• Title/Summary/Keyword: Water Stabilization

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Effect of nano-stabilizer on geotechnical properties of leached gypsiferous soil

  • Bahrami, Reza;Khayat, Navid;Nazarpour, Ahad
    • Geomechanics and Engineering
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    • v.23 no.2
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    • pp.103-113
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    • 2020
  • Gypsiferous soils classified as problematic soils due to the dissolution of gypsum. Presence of gypsum in the soils texture subjected to steady flow can cause serious damages for the buildings, roads and water transmission canals. Therefore, researchers have conducted a series of physical, mechanical and microstructural laboratory tests to study the effect of gypsum leaching on the geotechnical properties of a lean clay containing 0%, 3%, 6%, 9%, 12%, and 15% raw gypsum. In addition, a combination of two nano-chemical stabilizers named Terrasil and Zycobond was used in equal proportions to stabilize the gypsiferous clayey samples. The results indicated that gypsum leaching considerably changed the physical and mechanical properties of gypsiferous soils. Further, adding the combination of Terrasil and Zycobond nano-polymeric stabilizers to the gypsiferous soil led to a remarkable reduction in the settlement drop, compressibility, and electrical conductivity (EC) of the water passing through the specimens, resulting in improving the engineering properties of the soil samples. The X-ray diffraction patterns indicate that stabilization by terrasil and zycobond causes formation of new peaks such as CSH and alteration of pure soil structure by adding raw gypsum. Scanning electron microscope (SEM) images show the denser texture of the soil samples due to chemical stabilization and decrease of Si/Al ratio which indicates by Energy dispersive X-ray (EDS) interpretation, proved the enhance of shear strength in stabilized samples.

Disinfection Efficiency of the Waste Stabilization Ponds Coupled with Aquatic Plant Ponds (산화지와 수생식물 처리지를 결합한 통합 처리 시스템의 살균효율에 관한 연구)

  • Kim, Youngchul;Jeong, Ha-Young;Lee, Rae-Bum;Lim, Gyeongeun
    • Journal of Wetlands Research
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    • v.4 no.2
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    • pp.23-41
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    • 2002
  • In this paper, changes of the coliform bacteria were investigated when aquatic plant pond was used for separating algal particles from waste stabilization ponds(WSPs). Three different types of integrated natural systems were operated. It was found that there were no significant interferences for the disinfection efficiency of two integrated systems (WSPs coupled with water hyacinth ponds) used for treating domestic sewage and upgrading the secondary effluent as well. However, when constructed wetland (CW) was combined with the shallow algal ponds and used for the secondary effluent, it seriously interfered with the disinfection efficiency due to the regrowth and/or after-growth of the coliform bacteria, which can readily metabolize the amino acids and sugars leached from plants. In order to find out the primary disinfection parameters, several sets of the batch test were run. It was found that sunlight is the most predominant factor for the coliform decay. During the night, algal toxicity partly supports the decay but during the day, deteriorates it by attenuating the sunlight. The pH in the range of 4 to 10 did not affect the decay in the dark.

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Adsorption Stabilization of $TiC_{2}$ Particles in Water Soluble Block Copolymers (수용성 블록공중합물에서 산화티탄 분말의 흡착 안정화)

  • Kwan, Soun-Il;Jeong, Hwan-Kyeong;Choi, Seung-Ok;Nam, Ki-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.18 no.2
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    • pp.118-126
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    • 2001
  • Micelle formation and adsorption at the $Ti0_{2}$ interface of a series of polystyrene-polythylene oxide(PS-PEO) block copolymer in aqueous solution was studied using fluorescence probing and small-angle X-ray methods. Further, the stability of aqueous $Ti0_{2}$ dispersion in the presence of copolymer was investigated by microelectrophoresis, optical density and sedimentation measurements. The dissolution of pyrene as fluorescent probe in aqueous surfactant solution leads to a slow decrease of the $I_{1}/I_{3}$ ratio, as the copolymer concentration increase; $I_{1}$ and $I_{3}$ are respectively the intensities of the first and third vibrionic peaks in the pyrene fluorescence emission. The behaviour was due to the characteristics of the copolymers and/or to the copolymer association efficiency in water. Moreover, the adsorption at the plateau level increases with decreasing PEO until chain length. The zeta potential of $TiO_{2}$ particles decreases with increasing copolymer concentration and reaches a plateau value. Finally, stabilization using block copolymers was more effective with samples having higher weight fractions of PS block.

A Study on the Structure and Thermal Property of $Co^{2+}$-Exchanged Zeolite A

  • Jong-Yul Park
    • Bulletin of the Korean Chemical Society
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    • v.12 no.3
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    • pp.265-270
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    • 1991
  • Theoretical calculations on the stabilization energies of framework atoms in hydrolyses Co(Ⅱ )-exchanged zeolite A were made using some potential energy functions and optimization program. The protons which are produced by hydrolysis of $[Co(H_2O)_n]^{2+}$ ion in large cavity showed a tendency to attack the framework oxygen atom O(1) preferentially, and the oxygen atom O(4) within OH- ion was coordinated at Al atom. The weakness of bonds between T(Si, Al) and oxygen by attack of proton and too large coordination number around small aluminum atom will make the framework of Co(Ⅱ)-exchanged zeolite A more unstable. The stabilization energy of $Co_4Na_4$-A framework (- 361.57 kcal/mol) was less than that of thermally stable zeolite A($Na_{12-}$A: - 419.68 kcal/mol) and greater than that of extremely unstable Ba(Ⅱ)-exchanged zeolite A($Ba_{6-}$A: - 324.01 kcal/mol). All the data of powder X-ray diffraction, infrared and Raman spectroscopy of Co(Ⅱ)-exchanged zeolite A showed the evidence of instability of its framework in agreement with the theoretical calculation. Three different groups of water molecules are found in hydrated Co(Ⅱ )-exchanged zeolite A; W(Ⅰ) group of water molecules having only hydrogen-bonds, W(Ⅱ) group water coordinated to $Na^+$ ion, ans W(Ⅲ) group water coordinated to Co(Ⅱ) ion. The averaged interaction energy of each water group shows the decreasing order of W(Ⅲ)>W(Ⅱ)>W(Ⅰ).

Formation and Stabilization of Raphasatin and Sulforaphene from Radish Roots by Endogenous Enzymolysis

  • Kim, Jae-Won;Kim, Mi-Bo;Lim, Sang-Bin
    • Preventive Nutrition and Food Science
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    • v.20 no.2
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    • pp.119-125
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    • 2015
  • The biologically active compounds raphasatin and sulforaphene are formed during the hydrolysis of radishes by an endogenous myrosinase. Raphasatin is very unstable, and it is generated and simultaneously degraded to less active compounds during hydrolysis in aqueous media. This study determined the hydrolysis conditions to maximize the formation of raphasatin and sulforaphene by an endogenous myrosinase and minimize their degradation during the hydrolysis of radish roots. The reaction parameters, such as the reaction medium, reaction time, type of mixing, and reaction temperature were optimized. A stability test for raphasatin and sulforaphene was also performed during storage of the hydrolyzed products at $25^{\circ}C$ for 10 days. The formation and breakdown of raphasatin and sulforaphene in radish roots by endogenous enzymolysis was strongly influenced by the reaction medium, reaction time, and type of mixing. The production and stabilization of raphasatin in radishes was efficient in water and dichloromethane with shaking for 15 min at $25^{\circ}C$. For sulforaphene, the favorable condition was water as the reaction medium without shaking for 10 min at $25^{\circ}C$. The maximum yields of raphasatin and sulforaphene were achieved in a concurrent hydrolysis reaction without shaking in water for 10 min and then with shaking in dichloromethane for 15 min at $25^{\circ}C$. Under these conditions, the yields of raphasatin and sulforaphene were maximized at 12.89 and $1.93{\mu}mol/g$ of dry radish, respectively. The stabilities of raphasatin and sulforaphene in the hydrolyzed products were 56.4% and 86.5% after 10 days of storage in water and dichloromethane at $25^{\circ}C$.

폐탄광지역 퇴적물의 중금속 존재형태 및 안정화에 관한 연구

  • Lee Jeong-Ran;Lee Jae-Yeong;Kim Hwi-Jung
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.04a
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    • pp.253-259
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    • 2005
  • Mine is quickly decline, Nowadays, many of abandoned and closed mines. AMD is abandoned surface water by accumulated yellowboy and caused environmental pollution by amount of heavy metals. The aim of this study waste lime was mixed with the sediment to produce an aggregate far the purpose of neutralizing the acidity and stabilization the heavy metal in the aggregate structure .to pozzolan effect. The result of Waste lime and sediment mixed(5%, 10%, 20%)ration by curing days(3, 7, 38days), After 28 curing days as 5% mixed waste lime leaching solution concentration of all heavy metals is satisfied with regulation limit. Also, the result of fractionate heavy metals to stabilization as 28 curing days very decrease exchangeable and reducible type, and then increase carbonate type. With the above results, waste lime the most effective for the sediment treatment and useful for the recycling waste resource.

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Stabilization of .betha.-D-galactosidase from heat and chemical inactivation with the extract of panax ginseng C. A. Meyer

  • Kim, Doo-Ha;Hahn, Younghe;Hong, Soon-Keun
    • Archives of Pharmacal Research
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    • v.5 no.2
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    • pp.45-52
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    • 1982
  • Staibilization effect of Panax ginseng C. A. Meyer on .betha.-D-Galactosidase inactivation was proved by kinetic studies of thermal inactivation of the enzyme. The water extract Panax ginseng C. A. Meyer showed stabilization activity at minimal concentration of 10ppm. The methanolic extract was purified to obtain ginseng saponins, and two groups of the ginsenosides, i. e. protopanaxadiol and protopanaxatriol were isolated. They also showed a protective effect against the thermal and chemical inactivation of the enzyme; p-chloromercuribenzoic acid and hydroxylamine known as protein modifier greatly inactivated the enzyme but inactivation was significantly balocked by the ginseng component MG$^{2+}$, known as a cofactor, stabilized the enzyme and the poor stabilization effect by it was potentiated by ginseng components.s.

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Dimensional Stabilization through Heat Treatment of Thermally Compressed Wood of Korean Pine (잣나무 열압밀화재의 열처리를 통한 치수안정화)

  • Lee, Jeong Min;Lee, Won Hee
    • Journal of the Korean Wood Science and Technology
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    • v.46 no.5
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    • pp.471-485
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    • 2018
  • Post-heat treatment experiments were carried out for complete dimensional stabilization of thermally compressed wood (Pinus koraiensis). An absorption test was carried out to evaluate the dimensional stability. The specific gravity increased from 0.43 to 0.79 by thermal compression at a compression ratio of 50% thickness. Through the post-heat treatment of compressed wood, the water absorption and thickness swelling decreased with increasing the heat treatment temperature and time. In the case of the thickness recovery rate, when the heat treatment was performed for 24 hours at $120^{\circ}C$, $140^{\circ}C$ and $160^{\circ}C$, the thickness recovery was less than 1%. Therefore, it can be confirmed that the method of dimensional stabilization method of the thermal compression wood can be carried out very effectively through post heat treatment process.

Experimental Study on Performance Characteristics of High Speed Air Valve for Water Works (급수용 급속공기밸브의 성능특성에 관한 실험적 연구)

  • Lee, Sun Kon;Kaong, Sae Ho;Yang, Cheol Soo;Woo, Chang Ki
    • Journal of the Korean Society of Safety
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    • v.29 no.5
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    • pp.1-6
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    • 2014
  • When the fluid energy convert into kinetic energy due to water hammer, the propagation velocity of pressure wave appear. The propagation velocity of pressure wave(1050 m/s) of very fast could be damage to the pipeline system. If the occurrence of water hammer is due to down-pressure, the faster the air exhaust or supply device is needed. it is high Speed Air Valve. In this paper, Each 3.12, 3.13, 3.72, $3.74kg/cm^2$ pipeline pressure were setting, and then executed pressure rapid drop for obtaining a high Speed Air Valve Operating time and pressure change data. the result was that pipe line pressure stabilization time were each 0.98, 1, 1.22, 1.25 sec. In other words, that pressure drop experimental results pipe line pressure was equal to atmospheric pressure without negative pressure After about one second. The study result would be useful to pipe line system stability design because this data could be foresee pressure stabilization time.