abundant in natural waters. It affects the performance of unit operations for water purification. Several kinds of analytical indicators such as DOC, specific ultraviolet absorbance(SUVA), apparent molecular weight (AMW), fractionation and high performance size exclusive chromatography(HPSEC) have been used to understand characteristics and variations of NOM. This study aims to evaluate the characteristics of NOM in the Geum River system comprising with stream flows and reservoirs. It was identified that SUVA denoting the portion of humic substance in water ranged within 1.60~3.36. Using resin adsorbents, dissolved organic carbon(DOC) was fractionated into three classes: hydrophobic bases(HOB), hydrophobic acids(HOA) and hydrophilic substances(HI). HI dominates in all samples, collectively accounting for more than 62% of the DOC. HOA was the second dominated fraction and it varied considerably but accounted for about 30% of the DOC. The distribution of high molecular weight(HMW) measured by HPSEC being used to determine the molecular weight distribution of aquatic humic substances was 40.1% and 38.7% in reservoir and stream flow, respectively. The distribution of low molecular weight(LMW) in stream flow was 13.2% higher than that in reservoir. And apparent molecular weight less than 1KDa, which include the molecular weight of hydrophilic organic matter, occupied with 69.2% and 68.2% in stream flow and reservoir, respectively. While the molecular weight of 1 to 100 KDa including humic substances ranged with 18.6% and 21.6% in stream flow and reservoir, respectively. Seasonal variation of refractory dissolved organic carbon was similar to that of SUVA.

• 한국염색가공학회지
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• 제11권2호
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• pp.38-45
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• 1999

Natural red colorants were extracted from Phytolacca americana Linne by using 50% ethanol solution at room temperature for 12 hours. The colorant components were partially purified as yellow and deep red colorants by thin layer chromatography. Natural red colorants were consisted of major water-soluble red colorant, having maximum absorbance at 538nm and alcohol-soluble yellow colorant, having maximum absorbance at 664nm. Concentration of red colorants were calibrated by the equation of dye(mg/ml) $A_{538nm}\times{1.284}$. Red colorants were changed to yellow at extreme alkali pH and repaired 55% color intensity by neutralization of pH and stabled below $55^\circ{C}$. Dyeability of red colorants against wool fabrics was mainly operated by red pigment having 538nm absorbance without big color differences. Below $55^\circ{C}$, color differences $(\Delta{E}^*_{ab})$ were not changed in spite of big difference of chroma$(c^*)$, having higher scores at higher temperature. The effect of mordants were not drastically changed parameters of color difference without copper ion. Citric acid was big changes of color difference$(\Delta{E}^*_{ab})$ in spite of similar chroma$(c^*)$ values. From these experimental results, red colorants from Phytolacca americana Linne is available for wool fabric dyeing.

• 복식
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• 제14권
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• pp.133-144
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• 1990

The purpose of this study is to investigate the absorbance of the Shikonin, one of the major purple pigments, and the stability against the effect of light, $O_2$, and temperature. The effect of mordant and mordanting condition to color and color-fastness is compared and analysed through the color-fastness-test, color-difference value-test, and IR-test. The results were as follows; 1. The absorbance of Shikonin was examinated through 6 kinds of solutions and distilled water. Shikonin was absorbed by solutions rather easily than distilled water. 2. The light effect to Shikonin indicated that the solution with the light was more stable than that without it. 3. The effect of $O_2$ to Shikonin showed that the solution with the $O_2$ was more stable that without it $O_2$. 4. Shikonin -methyl alcohol solution was stable in $25^{\circ}C$. It was unstable in $60^{\circ}C$ and $100^{\circ}C$ with lowered absorbance and changed colors. 5. Color-fastness test to silk and cotton indicated washing color-fastness and perspiration color-fastness was more than 3 grade. But the light color-fastness and crocking color-fastness was low. 6. The comparison between non -colored sample and colored-sample showed the latter was better in fastness. 7. Mordant as $Alk(SO_4)_2{\cdot}24H_2O$ and $AlCl_3{\cdot}6H_2O$ was better than anything else in fastness. 8. Color-difference value-test indicated that the mordant which had the jade green color, the original purple pigment color, was the best in use. 9. The best way to extract the original purple pigment color was in $25^{\circ}C$, because extracted dyeing solution by Soxhlet had the bluish color.

• 멤브레인
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• 제21권4호
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• pp.351-359
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• 2011

For advanced drinking water treatment of high turbidity water, we used the hybrid process that was composed of photocatalyst packing in space of between outside of multi-channel ceramic microfiltration membrane and membrane module inside. Photocatalyst was polypropylene (PP) beads coated $TiO_2$ powder by CVD (chemical vapor deposition) process. Instead of natural organic matters (NOM) and fine inorganic particles in natural water source, standard NOM solution was prepared with humic acid and kaolin. Water-back-flushing of 10 sec was performed per every period of 10 min to minimize membrane fouling. Resistance of membrane fouling ($R_f$) increased and J decreased as concentration of humic acid changed from 2 mg/L to 10 mg/L, and finally the highest total permeate volume ($V_T$) could be obtained at 2 mg/L. Then, treatment efficiency of turbidity and $UV_{254}$ absorbance were above 96.4% and 78.9%, respectively. As results of treatment portions by membrane filtration, photocatalyst adsorption, and photo-oxidation in (MF), (MF + $TiO_2$), (MF + $TiO_2$ + UV) processes, turbidity was treated little by photocatalyst adsorption, and photo-oxidation. However, treatment portions of $UV_{254}$ absorbance by adsorption (MF + $TiO_2$) and photo-oxidation (MF + $TiO_2$ + UV) at humic acid of 4 mg/L and 6 mg/L were above 9.0, 9.5 and 8.1, 10.9%, respectively.