• Title/Summary/Keyword: Water+methanol

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Pervaporation of binary Water/Methanol and Water/Butanol Mixtures through Zeolite 4A Membranes: Experiments and Modeling (제올라이트 4A 분리막을 이용한 물/메탄올, 물/부탄올 혼합물의 투과증발 특성 연구: 실험 및 모형)

  • Oh, Woong-Jin;Jung, Jae-Chil;Yeo, Jeong-gu;Lee, Jung Hyun;Kim, Hyunuk;Park, Young Cheol;Lee, Dong-Ho;Moon, Jong-Ho;Cho, Churl-Hee
    • Membrane Journal
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    • v.27 no.6
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    • pp.487-498
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    • 2017
  • In this study, pervaporation performances of water/methanol and water/butanol mixture were evaluated using zeolite 4A membranes manufacutred by FINETECH by experimental works and numerical modeling. Permeation and separation characteristics, such as flux and separation factor, were analyzed by gas chromatography (TCD) and liquid nitrogen traps. Experiments have shown that water is selectively separated from a mixture of water and methanol (separation factor up to approximately 250) and water and butanol (separation factor up to approximately 1,500). Generalized Maxwell Stefan (GMS) theory was implemented to predict pervaporation behaviors of water/alcohol mixtures and diffusional coefficients of zeolite layer were obtained through parameter estimation using $MATLAB^{(R)}$ optimization toolbox. Since the pore size of zeolite 4A are much larger than kinetic diameter of water molecules and smaller than those of methanol and butanol, zeolite 4A membranes can be applied to in situ water removal process such as membrane reactors or hybrid reaction-dehydration process.

Water Swelling and Methanol Transport Behaviour of $PVdF/SPEEK/TiO_2$ Hybrid Membrane (PVdF/SPEEK/TiO2 하이브리드 막의 수분함량과 메탄올 전이현상)

  • Yu Seon Gyeong;Kim Han Ju;Park Su Gil;Kim Yeong Jae
    • 한국전기화학회:학술대회논문집
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    • 2005.07a
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    • pp.233-240
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    • 2005
  • A series of inorganic-organic hybrid membranes were prepared with a systematic variation of titanium dioxidenanoparticles content. Their water uptake, methanol permeability and proton conductivity as a function of inoranic oxide content were investigated. The results obtained show that the inorganic oxide network decreases the proton conductivity and water swelling. It is also found that increase In inorganic oxide content leads to decrease of methanol permeability. In terms of the morphology, membranes are homogeneous and exhibit a good adhesion between inorganic domains and the polymer matrix. The properties of the composite membranes are compared with the standard nafion membrane.

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Antimicrobial Effectiveness of Pine Needle Extract on Foodborne Illness Bacteria

  • Kim, Keun-Young;Davidson, P.-Michael;Chung, Hee-Jong
    • Journal of Microbiology and Biotechnology
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    • v.10 no.2
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    • pp.227-232
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    • 2000
  • Fresh pine needles were collected and extracted with 95% methanol and the extract was concentrated to determine its antimicrobial activity. The methanol extract had a considerable inhibitory effect on the tested bacteria, such as Esherichia coli 0157;H7, Listeria monocytogenes, Salmonella typhimurium, and Staphylococcus aureus. The methanol extract of pine needles was further fractionated to chloroform, ethylacetate, butanal, and water fractions. Among these four fractions, the butanol and water fractions, which showed a relatively strong inhibitory effect on all of the tested bacteria, were purified and the minimum ingibitory concentration (MIC) was determined for each microorganism. The MIC raged between 25 mg/ml and 45 mg/ml depending on the microorganism. the purified active fractions were applied to sterilized milk as a model food system to define the antimicrobial effectiveness and it was found that the antimicrobial activities in the water fractions were stronger than those in the butanol fractions.

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Titanium Dioxide Nanoparticles filled Sulfonated Poly(ether ether ketone) Proton Conducting Nanocomposites Membranes for Fuel Cell

  • Kalappa, Prashantha;Hong, Chang-Eui;Kim, Sung-Kwan;Lee, Joong-Hee
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.11a
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    • pp.87-90
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    • 2005
  • This paper presents an evaluation of the effect of titanium dioxide nanoparticles in sulfonated poly(ether ether ketone) (SPEEK) with sulfonation degree of 57%. A series of inorganic-organic hybrid membranes were prepared with a systematic variation of titanium dioxide nanoparticles content. Their water uptake, methanol permeability and proton conductivity as a function of temperature were investigated. The results obtained show that the inorganic oxide network decreases the proton conductivity and water swelling. It is also found that increase in inorganic oxide content leads to decrease of methanol permeability. In terms of morphology, membranes are homogeneous and exhibit a good adhesion between inorganic domains and the polymer matrix. The properties of the composite membranes are compared with standard nafion membrane.

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Application of a New Method to Reproduce the Enthalpies of Transfer of NaI from Water to Aqueous Methanol, Ethanol and iPrOH Solvent Systems at 298 K

  • Rezaej Behbehani, G.
    • Bulletin of the Korean Chemical Society
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    • v.26 no.2
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    • pp.238-240
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    • 2005
  • The enthalpies of transfer, ${\Delta}H_t{\Theta}$, of NaI from water to aqueous methanol, ethanol and isopropanol, iPrOH, systems are reported. These data have been analysed in terms of the new solvation theory. These data are considered in terms of the new developed solvation theory including variable ($\alpha$n + $\beta$N), the net effect of the solute on the solvent-solvent bonding, is positive if there is a net breaking or weakening of solvent-solvent bonds. The solvation parameters recovered from the analyses indicate that the net affect of NaI on solvent structure is a breaking of solvent-solvent bonds and that NaI is preferentially solvated by water in all aqueous alcohol systems considered. ($\alpha$n + $\beta$N) values increase with increasing in the size of the alcohol alkyl residue from methanol to iPrOH.

A Study on the Effects of Rhodiola rosea Root on the Immune System (홍경천(紅景天)의 면역증진(免疫增進) 효능(效能)에 대한 연구(硏究))

  • Kim, Jung-Yeal;Lee, Young-Jong
    • The Korea Journal of Herbology
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    • v.23 no.4
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    • pp.179-189
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    • 2008
  • Objectives: Effects of Rhodiola rosea root on immunity were examined. Methods: Water extracts and methanol extracts of Rhodiola rosea root were treated on the increase of immunity cells and the activation of cytokines were examined. Results: 1. Water extracts and methanol extracts of Rhodiola rosea root had positive effects on the increase of B-cells, T-cells, and NK cells, and on the facilitation of cytokines such as IL-6 and TNF-${\alpha}$. 2. Water extracts and methanol extracts of Rhodiola rosea root activated NK cells, and induced the generation of NO- of NK cells and macrophages. Conclusions: Rhodiola rosea root can be used to increase immunity.

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Plants with Liver Protective Activities (II) -Potential Hepatotonic Activities of Plantago asiatica Seed- (강간제(强肝劑)로 사용(使用)된 생약(生藥)의 조사연구(調査硏究) (II) -차전자(車前子)의 강간효과(强肝效果)에 관(關)하여-)

  • Chang, Il-Moo;YunChoi, Hye-Sook
    • Korean Journal of Pharmacognosy
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    • v.9 no.3
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    • pp.139-144
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    • 1978
  • Total methanol extract of Plantago asiatica seeds showed significant hepatotonic activities against animal model of hepatitis. The methanol extract was further fractionated with petroleum ether, chloroform, n-butanol and water. Among these fractions, methanol extract and water and chloroform fractions exhibited hepatonic activities, whereas petroleum ether and n-butanol fractions appeared to give rise a rather toxicity. Measurements of serum GOT, GPT and duration of sleeping time induced by hexobarbital after $CCl_4$ intoxication indicated that water fraction showed most potent activities.

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A study on Combustion and Exhaust Emission of Diesel Engine (디젤기관의 연소와 배출물에 관한 연구)

  • 조진호;김형섭;박정률
    • Journal of the korean Society of Automotive Engineers
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    • v.13 no.5
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    • pp.81-88
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    • 1991
  • Combustion characteristic, concentration of NOx and exhaust smoke opacity was experimentally tested, according to fuel injection timing, mixing ratio of water and methanol for the driving condition of 2000 rpm of engine revolution and constant load(7.5kg/cm$^{2}$) using emulsified fuel of gas oil-water methanol. The result obtained was as following. Thermal efficiency indicated highly 0.4-2.7% for emulsified fuel then gas oil, and injection timing when maximum thermal efficiency, slicily risen then gas oil. For constant fuel injection timing ignition lag was increased, combustion duration decreased, maximum heat release rate indicated high, and concentration of NOx and exhaust smoke opacity is decreased, as function of water and methanol content y was higher.

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Simultaneous Water and class I Methanol maser Survey of Shocker H2 Emitting regions

  • Lim, Wang-Gi;Lyo, A-Ran;Kim, Kee-Tae
    • The Bulletin of The Korean Astronomical Society
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    • v.36 no.2
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    • pp.118-118
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    • 2011
  • We executed a simultaneous survey of 22 GHz water maser and 44 GHz methanol maser toward 290 shocked $H_2$ emitting regions, which were identified from the galactic plane survey at $H_2$ 2.122 micrometer (UKIRT Widefield Infrared Survey for $H_2$; UWISH2). The primary goal of this observation is to characterize the H2 emission sources whether they are sincerely due to the outflows of young stellar objects or other shocked emission from older/evolved objects. We discovered 15 water maser sources and 15 methanol maser sources which provide the detection rate of around 5 percents. Most of detected sources have IRAS sources, infrared dark clouds, and/or submilimeter sources in the beam size of KVN single dish. In this poster, we will present the detailed results of our survey observation and discuss about the star formation rate in the galactic plane.

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A Bioassay of Ginseng Extract s Based on Yeast Growth Determination (효모성장 측정을 이용한 인삼추출물의 생물학적 검정)

  • Jung, Noh-Pal
    • Journal of Ginseng Research
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    • v.5 no.1
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    • pp.24-34
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    • 1981
  • For bioassay of the various extracts of ginseng, the growth determination method using Saccharomyces cerevisiae which was cultured with various doses of the extracts, was studied The water extract, Powder. and ethanol extract were more effective (about 45∼ 110% increase) than saponins or its fractions (about 20∼35% increase). The cold methanol residue showed a increase effect but it was not significant. The bioassay curves for the water extract, ethanol extract, the butanol extracted saponins and the cold methanol- residue were made from the experimental data. From these curves it is possible to find the relation between dose and effectiveness and the optimal doses of various ginseng extracts, and the amount of extract in a sample can be estimated The .angers of sample amount were 0.01% (100ppm) ∼0.32% (3200ppm) fo. the water extract, 0.025% (150ppm)∼0.1% (1000ppm) for the ethanol extract, and 0.008% (80ppm)∼0.016% (160ppm) for the saponins. It was impossible to determine the range for the cold methanol- residue, The acceleration effects on the cell proliferation by a only 0.0008% (8ppm) of the diol- and triol-saponin were measurable in earlier Period (24 hour treatment).

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